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Chemical characterization of atmospheric particulate matter and their source apportionment at an emerging industrial coastal city, Visakhapatnam, India Texte intégral
2016
Police, Sandeep | Sahu, Sanjay Kumar | Pandit, Gauri Girish
In the present study, particulate matter (PM10) was collected from two different locations viz. Jogannapalem and Parawada sites of Visakhapatnam. During study period, PM10 concentrations were found in the range from 34.8 to 109.7 μg/m3 and from 32.3 to 137.3 μg/m3 at Jogannapalem and Parawada sites respectively. Chemical characterization of PM10 was carried out to estimate the concentration levels of various particle bound chemical species (Al, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Pb, Cd, Cl−, F-, NO3-, SO42−, Na+, K+, Mg2+ and Ca2+). Among different species, Al was observed to have highest average concentration (4.1 μg/m3 at Jogannapalem and 3.8 μg/m3 at Parawada) at both the sampling sites followed by K at Jogannapalem and Ca at Parawada. PM10 concentration as well as trace metals concentration (except Mn and Fe) was observed to have higher concentrations at Parawada site as compared to Jogannapalem site, indicating higher pollution at Parawada.Source apportionment study carried out using PMF (USEPA PMF5.0) receptor model identified six major sources at Jogannapalem and seven predominant sources at Parawada, which are contributing to collected PM. The two study locations share five common sources viz. crustal, sea salt spray, coal combustion, fuel oil combustion and metal industry. The other sources include biomass burning at Jogannapalem; road traffic and secondary aerosols at Parawada. At Jogannapalem, biomass burning (35%) is the predominant source, whereas coal combustion (22.6%) is dominating at Parawada. PMF factor profiles were observed to have similar elemental profiles obtained at different industrial locations of Visakhapatnam.
Afficher plus [+] Moins [-]The evaluation of emission control to PM concentration during Beijing APEC in 2014 Texte intégral
2016
Li, Ruipeng | Mao, Hongjun | Wu, Lin | He, Jianjun | Ren, Peipei | Li, Xiaoyu
Several statistical methods are performed in this study to evaluate the effect of emission control measures on particulate matter (PM) concentrations during the 2014 Asia–Pacific Economic Cooperation (APEC) Summit held in Beijing. The concentration of PM2.5 is reduced by 30%, 38% on a year-on-year and month-on-month basis during the APEC emission control period while PM10 reducing by 41% and 26% respectively. Considering from the impacts of the weather circulation types, PM2.5 and PM10 are both reduced by 34%.ANN model is considered to be appropriate with the ability of characterising non-linear phenomena. In this work an ANN model is built to predict the daily averaged PM concentrations. Comparing the observed PM concentrations and the predicted value which are forecasted by ANN model on condition that no emission control measures were carried out during the APEC, the reductions for PM2.5 and PM10 are 24%, 28% respectively. All these results suggest that strict emission control measures push down the pollution level effectively, and more observed data with long time could improve the accuracy of evaluation results. More stringent controls of regional emissions should be lasted for the continuous improvements of air quality in Beijing-Tianjin-Hebei region.
Afficher plus [+] Moins [-]Environmental genotoxicity assessment along the transport routes of chemical munitions leading to the dumping areas in the Baltic Sea Texte intégral
2016
Baršienė, Janina | Butrimavičienė, Laura | Grygiel, Włodzimierz | Stunžėnas, Virmantas | Valskienė, Roberta | Greiciūnaitė, Janina | Stankevičiūtė, Milda
The frequencies of micronuclei (MN), nuclear buds (NB) and nuclear buds on filament (NBf) were examined in 660 specimens of herring (Clupea harengus) collected in 2009–2014 at 65 study stations located mainly along the chemical munition transport routes in the Baltic Sea. The frequency of nuclear abnormalities was strongly increased in herring caught at four stations located close to chemical munition dumping sites, or CWAs — substances (chemical warfare agents) in sediments. Significant increase of MN, NB and NBf was observed in fish caught November 2010–2013 compared to 2009. The most significantly increased genotoxicity responses were recorded in fish caught at stations along CW (chemical weapons) transport routes, close to the Bornholm CW dumping area, in zones with CWAs in sediments and with oil–gas platforms.
