In 2016, a massive harmful algal bloom (HAB) of Alexandrium catenella around Chiloe island caused one of the major socio-ecological crisis in Chilean history. This red tide occurred in two distinct pulses, the second, most anomalous, bursting with extreme toxicity on the Pacific coast, weeks after the highly controversial dumping off Chiloe of 4,700 t of rotting salmons, killed by a previous HAB of Pseudochattonella verruculosa. We study the transport of this pollution, analyzing the physical oceanographic conditions during and after the dumping. We find that a cyclonic gyre was present between the dumping site and the coast, visible in satellite altimetry and sea surface temperature data. Using Lagrangian simulations, we confirm that near-surface currents could have brought part of the pollution to the coast, and fueled the bloom. This scenario explains also the anomalous later finding of ammonium near Chiloe. Finally we discuss the mismanagement of risk throughout the events. | Comision Nacional de Investigacion Cientifica y Tecnologica (CONICYT) CONICYT FONDECYT 3150587

With the ever-increasing demand for lithium (Li) for portable energy storage devices, there is a global concern associated with environmental contamination of Li, via the production, use, and disposal of Li-containing products, including mobile phones and mood-stabilizing drugs. While geogenic Li is sparingly soluble, Li added to soil is one of the most mobile cations in soil, which can leach to groundwater and reach surface water through runoff. Lithium is readily taken up by plants and has relatively high plant accumulation coefficient, albeit the underlying mechanisms have not been well described. Therefore, soil contamination with Li could reach the food chain due to its mobility in surface- and ground-waters and uptake into plants. High environmental Li levels adversely affect the health of humans, animals, and plants. Lithium toxicity can be considerably managed through various remediation approaches such as immobilization using clay-like amendments and/or chelate-enhanced phytoremediation. This review integrates fundamental aspects of Li distribution and behaviour in terrestrial and aquatic environments in an effort to efficiently remediate Li-contaminated ecosystems. As research to date has not provided a clear picture of how the increased production and disposal of Li-based products adversely impact human and ecosystem health, there is an urgent need for further studies on this field.

The growing use of coastal areas for different economic purposes is responsible for increasing pollution by hydrocarbons in marine environments. As a consequence of these activities, accidents during fuel extraction, transport, and storage can occur, causing intense environmental degradation. Numerical modeling of the trajectory of oil stains becomes an important tool with low operational costs, providing powerful support to the government agencies in charge of risk management associated with possible oil accidents, by helping to generate scenarios and strategies for containment and cleaning of affected environments. In this sense, the aim of this study is to estimate environmental vulnerability to oil at beaches located in the Itapuã State Park (PEI), a Protection Conservation Unit. This work focused on describing a methodology to estimate the vulnerability of coastal areas, with emphasis on the fact that the study was carried out in a closed environment. For that, an approach was used based on the integration of: (1) an intrinsic variable to the environment; (2) a dynamic variable determined through diesel oil surface dispersion scenarios. Four hypothetical accident scenarios with 20 m³ of diesel oil were simulated in 2018, during five days of simulations with instant dumping in the navigation channel of the local waterway near the PEI. The results suggest the forcing of the field of intensity and direction of the local winds as preponderant for the dynamics of movement and structure of the spots, with the zonal and meridional components of the fields of superficial currents acting in this process as a secondary factor. The study showed that all beaches in the park are susceptible to contact with oil throughout the simulated year, with Pombas Beach, Pedreira Beach, and Onça Beach being affected in all simulated scenarios, which classifies them as very high vulnerability and defines them as priority protection areas.

