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Impact of Fertilizer Factory Emissions on Radiological Content of Soil: A Study in Upper Egypt
2024
Fares, Soad
This study investigated the potential impact of a fertilizer factory in Upper Egypt on the surrounding soil's radioactivity levels. Gamma-ray spectrometry was used to measure the concentrations of naturally occurring radionuclides (226Ra, 232Th, and 40K) in soil samples collected near the factory. Additionally, radon gas concentrations were measured, and various radiological hazard indices were calculated. Activity concentrations of 238U, 226Ra, 232Th, and 40K varied in the soil samples, ranging from 110.63 to 326.12 Bq/kg for 238U, 172.72 to 582.37 Bq/kg for 226Ra, 25.63 to 189.15 Bq/kg for 232Th, and 252.20 to 713.24 Bq/kg for 40K. Radium equivalent activity, absorbed gamma dose, and external and internal hazard indices exceeded permissible levels. Radon gas concentrations varied from 20.89 to 192.30 Bq/m3, with an average of 104.43 Bq/m3. The calculated effective dose from radon inhalation exceeded the recommended limit. The elevated levels of radioactivity in soil and the high radon gas concentrations suggest a potential health risk for farmers and residents near the fertilizer factory. Further investigations and mitigation strategies may be necessary to ensure the safety of the surrounding population.
Afficher plus [+] Moins [-]Ecological Risk Assessment of the Soil around Odo Iya-Alaro (Iya Alaro River) at Ojota, Lagos States, Nigeria
2023
Adio Hassan, Isiaka | Abdul Raheem, Wahabi Olaitan | Adejoke Obalola, Aishat | Oluwole Bello, Isiaq
Human developmental activities always result to waste generation; that invariably pollute the environment, if not properly managed. The aim of this study is to determine soil quality around Odo Iya-Alaro at Ojota, Lagos. A total of 12 soil samples were collected from 0 -15 cm and 15- 30 cm at three different spots of 100 and 500 m (control) away from the bank of the river. Samples were analysed for pH, EC, NO3, TOC; Zn, Na, K, Ca, Mg, Cu, Fe, Cd, Cr, Ni, and Pb using standard analytical methods. The results were subjected to both differential and inferential statistics using statistical package (SPSS 22.0 version). Subsequently, the data were compared with Earth crust values. The soil pollution was evaluated using pollution, ecological risk, and geo-accumulation index. Cr (50.43), Ni (29.47), and Cu (104.10) mg/kg at 100 m were higher than their controls; (12.09), (8.14), and (86.06) mg/kg respectively, but lower than their respective Earth crusts; (100), (80) except (50) mg/kg. The soil was moderately polluted with pH (1.15), Na (3.00), K (2.11), Mg (1.87), Ca (1.26) and Cu (1.21); considerably polluted with EC (3.82), TOC (3.39), and Ni (3.62); and very highly polluted with Fe (8.26). Fe (711.73) had a very high ecological risk. The Geo – accumulation index was moderately - strongly polluted with Zn (2.61), and very strongly polluted with pH (5.37), EC (14.90), NO3 (9.66), Na (15.41), K (11.31), Mg (9.51), Ca (17.08), Fe (15.32), Cu (12.54), Cr (8.67), and Ni (7.32). The soil was polluted. and urgently needs reclamation for Garden Park (relaxation).
Afficher plus [+] Moins [-]Performance Evaluation of Different Soil Media by Batch-Operated Pilot-Scale Horizontal Subsurface Flow Constructed Wetlands for Wastewater Treatment
2023
Kumar Swarnakar, Arvind | Bajpai, Samir | Ahmad, Ishtiyaq
Constructed wetland systems (CWs) are low-cost natural treatment systems for various types of influents. Although mainly the natural wetlands are soil-based, the constructed wetlands have been traditionally built using aggregate media. The performance of four types of available soils in Chhattisgarh was studied as the filter media in the horizontal subsurface flow-constructed wetland (HSFCW). Fourteen pilot-scale CW units with different soil types (entisol, vertisol, alfisol, inceptisol, and stone aggregate) and plant types (Canna indica and Typha latifolia) were used to treat domestic wastewater (WW). One set of each soil base reactor was planted with Canna indica and Typha latifolia, and one was kept blank (unplanted). All soils and plants are easily available.The reactors received primary wastewater in batch loads with WW loading for six hours to maintain aerobic conditions. The residence time of WW was 48 hours, and the applied hydraulic loading rate (HLR) was based on soil and aggregate. According to the findings, the planted HSFCW was more effective than the unplanted system. The results show that the wetland constructed on the treatment efficiency of the soil base has excellent potential to treat WW, with both plants.
Afficher plus [+] Moins [-]Anthropogenic share of metal contents in soils of urban areas
2018
Fazeli, G. | Karbassi, A.R. | khoramnejadian, Sh. | Nasrabadi, T.