Afficher plus [+] Moins [-]Multidrug-resistant Vibrio associated with an estuary affected by shrimp farming in Northeastern Brazil Texte intégral
2016
Rocha, Rafael dos Santos | Sousa, Oscarina Viana de | Vieira, Regine Helena Silva dos Fernandes
Bacteria of genus Vibrio with multidrug resistance in shrimp farm environment were recurrent. Thus, the aim of this study was to evaluate the antimicrobial resistance profile of 70 strains of Vibrio isolated from water and sediment of Acaraú estuary, Ceará, Brazil. In order to achieve this goal, disk diffusion technique was used with the following antimicrobial agents: ampicillin (Amp), aztreonam (Atm), cephalothin (Cef), cefotaxime (Ctx), ceftriaxone (Cro), ciprofloxacin (Cip), chloramphenicol (Clo), florfenicol (Flo), nitrofurantoin (Nit), gentamicin (Gen), oxytetracycline (Otc), tetracycline (Tet), streptomycin (Str), nalidixic acid (Nal), and sulfazotrim (Sut). All Vibrio strains were resistant to at least one antimicrobial agent, being verified as 17 multidrug-resistant profiles. All strains resistant to Otc and Tet were characterized to exhibit plasmidial resistance. Therefore, Vibrio strains from Acaraú estuary pose a risk to public health and aquatic culture.
Afficher plus [+] Moins [-]Seasonal hypoxia regulates macrobenthic function and structure in the Mississippi Bight Texte intégral
2016
Rakocinski, Chet F. | Menke, Daneen P.
Hypoxic conditions are escalating to the east of the Mississippi River within the Mississippi Bight. The objective of this study was to examine changes in macrobenthic function and structure relative to seasonal hypoxia over a 3.5year period at the 10m (Site 6) and 20m (Site 8) isobaths within the Mississippi Bight. Seasonal hypoxia acted as a regular periodic disturbance during the study period, although the magnitude and duration of hypoxia varied inter-annually. Macrobenthic metrics revealed seasonal hypoxia effects on secondary production potential and community maturity, which agrees with previous studies. In addition, metrics were notably higher at the 20m isobath during the latter half of the study period, following the Deepwater Horizon (DwH) oil spill. This study confirms hypoxia as a major driver affecting the function and structure of soft-bottom macrobenthos in the Mississippi Bight.
Afficher plus [+] Moins [-]Pathways of priority pesticides in sediments of coastal lagoons: The case study of Óbidos Lagoon, Portugal Texte intégral
2016
Pinto, M.I. | Vale, C. | Sontag, G. | Noronha, J.P.
This study reports the concentrations of the priority pesticides (PPs) in 14 surface sediments and 21 layers of a sediment core from Óbidos Lagoon, a shallow Portuguese coastal lagoon. Results show that the PPs are confined to the upper part of the lagoon that receives most of the inputs from surface runoff of the surrounding agricultural fields and from small tributaries. Past and recent applied PPs were registered in sediments, aluminum normalized concentrations varying between 0.05×10−7 and 6.85×10−7. The PP risk assessment based on sediment quality guidelines like the “Probable Effect Level” (PEL) shows no biological effects in either sediments or aquatic organisms of Óbidos Lagoon, except for dieldrin, lindane, DDT, heptachlor epoxide and its parent compound heptachlor.
