Groundwater quality regarding major anions and cations in the Birjand Plain located in the largest desert in Eastern Iran was monitored in this study. Fifteen boreholes were considered as sampling stations and the parameters pH, TDS, EC and major anions and cations were measured in groundwater samples. The dominant groundwater types can be introduced as sodium-chloride and magnesium-sulphate. The majority of samples were within the not-suitable category for drinking uses. Regarding agricultural use, around 80 and 50 per cent of samples indicated a very high salinity hazard and a very high sodium alkali hazard, respectively. Spatial distribution of salinity was also monitored within the study area. If the study area was considered to be a semicircle, the centre appeared to be the least polluted area, while towards the peripheral surroundings, an increasing behaviour was observed. Intrusion of salt water from eastern and western parts of the study area caused severe groundwater degradation. The relatively better quality of groundwater in southern areas may be attributed to a chain of mountains located along south of the study area. The prevention of uncontrolled groundwater withdrawal must be regarded to cease the salinization trend and to prepare the required infrastructure for implementing the artificial recharge projects.

The present study was undertaken to assess the impact of a candidate mosquito larvicide, spinosad (8, 17 and 33 μg L−1) on a field population of Daphnia magna under natural variations of water temperature and salinity, using Bti (0.16 and 0.50 μL L−1) as the reference larvicide. Microcosms (125 L) were placed in a shallow temporary marsh where D. magna was naturally present. The peak of salinity observed during the 21-day observation period may have been partly responsible for the decrease of daphnid population density in all the microcosms. It is also probably responsible for the absence of recovery in the microcosms treated with spinosad which caused a sharp decrease of D. magna abundance within the first two days following treatment whereas Bti had no effect. These results suggest that it may be difficult for a field population of daphnids to cope simultaneously with natural (water salinity and temperature) and anthropogenic (larvicides) stressors. Significant interaction between salinity and spinosad exposure impairs the recovery of a natural population of Daphnia magna

International audience | This review investigates the impact of salinity on the fate of the active compounds of pesticides in a cultivated environment. Due to the over-exploitation of water resources and intensification of agriculture, salinity outbreaks are being observed more often in cultivated fields under pesticide treatments. Nevertheless, there is a poor understanding of the incidence of varying water salt loads on the behavior of pesticides’ active ingredients in soil and water bodies. The present review established that water salinity can affect the diffusion of pesticides’ active ingredients through numerous processes. Firstly, by increasing the vapor pressure and decreasing the solubility of the compounds, which is known as the salting-out effect, salinity can change the colligative properties of water towards molecules and the modification of exchange capacity and sorption onto the chemicals. It has also been established that the osmotic stress induced by salinity could inhibit the biodegradation process by reducing the activity of sensitive microorganisms. Moreover, soil properties like dissolved organic matter, organic carbon,clay content, and soil texture control the fate and availability of chemicals in different processes of persistence in water and soil matrix. In the same line, salinity promotes the formation of different complexes, such as between humic acid and the studied active compounds. Furthermore, salinity can modify the water flux due to soil clogging because of the coagulation and dispersion of clay particle cycles, especially when the change in salinity ranges is severe.

The paper summarizes the results on the quality of surface water of the Gornji Banat region (Serbia, Yugoslavia). Based on different classifications, statistic data processing was made and the conclusions on the usability of the water for irrigation are given. According to the results obtained there is an urgent need for efficient measures to improve the quality of canal water and the control the polluters.

International audience | This review summarizes how salinity and temperature, two key global factors driven by climate change in freshwater systems, interact with other stressors on organisms in controlled small-scale factorial experiments at the population, individual, or subindividual level (excluding mesocosm and field studies). Despite the growing interest, research following all these criteria remains limited with 156 publications of which 50% analyzed stressors + salinity, 46% stressors + temperature, and only 4% involved the triple combination. Research on the combined effect of temperature and salinity predominantly focused on metals, pesticides, and, to a lesser extent, emergent contaminants, such as microplastics and nanomaterials, encompassing various biological models and responses. In general, increased temperature amplifies the single effect of stressors, whereas salinity leads to a higher diversity of responses, with similar proportions of synergisms and antagonisms. Fish (Salmoniformes, Perciformes, and Cypriniformes) were the most studied organisms. Among Crustacea, only cladocerans of the genera Daphnia and Ceriodpahnia were considered. The present review highlights the need to include other species that play key roles in freshwater food webs and to increase triple combination studies to understand complex interactions and develop adaptation and mitigation strategies to preserve the environment and its services in this changing world.