Rapid economic growth, urban sprawl, and unplanned industrialization has increased socioeconomic statuses but also decreased air quality in South Asian developing countries. Therefore, severe increase in air pollution has been a threat of local population, regarding health statuses, livability and quality of life. It is necessary to estimate fine-scale spatiotemporal distribution of ambient PM₂.₅ in a national context so that the environmental planners and government officials can use it for environmental protocol development and policy-making. In this study, a spatiotemporal land use regression (LUR) model is developed to refine global air quality data to the national-scale ambient PM₂.₅ exposure in a high-density country in South Asia – Pakistan. Combining with transport network, patterns of land use, local meteorological conditions, geographic characteristics, landscape characteristics, and satellite-derived data, our resultant model explains 54.5% of the variation in ambient PM₂.₅ concentration level. Furthermore, tree coverage and road transport are identified to be two influential factors of the national-scale spatial variation of PM₂.₅ in Pakistan, which implied that urbanization might be the major cause of air pollution across the country. In conclusion, our resultant LUR model as well as the spatial map of ambient PM₂.₅ concentration level can be used as a supporting tool for national health risk management and environmental planning, and could also contribute to the air quality management and pollution reduction actions of Pakistan.

Sustainable remediation is a new way of thinking and acting in the management of contaminated sites. This research aims to identify and structure the state-of-the-art of sustainable remediation from the risk management and stakeholder involvement perspective. A systematic and bibliometric study of scientific production was performed on scientific papers indexed in the Scopus and Web of Science databases with the objectives: 1) to select a bibliographic portfolio that is aligned with the perception of the researchers in regard to theme, 2) to perform a bibliometric analysis of the selected bibliographic portfolio, and 3) to conduct a thematic synthesis and identify the integration of sustainable remediation from the risk management and stakeholder involvement perspective. The results indicated that although sustainable remediation is a recent theme it presents a promising field for development worldwide, verified by the growing number of publications in recent years. A change is observed in the way risk management is considered with the rise of sustainable remediation, demonstrated by different approaches in publications. Likewise, the involvement of stakeholders is widely discussed, and the importance of their participation in decision-making processes in the field of sustainable remediation is identified. This research brings several and new contributions as it provides with a detailed overview and guidance about the main characteristics and peculiarities as well as what already exists, the form to approach, the advances and what still needs to be improved so that the perception of stakeholders and risk management are better understood within the context of sustainable remediation.

Hexabromocyclododecane (HBCD) is commonly used in commercial products and factories. HBCDs can be detected in the air, bioaccumulated deposits, water, soil, sediments, and in biota and foodstuffs in the food-chain because they are not chemically bound to the polymer. We determined the levels of α-, β-, and γ-HBCDs in 270 foodstuffs and the doses of HBCDs Taiwanese are normally exposed to. We also wanted to create a strategy of risk management for HBCDs based on margins of exposure (MOE). HBCDs were frequently detectible in fish, seafood, and poultry. Their highest concentrations were in fish, oil, poultry, and livestock. The highest estimated daily intake was in 0- to 3-year-olds (1.576 ng/kg/day), and lower in 3- to 6- (1.064 ng/kg/day), 6- to 12- (0.899 ng/kg/day), and lowest in 12- to 16- (0.632 ng/kg/day) year-olds. The exposure doses to HBCDs indicated no health concern for Taiwanese. Except for fish, significant concentrations of α- and γ-HBCDs were detected in many other foodstuffs, which might indicate that exposure to HBCD is a relatively recent problem. Therefore, one goal of a management policy should be to follow-up the flow direction of HBCDs in Taiwan.

Hexabromocyclododecanes (HBCDs) are the subject of recent interest and potential risk assessment particularly in China due to its ubiquitous existence in a variety of environmental media. This paper reviews the recent studies conducted on HBCDs in different environmental media (air, soil, water, river sediment, sewage sludge, biota and daily food) in China. At the same time, human health risks via food and occupational exposure of HBCDs in production plants, expanded polystyrene (EPS) and extruded polystyrene (XPS) plants were assessed. The review reveals that HBCDs levels of air, soil, sediment, sewage sludge, biota and food presented a geographical variation in the eastern coastal regions of China. There were many factors resulting in the variation, such as sampling sites, climate and analytical method. In terms of diastereoisomer, α-HBCD and γ-HBCD were the predominant diastereoisomers in air, soil, sediment, and sewage sludge. In the water, α-HBCD and γ-HBCD shared the major proportion to the total HBCDs. However, only α-HBCD was the predominant diastereoisomer in biota. With regard to human exposure pathway to HBCDs, food was the major route for human exposure to HBCDs, especially meat. In addition, soil and road dust were also important exposure pathways. Furthermore, workers and residents, especially infants in and around waste dumping sites and industrial areas are exposed to the highest HBCDs levels among all the populations studied thus far. HBCDs posed a potential threat to the environment and human health. Therefore, risk assessment and management have an important role to play in preventing and mitigating HBCDs risks.

