Emissions of volatile organic compounds (VOCs) were studied from three heavily polluted rivers (Huijiang, Nancun, and Zengbian Rivers) in Guangzhou, South China. A total of 49 species of VOCs were identified. Nancun River had the highest concentration of total VOCs (TVOCs), which ranged from 1,467 to 5,522 μg m⁻³. Trichloroethene, benzene, toluene, ethylbenzene, m/p-xylene, o-xylene, styrene, and 1,3,5-trimethylbenzene were the main pollutants. The levels of VOCs evaporated from the three rivers exhibited different patterns. Correlations between the concentrations of major VOCs were established and found to be statistically significant, except for o-xylene. The ratios of toluene/benzene, ethylbenzene/benzene, and xylene/benzene were estimated and found to be higher than widely reported in the literature. TVOC fluxes in the three rivers were calculated to be the range from 24.8 to 765 μg m⁻² h⁻¹. This study provides a regional background for the emission inventories of VOCs from heavily polluted rivers in southern China and provides resource managers with important information to guide remediation and policy concerning VOC emissions to the environment.

It is known that peat can be a potential adsorbent to remove contaminants from wastewaters. When raw peat is used, many limitations exist: Natural peat has a low mechanical strength, high affinity for water, poor chemical stability and tendency to shrink and/or swell. In this work, in order to obtain a more manageable substrate, to be used as adsorbent, peat was entrapped in calcium alginate beads. Box–Behnken factorial design was used to obtain the best condition for the immobilization of peat in calcium alginate beads. The independent variables studied were: peat concentration, sodium alginate concentration and calcium chloride concentration, whereas the dependent variables studied were based on the variation of colour parameters after the treatment of vinasses with entrapped peat. High colour reductions can be achieved using entrapped peat formulated by mixing 2 % of peat with 3 % of sodium alginate and pumped it on calcium chloride (0.05 M).

Water and sediment samples were collected along river transects at three artisanal gold mining areas in southern Ecuador: Nambija, Portovelo-Zaruma, and Ponce Enriquez. Samples were analyzed for a suite of major and trace elements, including filtered/unfiltered water samples and stream flow measurements to determine dissolved/particulate loads. Results show that the Q. Calixto, Calera, and Siete rivers (corresponding to Nambija, Portovelo-Zaruma, and Ponce Enriquez mining areas, respectively) have substantial trace element contamination due to mining inputs. Dissolved concentrations were elevated at Calera and Siete relative to Q. Calixto, possibly reflecting the input of soluble cyano-metal complexes in mining zones where cyanidation is used in ore processing. A negative correlation was found between MeHg:THg ratios and pH, indicating an inverse relationship of mercury methylation with cyanidation (since cyanidation increases water pH). This was the first comprehensive study to examine an extensive suite of trace elements in both water and sediment at the three main gold mining areas of southern Ecuador, including dissolved and particulate loads, and the first study to report MeHg concentrations in the mercury-contaminated rivers.

This paper addresses the oxidation by ultraviolet radiation of methylparaben, a ubiquitous and suspicious preservative which is massively added to cosmetics and personal care products. Experiments included pH and temperature variation, as well as several experimental conditions such as presence/absence of hydrogen peroxide, titanium dioxide, or some different water matrix (surface water or ground water). Results were evaluated under the line source spherical emission model, so quantum yield was the adequate target variable for explaining the process. A modified Arrhenius correlation including pH level was used for modelling the whole system.

This study assessed the effect of ambient air pollution on leaf characteristics of white willow, northern red oak, and Scots pine. Willow, oak, and pine saplings were planted at sixteen locations in Belgium, where nitrogen dioxide (NO2), ozone (O3), sulfur dioxide (SO 2), and particulate matter (PM10) concentrations were continuously measured. The trees were exposed to ambient air during 6 months (April-September 2010), and, thereafter, specific leaf area (SLA), stomatal resistance (R s), leaf fluctuating asymmetry (FA), drop contact angle (CA), relative chlorophyll content, and chlorophyll fluorescence (F v/F m) were measured. Leaf characteristics of willow, oak, and pine were differently related to the ambient air pollution, indicating a species-dependent response. Willow and pine had a higher SLA at measuring stations with higher NO2 and lower O3 concentrations. Willow had a higher R s and pine had a higher F v/F m at measuring stations with a higher NO2 and lower O 3 concentrations, while oak had a higher F v/F m and a lower FA at measuring stations with a higher NO2 and lower O3 concentrations. FA and R s of willow, oak, and pine, SLA of oak, and CA of willow were rather an indicator for local adaptation to the micro-environment than an indicator for the ambient air pollution. © 2013 Springer Science+Business Media Dordrecht.

To evaluate cadmium (Cd) remediation capacity of gray poplar (Populus × canescens Sm. referred to the hybrid of Populus tremula L. × Populus alba L.), the glasshouse experiment was conducted in hydroponics, and the effects of Cd (0, 10, 30, 50, and 70 μM) on plant growth as well as Cd uptake and translocation were investigated. The growth rate of all tissues in P. × canescens decreased slowly with an increase in Cd concentrations. Among different tissues, the root exhibited the highest level of bio-concentration factor (BCF), followed by leaves, bark, and wood. BCFs in bark and wood significantly decreased with an increase in Cd concentrations. The translocation factor in different tissues firstly increased and then declined with an increase in Cd concentrations, respectively. The translocation factor in different tissues decreased slowly with an increase in Cd concentrations. Cd accumulation rates significantly increased and reached about sevenfold the level after 70 μM than that observed after 0 μM (control) for 28 days. These results indicated that P. × canescens have good tolerance against Cd stress, varying in Cd accumulation and translocation. These properties need to be taken into account in selecting species for the phytoremediation of orefield.

