With the development of big data technology, traditional monitoring methods for the scope of marine pollution can no longer meet the current needs of accuracy and timeliness. In light of the outstanding topic, this study proposed to use big data technology to monitor the scope of marine pollution. The intelligent digital remote sensing technology was used for multi-dimensional monitoring of ocean water quality and completed the calculation of data collected by water quality sensors through the improved big data comparative analysis method. Finally, the scope of pollution monitoring was realized. The results verified that the proposed monitoring method could achieve high-precision and time-sensitive monitoring of the range of marine pollutants, and could identify the basic information of pollutants.