Persistent organic pollutants (POPs), including Perfluoroalkyl substances (PFASs), enter into the marine ecosystem, raising questions on possible adverse effects caused to the health of marine organisms and especially of top predators. Thus, there is an urge to assess the occurrence and the tissue distribution of PFASs in apex predators. To this end, the current study examines concentrations and distribution of 15 PFASs among 85 samples of different tissues from 9 shark and ray species collected in Greece. The results showed a similar PFAS pattern among the different tissues, with long carbon chain PFASs being the most frequently detected compounds. PFTrDA was the most predominant compound in terms of concentration and frequency of detection, followed by PFUnDA and PFOS. PFTrDA concentrations ranged between < LOQ and 27.1 ng/g ww, while PFUnDA and PFOS levels ranged from <LOQ to 16.0 and < LOQ to 21.6 ng/g ww, respectively. Regarding their frequency of detection, PFTrDA and PFUnDA were detected in 98% and 91% of the samples, respectively, while PFOS was detected in 79%. ΣPFAS concentrations in each analysed tissue ranged from 0.3 to 85 ng/g ww, with the latter being detected in the liver of angular roughshark (Oxynotus centrina). On average, PFASs were found to be accumulated in tissues in the following order: gonads > heart > liver ≈ gills > muscle. Relative contribution (%) of individual compounds to ΣPFAS concentration varied among the different shark tissues, and also among the different shark species. No correlation between PFASs levels in tissues and sharks’ gender, length and geographical origin was observed.

A study was undertaken to test the hypothesis that the presence of fly ash and other artifactual materials (AMs) significantly increases the toxicity of urban soil and street dust. AMs were distinguished as artifacts (artificial particles > 2 mm in size), and particulate artifacts (≤2 mm in size); street dust was the <63 μm fraction of street sediments. Reference artifacts, street dusts, and topsoils representing different land use types in Detroit, Michigan were analyzed for miscellaneous radionuclides, trace elements, magnetic susceptibility (MS), and acetic acid-extractable (leachable) Pb. Background levels were established using native glacial sediments. Street sediments were found to have a roadside provenance, hence street dusts inherited their contamination primarily from local soils. All soils and dusts had radionuclide concentrations similar to background levels, and radiological hazard indices within the safe range. Artifacts, fly ash-impacted soils and street dusts contained elevated concentrations of toxic trace elements, which varied with land use type, but none produced a significant amount of leachable Pb. It is inferred that toxic elements in AMs are not bioavailable because they are occluded within highly insoluble materials. Hence, these results do not support our hypothesis. Rather, AMs contribute to artificially-elevated total concentrations leading to an overestimation of toxicity. MS increased with increasing total concentration, hence proximal sensing can be used to map contamination level, but the weak correlation between total and leachable Pb suggests that such maps do not necessarily indicate the associated biohazard. Home site soils with total Pb concentrations >500 mg kg−1 were sporadically toxic. Thus, these results argue against street dust as the local cause of seasonally elevated blood-Pb levels in children. Lead-bearing home site soil tracked directly indoors to form house dust is an alternative exposure pathway.

The Wiśniówka rock strip mining area (south-central Poland) with quartzite quarries, acid water bodies and tailings piles is one of the most unique acid mine drainage (AMD) sites throughout the world. This is due to the occurrence of enormous amounts of pyrite unknown in sedimentary formations worldwide. Of the two mineralization zones, one that is the most abundant in arsenical pyrite occurs in the lowermost Upper Cambrian formation of the Podwiśniówka quarry. The As-rich pyritiferous clastic rocks are exposed as a result of deep quartzite extraction during 2013–2014. In addition, the clayey-silty shale interbeds are enriched in rare earth element (REE) minerals. The mining operation left an acidic lake with a pH of about 2.4–2.6 and increased contents of sulfates, metal(loid)s and REE. The Podwiśniówka pyrite-rich waste material was stacked up in many places of the mining area giving rise to strongly acidic spills that jeopardized the neighboring environment. One of these unexplored tailings piles was a source of extremely sulfate- and metal(loid)-rich pools with unusual enrichments in As (up to 1548 mg L⁻¹) and REE (up to 24.84 mg L⁻¹). These distinctly exceeded those previously reported in the Wiśniówka area. A broad scope of geochemical, mineralogical and petrographic methods was used to document these specific textural and mineralogical properties of pyrite facilitating its rapid oxidation. The pyrite oxidation products reacted with REE-bearing minerals releasing these elements into acid water bodies. Statistical methods were employed to connect the obtained tailings pool hydrogeochemical data with those derived from this and the previous studies of the Podwiśniówka and Wiśniówka Duża acid pit lakes. In contrast to metal(loid) profiles, the characteristic shale-normalized REE concentration patterns turned out to be more suitable for solving different AMD issues including provenance of mine waste material in the tailings pile examined.

