Methylmercury (MeHg), dissolved organic carbon (DOC), and sulfate (SO₄ ⁼) relationships were investigated in the mining-influenced St. Louis River watershed in northeast Minnesota. Fewer wetlands and higher SO₄ ⁼ in the mining region lead to generally lower availability and solubility of DOC in mining streams compared to non-mining streams. MeHg concentrations, however, are similarly low in mining and non-mining streams during low flow periods, implying that the extra DOC found in non-mining streams carries little MeHg with it during these periods. High water levels elevated MeHg concentrations in both stream types owing to release from wetlands of DOC species that contain MeHg and remain relatively soluble in streams with elevated ionic strength. In-river methylation appeared to be a negligible component of the MeHg budget for the St. Louis River during this study as MeHg and DOC concentrations were intermediate to those observed in its mining-influenced and wetland-dominated tributaries.

Hybrid electric vehicle (HEV) technology is critical to reduce the impact of the internal combustion engines on air pollution and greenhouse gases. HEVs have an advantage in market penetration due to their lower cost and higher driving range compared to battery electric vehicles (BEVs). On the other hand, HEVs use an internal combustion engine and still emit air pollutants. It is hypothesized that HEV performance is impacted by the weather conditions as a result of many factors. It was beyond the scope of this work to systematically evaluate all factors so instead we measured emissions from two vehicles driving city and highway routes in Minneapolis, Minnesota in the winter (−5 °C) and looked for major differences in emissions relative to each vehicle and relative to results that would be obtained from a chassis dynamometer in a controlled laboratory setting at a higher temperature approximately 20 °C). The study then looked to associate differences in emissions with the prevailing conditions to gain new insights. Emissions of interest included the total particle number (TPN), solid particle number (SPN), particulate matter mass (PM), and NOx. One key difference in vehicle engine technology was PFI (port fuel injection) versus GDI (gasoline direct injection). We found the frequency at which the Prius hybrid engine reignited was much higher than the Sonata for city and highway driving, although for both vehicles the catalyst temperature remained high and appeared to be unaffected by the reignitions, despite the cold weather. For most conditions, the Prius emitted more NOₓ but fewer particles than the Sonata. In some cases, NOₓ and particle emissions exceeded the most comparable laboratory-based emissions standards.

In recent years, numerous studies have reported the prevalence of organic micropollutants in natural waters. There is an increasing interest in assessing the occurrence and transport of these contaminants in groundwater because a large number of people in the United States rely on groundwater for their drinking water. However, commonly used mass-spectrometry-based analytical methods are expensive and time-consuming. The enzyme-linked immunosorbent assay (ELISA) method offers an inexpensive analytical alternative that provides semi-quantitative results in a relatively quick timeframe. We investigated the use of ELISA for two commonly detected micropollutants, sulfamethoxazole (SMX) and carbamazepine (CBZ), in groundwater collected as part of two different studies, one in Minnesota and the other in Iowa. The ELISA results were compared with two mass-spectrometry-based methods: (1) direct aqueous injection-high performance liquid chromatography/tandem mass spectrometry (HPLC) and (2) online solid-phase extraction with liquid chromatography/electrospray ionization-mass spectrometry (SPE LC). Differences in SMX and CBZ observations between ELISA and both HPLC and SPE LC were analyzed using the Paired Prentice-Wilcoxon test. Estimates of bias and limits of agreement between paired observations also were calculated. The SMX determinations by ELISA yielded results that were 30 and 14% greater than HPLC and SPE LC, respectively. The CBZ determinations by ELISA yielded results that were 25 and 9% greater than HPLC and SPE LC, respectively. The ELISA determinations were in presence-absence agreement with HPLC for 83% of samples for SMX and CBZ; and with SPE LC for 76 and 80% of samples for SMX and CBZ, respectively. Results indicate that ELISA for SMX and CBZ is a reliable and cost effective screening-tool alternative to more commonly used mass spectrometry-based analytical methods.

Although degradation data for herbicides are essential in understanding their potential to be contaminants and are indispensable inputs in computer-based modeling of their fate in environment, most available data only concern surface soils. Soil samples, collected at two depths from four representative sites of a 31.4-ha field located in Blue Earth County, MN, USA, were used to determine acetochlor dissipation under laboratory conditions. A field study was also carried out within a 16-ha watershed in Dakota County, MN, USA, where 38 locations were sampled to obtain sample representative of the full range of soil properties found within the watershed. Acetochlor DT50 values ranged from 6.51 to 13.9 days for surface soils and from 20.3 to 26.7 days for subsurface soils. DT90 values were a factor of four times longer than for DT50 values. Field DT50 values for acetochlor dissipation were not significantly different for the 2 years, 5.7 ±2.5 and 7.7±4.5 days. Dissipation was slightly faster in the field as compared to the laboratory; however, the difference seems insignificant in view of the wide range in soil properties inMinnesota. In both studies, acetochlor would be classified as slightly persistent. For acetochlor, laboratory dissipation studies can be considered representative of field dissipation for the soils and climatic conditions in this study. Inclusion of subsoil degradation data in mathematical models used for ground water risk assessment may improve their capability of predicting potential movement of acetochlor to groundwater. © Springer Science+Business Media Dordrecht 2013.