Methodology to quantify and distinguish the spatial distribution of the risks from multiple pollutants within the region was developed in this paper. An integrated quantitative risk assessment was conducted by utilizing a large amount of information available to explore spatial distribution of risk by single and multiple pollutants, and the magnitude of the overall risk from multiple pollutants based on the current concentrations of pollutants and toxicity data. Two target criteria levels – level I (NOEC/LOEC based) and level II (LC/EC/IC₅₀ based) – were employed, and thus, the regional and sub-regional risks were evaluated according to these two levels. The risk of multiple toxic metals (As, Cd, Cr, Hg and Pb) to a terrestrial ecosystem for the region around the Bohai Sea and the Yellow Sea were evaluated as a case. The total overall ecological risks from heavy metals in the region for level I and level II were 21.73% and 12.53%, respectively. The risks were ranked in the order of Cr > As > Pb > Cd > Hg with Cr posing the greatest ecological risk, which was 61.12% for level I. The top three cities according to the level II ecological risk were Cangzhou > Lianyungang > Panjin, while the top three cities of level I ecological risk were Cangzhou > Panjin > Lianyungang. This method provides a quantitative risk assessment with multiple and clear protection levels for risk management.

Produced water is a type of wastewater generated from hydraulic fracturing, which may pose a risk to the environment and humans due to its high ionic strength and the presence of elevated concentrations of metals/metalloids that exceed maximum contamination levels. The mobilization of As(V) and Se(VI) in produced water and selected soils from Qingshankou Formation in the Songliao Basin in China were investigated using column experiments and synthetic produced water whose quality was representative of waters arising at different times after well creation. Temporal effects of produced water on metal/metalloid transport and sorption/desorption were investigated by using HYDRUS-1D transport modelling. Rapid breakthrough and long tailings of As(V) and Se(VI) transport were observed in Day 1 and Day 14 solutions, but were reduced in Day 90 solution probably due to the elevated ionic strength. The influence of produced water on the hydrogeological conditions (i.e., change between equilibrium and non-equilibrium transport) was evidenced by the change of tracer breakthrough curves before and after the leaching of produced water. This possibly resulted from the sorption of polyacrylamide (PAM (-CH2CHCONH2-)n) onto soil surfaces, through its use as a friction reducer in fracturing solutions. The sorption was found to be reversible in this study. Minimal amounts of sorbed As(V) were desorbed whereas the majority of sorbed Se(VI) was readily leached out, to an extent which varied with the composition of the produced water. These results showed that the mobilization of As(V) and Se(VI) in soil largely depended on the solution pH and ionic strength. Understanding the differences in metal/metalloid transport in produced water is important for proper risk management.

Human exposure to polycyclic aromatic hydrocarbons (PAHs) in indoor environments can be particularly relevant because people spend most of their time inside buildings, especially in homes. This study aimed to investigate the most important particle-bound PAH sources and exposure determinants in PM2.5 samples collected in 19 homes located in northern Italy. Complementary information about ion content in PM10 was also collected in 12 of these homes. Three methods were used for the identification of PAH sources and determinants: diagnostic ratios with principal component and hierarchical cluster analyses (PCA and HCA), chemical mass balance (CMB) and linear mixed models (LMMs). This combined and tiered approach allowed the infiltration of outdoor PAHs into indoor environments to be identified as the most important source in winter, with a relevant role played by biomass burning and traffic exhausts to be identified as a general source of PAHs in both seasons. Tobacco smoke exhibited an important impact on PAH levels in smokers' homes, whereas in the whole sample, cooking food and natural gas sources played a minor or negligible role. Nitrate, sulfate and ammonium were the main inorganic constituents of indoor PM10 owing to the secondary formation of ammonium sulfates and nitrates.