In the present investigation, 41 soil samples were subjected to single step chemical partitioning to assess the lithogenic and non-lithogenic portions of metals in Tehran's soils. The share of various studied metals in the anthropogenic portion ranges from as low as 0.2% to as high as 85% of bulk concentration. Geo-accumulation index (Igeo) showed that Cd falls within "heavily contaminated" soils. It might be inferred that Ni, Cu, Cr, Zn, Co and Ca fall within "Deficient to minimal" class in accordance with enrichment factor (EF) classification.. Enrichment factor values (to some extents) match with the chemical partition studies results (except for Ni and Cr). The very low Ca content of soil samples could be indicative of low biological productivity in the Tehran's soil. Also the very low concentrations of Mn could be indicative of reducing environment in soils of Tehran.
Afficher plus [+] Moins [-]Assessment of Concentration and Distribution of Contaminants Using Magnetic Susceptibility Measurements
2023
Anis, Naushi | Kumar, Arun | Arya, Ajay
Magnetic properties are used throughout the world to measure the concentration of (ferri) magnetic minerals in soil, sediment and dust. These minerals in soil come from a variety of sources, including air-borne particulate pollution, parent rock and paedogenesis. Changes in the content of magnetic minerals, as well as their spatial and vertical distribution in soil profiles are caused by human activity. Magnetic minerals are distinguished by their affinity for other elements found in soil, such as heavy metal. As a result, magnetic susceptibility has been widely used as an approximation of heavy metal contamination in soil. The current study was conducted in a tropical deciduous forest in Central Uttar Pradesh, namely the kukrail reserve forest in Lucknow to assess heavy metal contamination levels caused by various anthropogenic activities and to confirm the utility of using MS surveying in these types of studies. The current study was conducted at two sites viz. agricultural area and forest area because these sites are the most contaminated ones. Significant correlation between heavy metal concentration and magnetic susceptibility with p<0.005 is noticed for Co, Cr, Pb, Zn, Cu and Fe of agricultural area. Similarly in forest area significant correlation exists between Cr, Ni, Pb and Zn. The χLF values show a significant correlation with the concentration of heavy metals except for Cu and Cr in forest area and Pb and Zn in agricultural area. In comparison to the methodologies of chemical analysis, the χLF measurement techniques provide us with lower cost and less time consuming method for identification of possible soil pollution.
Afficher plus [+] Moins [-]Analytical Methods for Extraction, Determination and Degradation of Diazinon in Soil Samples
2023
Dehghan Abkenar, Shiva | khakipour, Nazanin | Ganjali, Mohammad Reza
Diazinon is an organophosphorus insecticide that was widely used in agriculture to control pests on crops. It acts as an acetylcholinesterase inhibitor, which means that it interferes with the normal functioning of the nervous system of insects, leading to their death. Diazinon can also have an impact on human health and the environment, as it can contaminate water and soil and pose a risk to non-target species, including humans and animals. This review paper shows the progress made in the last years in analytical methods applied for the purpose of extraction, detection and degradation of Diazinon as an important environmental pollutant. A variety of sampling and analytical methods have been developed to measure diazinon and its metabolites in different media. The most popular methods for the identification and analysis of Diazinon are liquid and gas chromatography, liquid-liquid extraction, and solid-phase extraction (SPE). The focus of this review is on the identification, measurement, and elimination of diazinon as a major soil pollutant. It begins with a discussion of analytical techniques, followed by an examination of methods for removing diazinon from soil.
Afficher plus [+] Moins [-]Investigating the Potential Response of Jute Varieties for Phytoremediation of Arsenic Contaminated Soil
2022
Nahar, Nazneen | Gani, Md Nasimul | Huq, SM Imamul
A pot experiment was carried out in the green house of Bangladesh Jute Research Institute (BJRI), Dhaka to study the response of jute (Corchorus capsularies and Corchorus olitorius) to the accumulation of As from soil to plants when various rates of As were applied. In the experiment, four treatments of arsenic (control, 10, 20 and 40 mg/kg) were applied. The salt sodium meta-arsenite (NaAsO2) was used as a source of As. Three jute varieties of CVL-1, 0-9897 and OM-1 were used. CVL-1 variety is As sensitive whereas the 0-9897 and OM-1 varieties appeared to be As tolerant and OM-1 takes up the highest amount of As. Arsenic will be ingested into the body exceeding the maximum allowable daily limit (0.22mg/kg per day) through the consumption of 100g of jute leaves of these three varieties per day. Accumulation of As at 10 and 40 mg/kg treatment, the maximum was observed at 52 days harvest for CVL-1 while for the other two treatments, the maximum was observed at 42 days of growth. In the case of 0-9897 and OM-1 varieties, overall the maximum accumulation of As was observed at 42 days of growth at 40 mg/kg treatment.