Afficher plus [+] Moins [-]PCBs and OCPs in fish along coastal fisheries in China: Distribution and health risk assessment Texte intégral
2016
Pan, Hui | Geng, Jingjing | Qin, Yukun | Tou, Feiyun | Zhou, Junliang | Liu, Min | Yang, Yi
PCBs and OCPs were analyzed in fish (bass) taken along Chinese coastal fisheries. In the bass muscle, PCB, DDT and HCH concentrations were in the range of 1.02–2.2ng/g, 0.44–1.74 and 2.84–106.11ng/gww, respectively. Spatial distribution showed that the concentrations of target contaminants in bass from south fisheries were in general much lower than those from north fisheries in China. The ratios of OCP congeners suggested that technical DDT was not the main input and a recent usage of lindane or old technical HCH residuals could be the source of HCHs. The OCC concentrations in liver (127–442.43ng/gww) from selected samples were 8–12 and 10–14 times higher than those in gills and muscles, respectively. Based on the maximum allowable fish assumption rate (CRlim and CRmm), it could cause human health risk, by consuming bass samples taken from highly contaminated fisheries including QD and ST.
Afficher plus [+] Moins [-]Trace metal contamination in surface sediments of intertidal zone from Qinhuangdao, China, revealed by geochemical and magnetic approaches: Distribution, sources, and health risk assessment Texte intégral
2016
Zhu, Zongmin | Xue, Junhui | Deng, Yuzhen | Chen, Lin | Liu, Jiangfeng
Based on geochemical and magnetic approaches, the distribution, sources, and health risk of trace metals in surface sediments from a seashore tourist city were investigated. A significant correlation was found between magnetic susceptibility (χ) and trace metals, which suggested that levels of trace metals in the sediments can be effectively depicted by the magnetic approach. The spatial distribution of χ and trace metals matched well with the city layout with relatively higher values being found in the port and busy tourist areas. This result, together with enrichment factors (EFs) and Tomlinson pollution load index (PLI) of metals, suggested that the influence of human activities on the coastal environment was noticeable. Principal component analysis (PCA) indicated that trace metals in the sediments were derived from both anthropogenic and natural sources. Noncarcinogenic risk assessment showed that there was no potential health risk of exposure to metals by means of ingestion or inhalation.
Afficher plus [+] Moins [-]Heavy metal pollution and Pb isotopic tracing in the intertidal surface sediments of Quanzhou Bay, southeast coast of China Texte intégral
2016
Yu, Ruilian | Zhang, Weifang | Hu, Gongren | Lin, Chengqi | Yang, Qiuli
Concentrations of 16 heavy metals and Pb isotopic ratios in the intertidal surface sediments of Quanzhou Bay were determined to study the pollution level of heavy metals and the sources of Pb. The results showed that most concentrations of Cd, Sn, Mn, Cu, Zn, Cr, Pb, Hg, Ni, Co, Cs, Fe and V were higher than the background values, while most concentrations of Ti, Sb and Sr were lower than the background values. The mean concentrations of Cu, Zn, Pb, Cr and Cd exceeded the first-grade criteria of Chinese marine sediment quality. The geo-accumulation indexes revealed that the sediments had been polluted by some heavy metals. The results of Pb isotopic tracing indicated that the total Pb in the sediments were mainly from parent material, industrial emission and vehicle exhaust with the mean contributions of 38.2%, 51.3% and 10.5%, respectively, calculated by a three-end-member model of Pb isotopic ratios.
Afficher plus [+] Moins [-]Ophthalmic effects of petroleum dispersant exposure on common murres (Uria aalge): An experimental study Texte intégral
2016
Fiorello, Christine V. | Freeman, Kate | Elias, Becky A. | Whitmer, Emily | Ziccardi, Michael H.
The safety of chemical dispersants used during oil spill responses is largely unknown in birds. We captured common murres in Monterey Bay, CA and exposed them to Corexit EC9500a, crude oil, or a combination in artificial seawater. We performed ophthalmic examinations and measured intraocular pressures and tear production before and after exposure. Loglinear analysis found that exposure to oil or dispersant was related to the development of conjunctivitis and corneal ulcers. Odds ratios for birds exposed to oil or dispersant were positive and significant for the development of conjunctivitis, while odds ratios for the development of corneal ulcers were positive and significant only for birds exposed to a high concentration of oil. Ocular exposure to dispersants and petroleum in seabirds may cause conjunctivitis and may play a role in the development of corneal ulcers. These results have implications for policymakers who develop protocols for the use of dispersants during marine oil spills.
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