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Emission characteristics and health risk assessment of VOCs from a food waste anaerobic digestion plant: A case study of Suzhou, China
2020
Zheng, Guodi | Liu, Junwan | Shao, Zhuze | Chen, Tongbin
The process of anaerobic digestion in food waste treatment plants generates a large amount of volatile organic compounds (VOCs). Long-term exposure to this exhaust gas can pose a threat to the health of workers and people living nearby. In this study, VOCs emitted from different working units in a food waste anaerobic digestion plant were monitored for a year. Variations in VOCs emitted from each unit were analyzed and a health risk assessment was conducted for each working unit. The results show that the concentration of VOCs in different units varied greatly. The highest cumulative concentration of VOCs appeared in the hydrothermal hydrolysis unit (3.49 × 10⁴ μg/m³), followed by the sorting/crushing room (8.97 × 10³ μg/m³), anaerobic digestion unit (6.21 × 10² μg/m³), and biogas production unit (2.01 × 10² μg/m³). Oxygenated compounds and terpenes were the major components of the emitted VOCs, accounting for more than 98% of total VOC emissions. The carcinogenic risk in the plant exceeded the safety threshold (ILCR<1 × 10⁻⁶), while the non-carcinogenic risk was within the acceptable range (HI < 1). The carcinogenic risk from the hydrothermal hydrolysis unit was the highest, reaching 4.4 × 10⁻⁵, and was labeled as “probable risk.” The carcinogenic risk at the plant boundary was 1.2 × 10⁻⁵, indicating exhaust gases can cause a health threat to neighbors. Therefore, management VOCs in anaerobic digestion plants should receive more attention, and employees should minimize the time they spend in the hydrothermal hydrolysis unit.
Afficher plus [+] Moins [-]Decreased rates of terpene emissions in Ornithopus compressus L. and Trifolium striatum L. by ozone exposure and nitrogen fertilization
2014
Llusia, Joan | Bermejo-Bermejo, Victoria | Calvete-Sogo, Héctor | Peñuelas, Josep
Increasing tropospheric ozone (O3) and nitrogen soil availability (N) are two of the main drivers of global change. They both may affect gas exchange, including plant emission of volatiles such as terpenes. We conducted an experiment using open-top chambers to analyze these possible effects on two leguminous species of Mediterranean pastures that are known to have different O3 sensitivity, Ornithopus compressus and Trifolium striatum. O3 exposure and N fertilization did not affect the photosynthetic rates of O. compressus and T. striatum, although O3 tended to induce an increase in the stomatal conductance of both species, especially T. striatum, the most sensitive species. O3 and N soil availability reduced the emission of terpenes in O. compressus and T. striatum. If these responses are confirmed as a general pattern, O3 could affect the competitiveness of these species.
Afficher plus [+] Moins [-]Biogenic volatile organic compounds from the urban forest of the Metropolitan Region, Chile
2013
Préndez, Margarita | Carvajal, Virginia | Corada, Karina | Morales, Johanna | Alarcón, Francis | Peralta, Hugo
Tropospheric ozone is a secondary pollutant whose primary sources are volatile organic compounds and nitrogen oxides. The national standard is exceeded on a third of summer days in some areas of the Chilean Metropolitan Region (MR). This study reports normalized springtime experimental emissions factors (EF) for biogenic volatile organic compounds from tree species corresponding to approximately 31% of urban trees in the MR. A Photochemical Ozone Creation Index (POCI) was calculated using Photochemical Ozone Creation Potential of quantified terpenes. Ten species, natives and exotics, were analysed using static enclosure technique. Terpene quantification was performed using GC-FID, thermal desorption, cryogenic concentration and automatic injection. Observed EF and POCI values for terpenes from exotic species were 78 times greater than native values; within the same family, exotic EF and POCI values were 28 and 26 times greater than natives. These results support reforestation with native species for improved urban pollution management.
Afficher plus [+] Moins [-]Investigation of polycyclic aromatic hydrocarbons (PAHs) and cyclic terpenoid biomarkers in the sediments of fishing harbors in Taiwan
2015
Kao, Nien-Hsin | Su, Ming-Chien | Fan, Jheng-Rong | Yen, Chih-Chun
Three fishing harbors were investigated to study the polycyclic aromatic hydrocarbons in the sediments and trace possible anthropogenic sources by identification of cyclic terpenoid biomarkers. Seventeen terpanes, 10 steranes and 10 bicyclic sesquiterpanes in the marine diesel and the three kinds of lubricants that are mainly used by fishing boats were identified and quantified. Eighteen biomarker diagnostic ratios are suggested and the correlation coefficients among the lubricants and sediment samples have the R2 value greater than 0.73. Analyzed 16 PAHs in the sediment shows non-normal distributions and the Kruskal Wallis Test shows the significant differences (p value smaller than 0.05) with the greatest variability in benzo[g,h,i]perylene which more than 84% of the effective size (E.S.) is accounted. X-ray Photoelectron Spectroscopy (XPS) analysis was applied and the Kruskal Wallis Test shows a significant difference (p value smaller than 0.05) among certain atoms with the effective size greater than 60%.