Afficher plus [+] Moins [-]Health Risk Assessment of Heavy Metals in the Soil of Angouran Mineral Processing Complex in Iran
2021
Sheikhi Alman Abad, Z. | Pirkharrati, H. | Mojarrad, M.
This study aims at assessing the health-related risk of As, Co, Cr, Ni, and Cu in the soil around Angouran Mineral Processing Complex (AMPC), due to environmentally sensitive nature of the area, having agricultural activities, habitats of animal and plant species, and industrial activities integrated with each other. Soil samples have been collected from 74 points (0-20 cm) of the area and concentrations of heavy metals have been measured, using ICP-OES. The Geoaccumulation Index (Igeo), Enrichment Factor (EF), and Integrated Pollution Index (IPI) have been used to examine the pollution level. Moreover, hazard indices (HI), hazard quotient (HQ) and cancer risk (CR) have been utilized to assess the non-carcinogenic and carcinogenic health risks of heavy metals. The average concentration of heavy metals indicates that metals’ concentration in the soil have increased in the following order: Cr = Ni> As> Cu> Co. Results from Igeo, Ef, and IPI show that As and Ni are placed in the very high pollution category. The non-carcinogenic risk of dermal absorption (adults = 1.30 E + 00, children = 1.35 E + 00) of Cr and Co polluted particles turn out to be very high. In addition, the risk of cancer as a result of the ingestion of As- and Cr-contaminated soil particles is high in both of age groups, with children being 68% more likely to be at risk of cancer than adults. Therefore, actions such as soil remediation should be done to reduce the risk of exposure and protect the health of the residents, especially the farmers.
Afficher plus [+] Moins [-]Natural radioactivity in virgin and agricultural soil and its environmental implications in Sungai Petani, Kedah, Malaysia
2015
Ahmad, Nisar | Jaafar, Mohamad | Alsaffar, Mohammed
A study on natural radioactivity in virgin and agricultural soil samples collected from Sungai Petani was conducted using high-purity germanium. The mean activity concentrations of 226Ra, 232Th, and 40K in virgin soils were 51.06±5.83, 78.44±6.42, and 125.66±7.26 Bq kg−1, respectively, while those in agricultural soils were 80.63±5.78, 116.87±7.87, and 200.66±18.24 Bq kg−1, respectively. The corresponding activity concentrations in agricultural soils were higher than those in virgin soils and those reported for other countries of the world. The average values of radium equivalent activity (Raeq), external hazard index (Hex), internal hazard index (Hin), outdoor annual effective doses (Eout), and indoor annual effective doses (Ein) in agricultural soils were 258.38 Ba kg−1, 0.708, 0.925, 0.162 mSv y−1, and 0.669 mSv y−1, respectively. The average values of outdoor external dose (Dout) and indoor absorbed dose (Din) rate in agricultural soils were 116.04 and 218.46 nGy h−1, respectively, which were higher than the permissible limit. Soil with Hex and Hin less than unity are suitable for use as building materials and in agriculture.
Afficher plus [+] Moins [-]Bioremediation: Assessment of Growth Attributes of Maize (ZEA MAYS) on Crude oil-Polluted Soils
2024
Agbor, Reagan | Asuquo, Eno | Ivon, Ettah | Ellen, Simon
Environmental pollution has posed a major threat to terrestrial, aquatic, and marine ecosystems, thereby affecting microflora and micro-fauna populations. This study assessed the growth attributes of maize plants on crude oil-polluted soils amended with agro-wastes. Six kilograms each of composite soil sample was weighed and transferred into one hundred and fifty labeled plastic buckets with drainage holes for soil aeration and spiked with 300mls each of crude oil, allowing for 14 days of soil acclimatization. Soil amendments such as groundnut husks, cassava peels, empty fruit bunch of oil palm, and maize cob powder were applied and allowed for 90 days. Maize seeds were sowed, while periodic data were collected and subjected to a three-way ANOVA. The result obtained revealed that maize seeds grown on agro-wastes treated and pristine control soils show early seed germination than the crude oil-polluted control soil. The plant height obtained for GnH14P + MaC14P at 10% was the highest with a mean (of 152.81cm2), and the leaf area of the maize from soil treated with GnH14P + EFBOP14P at 10% had the highest mean (756cm2), the leaf length of maize from soil treated with GnH14P + CasP14P at 3%, 6%, and 10% was the highest with mean ranging (54-97 cm2) with no significant difference in mean values obtained. The stem girth, number of leaves, and leaf width were generally improved in the bio-remediated soils. The result for the yield performance of maize shows that the days to flowering were shortened in the bio-remediated soil compared to the prolonged flowering days observed in the crude-oil polluted control. The number of seeds per cob was high in the bio-remediated soils while no seed was obtained in the crude-oil-polluted control soils. It can be concluded that the ameliorated treatment with the agro-wastes improves the performance of maize plants in crude oil-polluted soils.
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