The beneficial uptake of nutrients by wetland plants is countered to some extent by nutrient release back into the aquatic environment due to vegetative die-back. This current study examined whether Leersia oryzoides, a common wetland plant, exhibits luxury uptake of nutrients from simulated farm runoff. The study also tested whether with subsequent decomposition, these nutrients are released back into the water column. When exposed to elevated (>2 mg/L N and P) runoff, L. oryzoides assimilated significantly higher concentrations of nitrogen (p < 0.001) and phosphorus (p < 0.001) in above-ground biomass as compared to non-enriched treatments (<0.05 mg/L N and P). Subsequently, senescence of enriched above-ground biomass yielded significantly higher concentrations of phosphorus (2.19 ± 0.84 mg P/L). Using L. oryzoides as our model, this study demonstrates nitrogen and phosphorus sequestration during the growing season and release of phosphorus in the winter. Release of sequestered nutrients during plant senescence.

As tracers, rare earth elements (REEs) can reflect the influence of human activities on the environmental changes in aquatic systems. To reveal the geochemical behavior of REEs in a water–sediment system influenced by human activities, the contents of REEs in the surface water and sediment in the Chaohu Lake Basin were measured by inductively coupled plasma mass spectrometry (ICP–MS). The results show that the ΣREE contents in the surface water are 0.10–0.850 μg L⁻¹, the ΣREE contents in the sediments are 71.14–210.01 μg g⁻¹, and the average contents are 0.24 μg L⁻¹ and 126.72 μg g⁻¹, respectively. Almost all water and sediment samples have obvious light REE (LREE) enrichment, which is the result of the input of LREE-rich substances released by natural processes and human activities (industrial and agricultural production). Under the alkaline water quality conditions of Chaohu Lake, REEs (especially LREEs) are easily removed from water by adsorption/coprecipitation reactions with suspended colloidal particles, which leads to the enrichment of LREEs in sediments. The Ce anomaly of the water–sediment system is related to the oxidation environment, while the Eu anomaly is related to the plagioclase crystallization. Significant Gd anomalies was observed in the downstream of rivers flowing through urban areas, which was related to the anthropogenic Gd wastewater discharged by hospitals. The ∑REE–δEu and provenance index (PI) discrimination results are consistent, indicating that the sediments in Chaohu Lake mainly come from rivers flowing through the southwest farmland. Furthermore, the spatial distribution of REEs shows that these tributaries are significantly affected by agricultural activities. The distribution and accumulation of REEs in Chaohu Lake are the result of the interaction of natural and human processes. The results can provide a scientific reference for the distribution and environmental behavior of REEs in aquatic environments disturbed by human beings.

Effective and fair mitigation measures hinge on the identification of hotspots and tracking provenance on reactive nitrogen (Nr) loss at a high spatial resolution. We assessed the Nr loss intensity in China at 1 km spatial resolution from 1980 to 2015. The total Nr loss increased from 20.2 to 54.5 Tg N yr⁻¹, with hotspots (>100 kg N ha⁻¹ yr⁻¹) concentrated in the North China Plain, the Middle and Lower Yangtze River and the Sichuan Basin. The Nr loss hotspots covered less than 20% of the Chinese territory but contributed more than 90% of total Nr loss since 1990. Geographical disparity in Nr loss has increased and calls for a fair regional policy synergy. Compared to managing Nr loss based only on production, we demonstrate that the estimation of Nr loss responsibility driven by consumption has greater potential to allocate a fair share of responsibility for reducing Nr loss.

Rare earth elements (REEs) are widely used in optoelectronic industries, and they can be emitted into the environment and may induce biological effects. In this study, we investigated the provenance and bioaccessibility of REEs in atmospheric particles (APs) collected from areas impacted by the optoelectronic industry. The geoaccumulation index (Igₑₒ) values showed that Y, Eu, and Tb were much more enriched in the APs from the optoelectronic recycling sites than in those from the optoelectronic producing sites and were not enriched in the APs from the optoelectronic administrative sites and background sites. The characteristic parameters and the distribution patterns of REEs demonstrated that the AP samples from the recycling sites and producing sites showed remarkably positive Eu and Tb anomalies. According to the positive matrix factorization (PMF) model, the optoelectronic industry was quantitatively determined to contribute 82.8% of Y, 86.5% of Eu, and 83.4% of Tb. Furthermore, an in vitro physiologically based extraction test (PBET) was performed to assess the bioaccessibility of REEs in the APs. The results showed that the bioaccessibility of all the REEs in the APs was below 50.0% in the human gastrointestinal tract, with higher values in the gastric phases than in the intestinal phases. In particular, extremely low gastric bioaccessibilities of Tb and Ce and relatively high gastric bioaccessibilities of Y and Eu were observed in the APs from the recycling sites and producing sites, which may due to the chemical composition of the compounds containing REEs that are used in the optoelectronic industry. In conclusion, our results provide additional information about the contribution and influence of the optoelectronic industry on the provenance and bioaccessibility of REEs in APs.