Afficher plus [+] Moins [-]Effects of ozone concentrations on biogenic volatile organic compounds emission in the Mediterranean region
1999
Penuelas, J. | Lluisa, J. | Gimeno, B.S. (Centre de Recerca Ecologica i Aplicacions Forestals (CREAF), Facultat de Ciencies, Universitat Autonoma de Barcelona, 08193 Bellaterra, Barcelona (Spain))
Multifaceted role of natural sources for COVID-19 pandemic as marine drugs
2022
Rahman, Md Mominur | Islam, Md Rezaul | Shohag, Sheikh | Hossain, Md Emon | Shah, Muddaser | shuvo, Shakil khan | Khan, Hosneara | Chowdhury, Md Arifur Rahman | Bulbul, Israt Jahan | Hossain, Md Sarowar | Sultana, Sharifa | Ahmed, Muniruddin | Akhtar, Muhammad Furqan | Saleem, Ammara | Md. Habibur Rahman,
COVID-19, which is caused by the novel severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), has quickly spread over the world, posing a global health concern. The ongoing epidemic has necessitated the development of novel drugs and potential therapies for patients infected with SARS-CoV-2. Advances in vaccination and medication development, no preventative vaccinations, or viable therapeutics against SARS-CoV-2 infection have been developed to date. As a result, additional research is needed in order to find a long-term solution to this devastating condition. Clinical studies are being conducted to determine the efficacy of bioactive compounds retrieved or synthesized from marine species starting material. The present study focuses on the anti-SARS-CoV-2 potential of marine-derived phytochemicals, which has been investigated utilizing in in silico, in vitro, and in vivo models to determine their effectiveness. Marine-derived biologically active substances, such as flavonoids, tannins, alkaloids, terpenoids, peptides, lectins, polysaccharides, and lipids, can affect SARS-CoV-2 during the viral particle’s penetration and entry into the cell, replication of the viral nucleic acid, and virion release from the cell; they can also act on the host’s cellular targets. COVID-19 has been proven to be resistant to several contaminants produced from marine resources. This paper gives an overview and summary of the various marine resources as marine drugs and their potential for treating SARS-CoV-2. We discussed at numerous natural compounds as marine drugs generated from natural sources for treating COVID-19 and controlling the current pandemic scenario.
Afficher plus [+] Moins [-]An assessment of growth, floral morphology, and metabolites of a medicinal plant Sida cordifolia L. under the influence of elevated ozone
2021
Ansari, Naushad | Agrawal, Madhoolika | Agrawal, Shashi Bhushan
Tropospheric ozone (O₃) is a major secondary air pollutant and greenhouse gas, and its impact on growth, yield, and its quality is well established in the case of crop plants. However, the effects of tropospheric O₃ have not been comprehensively studied on medicinal plants. Therefore, a field study was planned on a medicinally important Sida cordifolia L. plant (commonly known as country mallow or Bala) to assess the expected changes on the morphology, growth, and leaf injury under elevated O₃ (ambient + 20 ppb) by using open-top chambers (OTCs) at 30, 60, and 90 days after treatment (DAT), while leaf and root metabolites were observed at 60 DAT. At all the growth stages, significant leaf damage was recorded as foliar injury symptoms. Most of the growth parameters also showed significant reductions at all the growth stages. Plants under elevated O₃ showed a significant negative impact on most of the reproductive parts of the plant. Leaf weight ratio (LWR) showed significant increment at early stages while reduced at 90 DAT; however, root shoot ratio (RSR) showed a significant reduction at 60 DAT. The majority of the steroid metabolites showed an increase in root and leaves under elevated O₃, while terpenes showed variable response. Due to O₃ stress, most of the major metabolites showed an increase possibly due to their role in defense and other metabolic activities. Based on the outcomes, it is concluded that the future increase in the levels of tropospheric O₃ will impact a significant effect on important metabolites of medicinal plants growing in tropical countries like India.