The development of relationships for predicting the impact of highway stormwater runoff is described. The predictive relationships are regression-based equations reflecting variations in the magnitude of the constituents of interest. The objective is to identify a subset of constituents that can be used as surrogates for the remaining constituents as a means of decreasing the costs of collection and measurement of highway stormwater runoff quality data.The Minnesota highway stormwater quality database complied in the late 1970's and early 1980's is employed in identifying the set of surrogate parameters. The findings indicate that total suspended solids, total dissolved solids, total volatile solids, and total organic carbon are effective surrogate parameters for numerous metals, ionic species, and nutrients. The findings also indicated that the developed ionic species constituent relationships are portable, while the metal and nutrient constituent relationships were limited to urban sites with similar environmental conditions. The development of these relationships represents a step towards remediating and preventing the problem of nonpoint source highway pollution.

This article identifies environmental factors that explain most of the dynamic year-to-year changes in mercury concentrations of young-of-year (YOY) yellow perch (Perca flavescens) in study reservoirs. Mercury concentrations in fish, collected each fall, were measured for 9 years in four reservoirs in northeastern Minnesota. Three to 4 years of data were also obtained for two natural lakes and one other reservoir. Average annual concentrations varied considerably from year to year with a mean change of 39% between consecutive years across all lakes. Those averages show a similar time trend for each lake over the years and suggest that important factors influencing mercury bioaccumulation change annually and are also experienced in common over the study region. Three factors satisfying that description are precipitation depth, water level, and average air temperature. This article reveals that all three have statistically significant correlations with observed mercury concentrations. Moreover, multiple regressions indicate that maximum water levels and average air temperatures explain most of the observed variations. Regressions employing precipitation depth and temperature are less significant.

Atmospheric mercury deposition by wet and dry processes contributes mercury to terrestrial and aquatic systems. Factors influencing the amount of mercury deposited to boreal forests were identified in this study. Throughfall and open canopy precipitation samples were collected in 2005 and 2006 using passive precipitation collectors from pristine sites located across the Superior National Forest in northern Minnesota, USA. Samples were collected approximately every 2 weeks and analyzed for total (THg) and methyl mercury (MeHg). Forest canopy type and density were the primary influences on THg and MeHg deposition. Highest THg and MeHg concentrations were measured beneath conifer canopies (THg mean = 19.02 ng L⁻¹; MeHg mean = 0.28 ng L⁻¹) followed by deciduous throughfall (THg mean = 12.53 ng L⁻¹; MeHg mean = 0.19 ng L⁻¹) then open precipitation (THg mean = 8.19 ng L⁻¹; MeHg mean = 0.12 ng L⁻¹). The greater efficiency of conifers at scavenging THg and MeHg from the atmosphere may increase the risk of mercury related water quality issues in conifer-dominated systems.

Perfluorooctane sulfonate (PFOS) and PFOS-related substances have been listed as persistent organic pollutants in the Stockholm Convention. From August 2012, Parties to the Convention needed to address the use, storage, and disposal of PFOS—including production sites and sites where PFOS wastes have been deposited—in their national implementation plans. The paper describes the pollution in Minnesota (USA) caused by the 3M Company at one of the largest per/polyfluorinated chemical (PFC) production facilities. From early 1950s until the end of 2002, when 3M terminated PFOS and perfluorooctanoic acid (PFOA) production, PFOS, PFOA, and other PFC production wastes were disposed around the plant and in local disposal sites. Discharges from the site and releases from deposits caused widespread contamination of ground and surface waters including local drinking water wells. Fish in the river downstream were contaminated with PFOS to levels that led to fish consumption advisories. Human exposures resulted from ingesting contaminated drinking water, requiring installation of water treatment facilities and alternate water supplies. The critical evaluation of the assessments done revealed a range of gaps in particular of human exposure where relevant exposure pathways including the entire exposure via food have not been taken into consideration. Currently, the exposure assessment of vulnerable groups such as children or Hmong minorities is inadequate and needs to be improved/validated by epidemiological studies. The assessment methodology described for this site may serve—with highlighted improvements—as a model for assessment of other PFOS/PFC production sites in the Stockholm Convention implementation.