En 1997, le ministere de l'Amenagement du Territoire et de l'Environnement et l'Agence de l'environnement et de la maitrise se de l'energie (ADEME) ont commande au Laboratoire de Glaciologie et Geophysique de l'environnement de Grenoble (LGGE) (CNRS) une etude visant a evaluer les depots de metaux lourds dans les Alpes francaises en utilisant le manteau neigeux saisonnier comme piege des ces polluants pour les hivers 1997-1998 et 1998-1999. La neige est en effet un support interessant car elle ne permet pas d'interaction chimique avec les metaux. Contrairement aux mousses, ce support a donc l'avantage de permettre la determination du depot reel de ces metaux, parametre indispensable pour evaluer ulterieurement les niveaux superieurs aux charges critiques. Le domaine d'etude a ete delimite au massif alpin, car il fallait trouver un domaine de montagne ou l'on avait des altitudes suffisamment elevees (1500m) pour obtenir un manteau neigeux consequent pendant une assez longue periode. De plus, la region Rhone-Alpes est dotee de vallees fortement industrialisees, avec un fort trafic routier, ce qui va permettre de suivre, entre autres, des polluants traceurs ainsi que leur repartition spatiale, et les niveaux de contamination des Alpes. L'etendue du domaine d'etude a, en revanche, ete etablie selon des criteres pratiques. L'integralite du massif Alpin francais n'etait pas gerable, meme avec l'aide des parcs nationaux, regionaux et des reserves naturelles. Nous avons donc prefere mettre l'accent sur des analyses et interpretations plus poussees au sein de chaque massif plutot que sur une plus grande quantite de mailles donc des echantillons. Dans cet article est presentee toute la methodologie mise en place pour le choix des sites, les prelevements, les analyses. Des premiers resultats sont presentes sur certains massifs

The maintenance of safe-drivingconditions in snow and ice-affected areas in thewintertime includes the use of sodium chloride (NaCl)as de-icing salts. In this study, the impact of NaClon soil-colloid mobilisation and exchangeablebase-cation leaching has been evaluated. The chemistryof groundwater samples below an infiltration trenchfor highway runoff and leachate from column studiessuggested that soil-colloid mobilisation had occurred,as the exchangeable sodium (Na) concentration and theelectrical conductivity (EC) in the groundwater/columnleachate reached the threshold values for colloiddispersion. Generally, samples with no dispersionproblems had high Na and calcium (Ca) concentrations,suggesting that the initial effect of the de-icingsalt was to stabilise the colloids. In the columnstudy there was a good agreement between the degree ofcolloid dipersion problems and lead (Pb) concentrationwhen the pH value was above 7.0. Significant negativecorrelations between Na/CEC (cation exchange capacity)and Ca/CEC in roadside soils from three sitesindicated that Na preferentially displaces Ca from theexchange sites. However, the groundwater dataindicated that Na ions also displace potassium (K) andmagnesium (Mg). A positive effect of NaCl seen at onesite was an increase in the K concentration, which ishighly likely an effect of Na ions displacing fixed Kbetween the layers of 2:1 type clay minerals. In soilslacking these types of clay minerals, severe Kshortage may result from a high plant demand combinedwith the low K concentration in the readily availablefractions in the original soil and a highsusceptibility to leaching. The most significantimpact on soil exchange processes was found to occurwithin 6 m from the road.

Results from the photolysis ofo, p-dichlorobenzene, bromobenzene, andp-dibromobenzene in water ice are reported. All phototransformations appeared to be based on dehalogenation, coupling, and rearrangement reactions in ice cavities. No photosolvolysis products, i.e. products from intermolecular reactions between organic and water molecules, were found. Many of the products were very toxic substances of a high environmental risk, such as PCBs. The results support our model, in which secondary, very toxic, pollutants can be formed in ice, snow, and atmospheric ice particles from primary pollutants through the action of solar irradiation. The photoproducts may be released to the environment by ice melting and evaporation.