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Agricultural pesticide residues in oysters and water from two Chesapeake Bay tributaries
1998
Lehotay, S.J. | Harman-Fetcho, J.A. | McConnell, L.L.
Little is known of the impact of agricultural activity on oysters in Chesapeake Bay tributaries. As a preliminary assessment of pesticide residues in oyster tissues, this study monitored more than 60 pesticides in oysters and overlying water in two tributaries of the Chesapeake Bay. Paired water and oyster samples were collected throughout 1997 from the Patuxent and Choptank Rivers which discharge into opposite shores of the Chesapeake Bay in Maryland. In water, herbicides such as atrazine, simazine, cyanazine, and metolachlor were present throughout the year with individual water concentrations peaking as high as 430 ng/1 in the late spring and summer and subsiding in the fall. These herbicides were not detected in the oysters even when concentrations were highest in the water. Another herbicide, trifluralin, was detected throughout the year at concentrations of less than 0.6 ng/1 and 0.4 ng/g (wet weight) in water and oyster samples, respectively. Several insecticides, such as endosulfans I and II, endosulfan sulfate, chlorpyrifos, α- and γ-HCH, p,p'-DDE, o,p'-DDT, trans-nonachlor, and trans-chlordane were also measured in both oysters and water at low concentrations.
Afficher plus [+] Moins [-]Polycyclic Aromatic Hydrocarbons in the Sediments of the Milwaukee Harbor Estuary, Wisconsin, U.S.A
1998
Li, An | Ab Razak, Irwan A. | Ni, Fan | Gin, Michael F. | Christensen, Erik R.
From 1990 to 1994, a total of 21 sediment cores and 37 grab sediment samples were collected from the Milwaukee Harbor Estuary. Each sediment core was sectioned and dated using ²¹⁰Pb and¹³⁷ Cs radioisotope techniques. A total of 305 samples were analyzed for sixteen polycyclic aromatic compounds (PAHs). Grain size distribution, porosity, and total organic carbon content as measured by loss on ignition were also determined. The results provide a historical overview of the impact of industrialization in the Milwaukee area. Although highly variable, the concentration profile of PAHs show, in general, peaks in the 1950's through 1980's. The PAH concentrations have declined since then for most sediment cores. The current levels of total PAHs in most surface sediment samples range from 25 to 200 ppm. A few cores, some of which were collected in 1994, have an elevated PAH concentration at the surface. Toxicity of the surface sediments was evaluated by comparing with the benchmark values developed by the United States National Oceanic and Atmospheric Administration (NOAA). The most heavily contaminated area was found in the Kinnickinnic River between the Becher Street Bridge and the Wisconsin Wrecking Company Wharf. The highest total PAH concentration determined from seven vibra cores collected in this area ranges from 380 to 1000 ppm. The former Wisconsin Solvay Coke Company may have been a major point source of PAHs until the 1970's. Highway traffic and various industrial discharges also contribute to the sediment PAHs in this area.
Afficher plus [+] Moins [-]Assessment of Atmospheric Heavy Metals by Moss Monitoring with Isothecium Stoloniferum Brid. in the Fraser Valley, B.C., Canada
1998
Pott, Ute | Turpin, David H.
The atmospheric heavy metal pollution of the Fraser Valley, B.C., Canada was assessed in 1993 by analyzing 62 samples of the common woodland moss Isothecium stoloniferum for lead, cadmium, nickel, zinc, chromium, and manganese. The latter two metals did not show a distinct regional distribution, but lead, cadmium, nickel, and zinc showed distinct pattern along a west-east gradient. High values were found in the metropolitan Vancouver area, located in the west of the study region. Significantly lower values were recorded for mosses from the eastern more rural areas of the Fraser Valley. Metal pollutants are likely to be contained close to their emission sources by alternating south-east, north-west winds. Highest values overall were found in the North Shore Mountains, adjacent to Vancouver. This was related to higher precipitation and short range pollutant transport from the industrialized, heavily populated areas in the floodplain of the Fraser River.
Afficher plus [+] Moins [-]Bioaccumulation and Toxicity of Zinc in Spirogyra Fluviatilis Hilse (Chlorophyta)
1998
Saygideger, S.
The bioaccumulation and toxicity of zinc in Spirogyra fluviatilis Hilse, from two populations in the River Seyhan, Adana, Turkey, were examined in laboratory flowing-water channels. Plants were subjected to zinc concentrations ranging from 0 to 4.0 mg L⁻¹ at current velocities of 25–35 cm s⁻¹ for up to 3 h. There was little difference in zinc bioaccumulation between Spirogyra from the site showing mild organic pollution and that from the site subjected to considerable inputs from urban and motorway runoff. Uptake of zinc increased with increasing concentration in the test solution and was linear and proportional up to 0.5 mg L⁻¹. Cellular damage was evident in Spirogyra subjected to 0.5 mg L⁻¹ zinc, and increased with increasing zinc concentration.
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