In this paper, some data on long term seasonal investigation of hydrography and plankton are presented. The most important fact is that the whole area is exposed to the impact of the freshwater from numerous sources from the coast and submarine springs in Boka Kotorska Bay, as the impact of rivers Bojana and Drim. Exchange of the intermediate water-masses between Adriatic and Jonian basins is of great importance, too. So, basic ecological data, as well as characteristic phytoplankton and zooplankton groups and species are described.

The main characteristics of catchment area of Boka Kotorska Bay (Adriatic sea, Montenegro, Yugoslavia), are high slope, carstic structure of ground, high precipitation (over 5000 mm a year) and high run-off of rain water. All rainwater is transported trough carstic ground structures quickly appearing in numerous sources along the sea cost or ones located on the bottom of the Bay. The large volume of freshwater which permanently empty into the Bay has the strong influence on the aquatic environment (salinity, temperature, transparency, etc.) and biota (abundance of the species) as it has been observed in the parts of Boka Kotorska Bay (i.e. Morinj and Risan Bays). The abundance and number of species are the good indicator of changes of aquatic environment and hydrological changes as well as of the capability of aquatic organisms to adapt quickly on the severe changes of conditions.

Arsenic (As) is a highly toxic metalloid adversely affecting the environment, human health, and crop productivity. The present study assessed the synergistic effects of salinity and As on photosynthetic attributes, stomatal regulations, and metabolomics responses of the xero-halophyte Salvadora persica to decipher the As-salinity cross-tolerance mechanisms and to identify the potential metabolites/metabolic pathways involved in cross-tolerance of As with salinity. Salinity and As stress-induced significant stomatal closure in S. persica suggests an adaptive response to decrease water loss through transpiration. NaCl supplementation improved the net photosynthetic rate (by +39%), stomatal conductance (by +190%), water use efficiency (by +55%), photochemical quenching (by +37%), and electron transfer rate (54%) under As stress as compared to solitary As treatment. Our results imply that both stomatal and non-stomatal factors account for a reduction in photosynthesis under high salinity and As stress conditions. A total of 64 metabolites were identified in S. persica under salinity and/or As stress, and up-regulation of various metabolites support early As-salinity stress tolerance in S. persica by improving antioxidative defense and ROS detoxification. The primary metabolites such as polyphenols (caffeic acid, catechin, gallic acid, coumaric acid, rosmarinic acid, and cinnamic acid), amino acids (glutamic acid, cysteine, glycine, lysine, phenylalanine, and tyrosine), citrate cycle intermediates (malic acid, oxalic acid, and α-ketoglutaric acid), and most of the phytohormones accumulated at higher levels under combined treatment of As + NaCl compared to solitary treatment of As. Moreover, exogenous salinity increased glutamate, glycine, and cysteine, which may induce higher synthesis of GSH-PCs in S. persica. The metabolic pathways that were significantly affected in response to salinity and/or As include inositol phosphate metabolism, citrate cycle, glyoxylate and dicarboxylate metabolism, amino acid metabolism, and glutathione metabolism. Our findings indicate that inflections of various metabolites and metabolic pathways facilitate S. persica to withstand and grow optimally even under high salinity and As conditions. Moreover, the addition of salt enhanced the arsenic tolerance proficiency of this halophyte.

Zero valent iron-loaded biochar (Fe⁰-BC) has shown promise for the removal of various organic pollutants, but is restricted by reduced specific surface area, low utilization efficiency and limited production of reactive oxygen species (ROS). In this study, iron carbide-loaded activated biochar (Fe₃C-AB) with a high surface area was synthesized through the pyrolysis of H₃PO₄ activated biochar with Fe(NO₃)₃, tested for removing bisphenol A (BPA) and elucidated the adsorption and degradation mechanisms. As a result, H₃PO₄ activated biochar was beneficial for the transformation of Fe⁰ to Fe₃C. Fe₃C-AB exhibited a significantly higher removal rate and removal capacity for BPA than that of Fe⁰-BC within a wide pH range of 5.0–11.0, and its performance was maintained even under extremely high salinity and different water sources. Moreover, X-ray photoelectron spectra and density functional theory calculations confirmed that hydrogen bonds were formed between the COOH groups and BPA. ¹O₂ was the major reactive species, constituting 37.0% of the removal efficiency in the degradation of BPA by Fe₃C-AB. Density functional reactivity theory showed that degradation pathway 2 of BPA was preferentially attacked by ROS. Thus, Fe₃C-AB with low cost and excellent recycling performance could be an alternative candidate for the efficient removal of contaminants.