Atmospheric particulates play a vital role in the transport of potentially toxic metals, being an important exposure pathways of people to toxic elements, which is faster and can occur in a much larger scale than water, soil and biota transport. Windblown materials in abandoned tailing ponds have not been well examined. The objectives of this investigation were: to study the major physical and geochemical properties of the materials eroded by wind inside the tailing ponds, and to understand the relative contribution of different sources to its heavy metals concentration. Study area is located in Cartagena-La Union mining district (SE Spain), where metallic mining of Fe, Pb and Zn has been developed for more than 2500 years. Wind-eroded particulates were monthly collected at 3 different heights (20, 50, and 80 cm) from the ground for a period of a full year using 4 dust collectors. Four tailing samples and 4 surface soil samples from the surrounding hills were also taken. Dust, soil, and tailing samples were examined for pH, particle size distribution, electrical conductivity, calcium carbonate content, Pb, Cu, Zn, Cd, Mn, Co, Ni, Ti and Zr concentrations. The results indicated that very coarse textured, slightly saline, and almost neutral wind-eroded deposits were generated with a very high temporal variability throughout the year. They also showed that the concentration of Cd, Mn, Pb and Zn, in the dust samples is extraordinarily high (18, 1254, 1831, and 5747 mg kg−1 respectively), whereas Co, Ni, and Cu had concentrations into the range of background concentrations found in the Earth's crust (3.8, 12, and 60 mg kg−1 respectively). Besides, the concentration of both categories of heavy metals in the dust samples was higher than that in tailing and less than that of the soils. The barren surfaces of tailing ponds and also the surface soils of the surrounding area seem to be the major contributors to the dust collected. Therefore, abandoned mines as well as their tailing ponds should be rehabilitated by proper technologies and then well stabilized and/or covered by appropriate plant vegetation to control the transfer, particularly by air, of environmentally hazardous materials to other areas.

The exposure of benzo [a]pyrene (BaP) in recent times is rather unavoidable than ever before. BaP emissions are sourced majorly from anthropogenic rather than natural provenance from wildfires and volcanic eruptions. A major under-looked source is via the consumption of foods that are deep-fried, grilled, and charcoal smoked foods (meats in particular). BaP being a component of poly aromatic hydrocarbons has been classified as a Group I carcinogenic agent, which has been shown to cause both systemic and localized effects in animal models as well as in humans; has been known to cause various forms of cancer, accelerate neurological disorders, invoke DNA and cellular damage due to the generation of reactive oxygen species and involve in multi-generational phenotypic and genotypic defects. BaP's short and accumulated exposure has been shown in disrupting the fertility of gamete cells. In this review, we have discussed an in-depth and capacious run-through of the various origins of BaP, its economic distribution and its impact as well as toxicological effects on the environment and human health. It also deals with a mechanism as a single compound and its ability to synergize with other chemicals/materials, novel sensitive detection methods, and remediation approaches held in the environment.

Globally, arsenic (As) contamination is widespread in hydrological systems and the link between As enrichment and regional tectonic and climatic factors is still not well understood in orogenic environments. This work provides new insights on the relationship between As, tectonics, and climate by assessing the hydrochemistry of Chile, an active subduction zone with highly diverse natural settings. Selected study sites include fluvial courses along four regional transects connecting the Chilean coast to the Andes Cordillera in the northern, central, and southern areas of the country. The results indicate that As concentrations in surface water and fluvial sediments show a general positive correlation to crustal thickness and they tend to decrease progressively from northern to southern Chile. In contrast, As concentrations are negatively correlated to average annual precipitation which shows a significant increase toward southern Chile. From a regional tectonic perspective, northern Chile presents greater Andes shortening and higher crustal thicknesses, which induces increased crustal contamination and As content at the surface. Extremely low precipitation rates are also tied to local As enrichment and a sediment-starved trench that might favor higher plate coupling and shortening. On the contrary, decreased shortening of the Andes in southern Chile and related lower crustal thickness induces lower crustal contamination, thus acting as an As-poor provenance for surficial sediments and surface water. High precipitation rates further induce dilution of surface water, potential mobilization from the solid phase, and a significant amount of trench sediments that could induce lower plate coupling and lower shortening. At the local scale, a low potential for As mobilization was found in northern Chile where a greater distribution of As-bearing minerals was observed in sediments, mostly as finer particles (<63 μm). The abundance of Fe-oxides potentially acts as a secondary surficial sink of As under the encountered physicochemical conditions.