The disposal of olive mill wastes (OMW) is considered as a major environmental problem worldwide, but especially for Mediterranean countries. Disposal in evaporation ponds or directly on soil is a common practice, which causes serious damages to soil and to the environment. The present study was performed in the framework of the LIFE project “Strategies to improve and protect soil quality from the disposal of Olive Mill Wastes in the Mediterranean region-PROSODOL” and one of its main objectives was the identification of appropriate soil parameters that could be used as soil indicators to assess soil quality at OMW disposal areas. For this, a well-designed soil sampling strategy was developed and implemented in Crete, South Greece at five OMW disposal areas. Many soil parameters were monitored bimonthly for a year. After statistical evaluation, eight soil parameters were selected as being appropriate soil indicators for OMW disposal areas, i.e., electrical conductivity, pH, organic matter, polyphenols, total N, exchangeable K, available P, and available Fe. Although many researchers have extensively studied the effect of OMW on soil quality, yet the identification of soil indicators to assess and monitor soil quality is an innovative issue and has never been studied before.

This study was aimed to examine the efficiency of a novel bacterial consortium on the reduction of toxic hexavalent chromium [Cr(VI)] to non-toxic trivalent Cr [Cr(III)]. Six Cr(VI)-resistant bacteria (IS1-IS6) were isolated from a tannery waste disposal site at Mount Barker, South Australia, of which three viz., IS1, IS2 and IS3 were selected based on Cr(VI) reduction ability in minimal salt medium. The isolates were identified as Bacillus endophyticus (IS1), Microbacterium paraoxydans (IS2) and Bacillus simplex (IS3) by 16S rRNA gene sequencing. All three isolates were able to tolerate chromium (Cr(VI), 300–400 mg L ⁻¹), arsenic (As(V), 1,000 mg L ⁻¹), copper (Cu(II), 300–400 mg L ⁻¹) and lead (Pb(II), 1,000 mg L ⁻¹). The isolates were evaluated both as an individual and as a consortia for Cr(VI) reduction in minimal salt medium and storm water, both spiked with 100 mg Cr(VI) L ⁻¹. In both cases, the rate of Cr(VI) reduction was found to be significantly higher in the bacterial consortium inoculation ( t_½ = 8.45 for minimal salt medium; 6.02 h for storm water), compared to inoculation with individual isolates ( t_½ = 53.3–115.5 h for minimal salt medium; 8.77–9.76 h for storm water). The rate of Cr(VI) reduction in both minimal salt medium and storm water was found to be higher in bacterial consortium inoculation (IS1 + IS2 + IS3) than in individual isolate inoculation. This experiment demonstrated that bacterial consortium prepared by using B. endophyticus, M. paraoxydans and B. simplex was more effective in Cr(VI) detoxification than application of individual bacterium. This experiment also proved that a bacterial consortium was more effective in Cr(VI) detoxification than the application of individual bacterial strain.

Acid mine drainage (AMD) has long been a significant environmental problem that impairs water resources in historic or current mining industries throughout the world. One of the methods using passive treatment system at low cost to remove metals from solution involves the use of clays. The ability of three different adsorbents (montmorillonite K-10, bentonite (NT-25), and hydrotalcite (HT)) to remove Fe and Mn from aqueous solutions and acid mine drainage samples has been studied at different optimized conditions such as pH, amount of adsorbent and contact time. Flame atomic absorption spectrometer (FAAS) was used for measuring Fe and Mn concentrations. Langmuir and Freundlich isotherms were applied and isotherm coefficients were computed. A kinectic study was also developed for HT using the first order, second order and intraparticle diffusion models. A great amount of clay (more than 100 mg) and also contact times higher than 60 min had also no influence in the adsorption capacity for all adsorbents. HT was found to be the best among the studied clays removing more than 90 % of Fe and Mn for all AMD samples investigated. Moreover, the maximum adsorption capacity was 63.7 mg Mn g⁻¹ HT and 666.7 mg Fe g⁻¹ HT.

This study aimed to chemically and radiologically characterize the water resources influenced by a phosphogypsum stack in Imbituba, SC, Brazil and to identify the annual intake by ingestion. Surface water was collected at six points downstream of the phosphogypsum stack. Subsurface water samples were collected from a piezometer in the stack area. These samples were analyzed using a radiochemical method to determine the natural radionuclide content and an inductively coupled plasma optical emission spectrometry to determine the concentration of selected metals. The concentrations of radionuclides were also compared with current standards. The radionuclide concentrations in the surface waters samples were lower or similar to those found in other studies. The effective dose resulting from water ingestion is below the recommended reference levels for drinking water. Samples collected exhibited no increase in radioactivity, under the influence of phosphogypsum stacks.