Because of the pinch of air pollution on human health and its environment, it has become necessary to monitor and map out the peaks and lows threat places of air pollution in different land use across a city. In this regard, air pollution exposure mapping of Kano metropolis based on land use classifications namely industrial, residential, commercial and institutional was carried out for interpretive and assessment of health hazard associated with the selected pollutants. The observations for ambient air quality parameters (CO, SO2, H2S, NO2, and PM10) monitored with portable digital air pollution detecting devices for creation of data. Geographic Information Systems (GIS) technique was applied to create spatial distribution maps of urban air quality of the metropolitan area. The results of pollution index map of ArcGIS extrapolation indicated that neighbourhoods in the vicinity of Bompai and Sabon Gari industrial and commercial zones, respectively were found to be highly exposed and liable to ailments associated with air pollution, while places nearby Dorawa and School of Technology were air pollution-ease zones but could experience bioaccumulation over long exposure time. Therefore, the study reveals that variability of air quality was strongly related to predominant land use in particular areas within the metropolis and could help in estimate and valuation of likely health challenges associated with poor air quality due to air pollution. Besides, the observed spatial variation for air quality could serve as hot spot identifier and as an informant for rational decision on air quality control strategies for environmental management.

Exposure to airborne particulates is a major occupational hazard especially for outdoor workers who spending time outdoors at ground level getting exposed to traffic fumes and roadside dust. Aim of this study was to assess respiratory health symptoms and determine the change of lung functions of the roadside vendors and its association with traffic-related exposures and their working experience. A cross-sectional study was conducted in key market places of Kolkata – Gariahat (GH), Esplanade-Park Street (EP), Shyambazar-Hatibagan (SH) and Behala (BE). Particulate (PM10 and PM2.5) levels and meteorological parameters (wind speed, temperature and relative humidity) were monitored in the morning, afternoon and night over the period of October 2019 to February 2020. Lung function status (FEV1, FVC, FEV1/FVC ratio and PEF) was measured for 111 purposively selected participants. PM concentration was observed higher in the morning and night peak hours for all sites. At SH area the average occupational exposure level for PM10 and PM2.5 were observed as 1502.22 μg/m3h and 684.01 μg/m3h. Percentage predicted FEV1 (%FEV1) of street vendors was found decreasing with their work experience and the worst-case scenario was observed in the EP area, with the corresponding value being 70.75%, 49.15% and 47.3% for less than 10 years, 10 to 20 years and more than 20 years participation respectively. The higher particulate burden was observed to have declining lung function status of the street vendors. A strong policy framework should be adopted to improve outdoor working environment for outdoor workers.

Discarded micro/nano-plastic inputs into the environment are emerging global concerns. Yet the quantification of micro/nanoplastics in complex environmental matrices is still a major challenge, notably for soluble ones. We herein develop in-laboratory built nanostructures (zinc oxide, titanium oxide and cobalt) coupled to mass spectrometry techniques, for picogram quantification of micro/nanoplastics in water and snow matrices, without sample pre-treatment. In parallel, an ultra-trace quantification method for micro/nanoplastics based on nanostructured laser desorption/ionization time-of-flight mass spectrometry (NALDI-TOF-MS) is developed. The detection limit is ∼5 pg for ambient snow. Soluble polyethylene glycol and insoluble polyethylene fragments were observed and quantified in fresh falling snow in Montreal, Canada. Complementary physicochemical studies of the snow matrices and reference plastics using laser-based particle sizers, inductively coupled plasma tandem mass spectrometry, and high-resolution scanning/transmission electron microscopy, produced consistent results with NALDI, and further provided information on morphology and composition of the micro/nano-plastic particles. This work is promising as it demonstrates that a wide range of recyclable nanostructures, in-laboratory built or commercial, can provide ultra-trace capability for quantification for both soluble polymers and insoluble plastics in air, water and soil. It may thereby produce key missing information to determine the fate of micro/nanoplastics in the environment, and their impacts on human health.

Urban activities intensify air pollution by increasing the amount of particulate matter (PM). The trees collect PM by adsorption on the leaf surface and simultaneously absorb inorganic components. In this research, we investigated the potential of the black pine as bioindicator of road traffic emissions in Cluj-Napoca (Romania). We defined three sites types with different exposure to the road traffic (streets, outskirts, parks) and a control site far from the city. We quantified 17 inorganic components (Al, B, Ba, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, Sr, Zn) by MP-AES (microwave-plasma atomic emission spectroscopy) technique in the one-year-old needles and we identified the best candidates for biomonitoring purposes. The concentration of Ba, Cr, Cu and Fe showed the most sensitive variations with the road traffic intensity. While in the streets the Ba, Cu and Fe increased by 2.8–3.5 times in relation to the control site, the Cr varied in the highest degree exhibiting ratios of 2.2 (parks), 3.3 (outskirts) and 6.3 (streets). The success of these elements lies in several characteristics: they are closely related to non-exhaust emissions, they are readily absorbed through the leaves rather than the roots, and they tend to accumulate in the needles instead of being relocated to other organs. The street maintenance activities caused considerable accumulation of Na in the trees from the roadsides, but had no impact over the trees from the parks. The elements originating mainly in the re-suspended urban dust (Ni, Pb, Sr) equally affected the pines from the streets and parks.