Afficher plus [+] Moins [-]Proximate composition and spatio-temporal heterogeneity of phytochemicals in Agave sisalana Perrine (sisal) adapted in different agro-ecological zones of Punjab, Pakistan
2022
Shahzad, Sobia | Hussain, Mumtaz | Munir, Hassan | Arfan, Muhammad
Exploring extractable phytochemicals from locally adapted sisal plant vegetation vary seasonally at different locations. This study elaborated proximate composition and phytochemical heterogeneity in sisal due to varying environmental conditions analyzed from five districts, i.e., Chakwal, Khushab, Rawalpindi, Faisalabad, and Layyah in Punjab, Pakistan. Extensive surveying and plant sampling across 2 years 2017–2018 and 2018–2019, during mid-spring, summer, autumn, and winter seasons were carried out for understanding the seasonal impact on sisal. The present study was designed in a randomized complete block design (RCBD) and analyzed considering seasonal, yearly, and locational impact. The spatial differences in phytochemicals concentration were strongly associated with environmental conditions prevailing in different seasons. Autumn season reflected saponins, tannins, and flavonoids in higher concentrations during 2018–2019 while steroids and terpenoids were higher during spring 2018–2019. Spatio-temporal variations in the proximate analysis were more apparent in different samples collected from different districts. Data recorded for the Khushab district and autumn season reflected the higher composition of a proximate analysis and phytochemical contents as compared to other seasons. Overall, the spatial differences in phytochemicals concentration were strongly associated with soils and environmental conditions prevailing in different seasons in selected districts.
Afficher plus [+] Moins [-]Heavy Metal Uptake by Herbs. V. Metal Accumulation and Physiological Effects Induced by Thiuram in Ocimum basilicum L
2017
Adamczyk-Szabela, Dorota | Romanowska-Duda, Zdzisława | Lisowska, Katarzyna | Wolf, WojciechM.
Basil (Ocimum basilicum L.) is extensively cultivated as either an important spice and food additive or a source of essential oil crucial for the production of natural phenylpropanoids and terpenoids. It is frequently attacked by fungal diseases. The aim of the study was to estimate the impact of thiuram contact time on the uptake of manganese, cobalt, nickel, copper, zinc, cadmium, and lead by Ocimum basilicum L. The relevant plant physiological parameters were also investigated. Two farmland soils typical for the Polish rural environment were used. Studies involved soil analyses, bioavailable, and total forms for all investigated metals, chlorophyll content, and gas exchange. Atomic absorption spectrometry was used to determine concentration of all elements. Analysis of variance proved hypothesis that thiuram treatment of basil significantly influences metal transfer from soil and their concentration in roots and aboveground parts. This effect is mostly visible on the 14th day after the fungicide administration. Thiuram modifies mycoflora in the rhizosphere zone and subsequently affects either metal uptake from the soil environment or their further migration within the basil plant. Notable, those changes are more evident for basil planted in mineral soil as compared to organic soil with higher buffering capacity.
Afficher plus [+] Moins [-]Anticancer properties of medicinal plants and their bioactive compounds against breast cancer: a review on recent investigations
2022
Khan, Muhammad Idrees | Bouyahya, Abdelhakim | Hachlafi, Naoufal E. L. | Menyiy, Naoual El | Akram, Muhammad | Sultana, Sabira | Zengin, Gokhan | Ponomareva, Lilya | Shariati, Mohammad Ali | Ojo, Oluwafemi Adeleke | Dall’Acqua, Stefano | Elebiyo, Tobiloba Christiana
Breast cancer (BC) is one of the most common and recurring diseases and the second leading cause of death in women. Despite prevention, diagnostics, and therapeutic options such as radiation therapy and chemotherapy, the number of occurrences increases every year. Therefore, novel therapeutic drugs targeting specifically different checkpoints should be developed against breast cancer. Among drugs that can be developed to treat breast cancer, natural products, such as plant-derived compounds, showed significant anti-breast cancer properties. These substances belong to different chemical classes such as flavonoids, terpenoids, phenolic acids, and alkaloids. They exert their in vitro and in vivo cytotoxic activities against breast cancer cell lines via different mechanisms, including the inhibition of extrinsic and intrinsic apoptotic pathways, the arrest of the cell cycle, and the activation of autophagy. Moreover, they also exhibit anti-angiogenesis and antimetastatic action. Moreover, chemoprevention effects of these bioactive compounds were signaled only for certain drugs. Therefore, the aim of this review is to highlight the pharmacological actions of medicinal plants and their bioactive compounds on breast cancer. Moreover, the role of these substances in breast cancer chemoprevention was also discussed.
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