Positive Matrix Factorization (PMF) was used to identify sources of PM0.09–0.26, very fine aerosol particles, in a residential district of Ostrava Radvanice and Bartovice, a European air pollution hot-spot. Two-hours resolved elemental composition of very fine particulate matter samples were collected by the eighth stage of Davis Rotating-drum Universal-size-cut Monitoring (DRUM) impactor for the campaign period of the 26th January to the 21st February 2012. The campaign consists of smog (26.1–14.2) and post-smog (15–21.2) periods defined by their PM1 concentrations. Three factors were resolved by PMF: coal combustion, raw iron production and steel production. Coal combustion, associated with high concentrations of Se, Br, Pb, K, and As, dominated during the whole period. The contribution of raw iron production, a factor with high concentration of Mn, Fe, Co and Cr, increased significantly when ambient air temperature and the wind direction changed from NE to SW. Alternatively, the contributions of steel production, associated with Cl, K and Zn, were high under NE winds and decreased during the post-smog period. The mass of very fine particles correlated well with CO concentrations (smog r2 = 0.86, post-smog r2 = 0.43), which may indicate an industrial plume. The low value of S/Se (1448) suggests the impact of local/city-wide stationary coal combustion sources located to the N–NE of the monitoring site.

The total air pollution model (TAPM, www.cmar.csiro.au/research/tapm) was used to explore the phenomena of spreading ambient ozone in the complex 196 km × 196 km terrain of the west coast air basin of Taiwan (including ocean area). The altitude in the air basin ranges from 0 m (sea level) to 3000+ m (high mountain). The data of 2010–2014 from 21 air-quality monitoring stations were used to ensure the accuracy of the simulation results in accordance with an average index of agreement (IOA) > 0.61. Four ozone-spreading phenomena were observed among the air basin: the north–south spreading on the offshore (N–S SOO), north–south spreading around the coast (N–S SAC), east–west spreading from the ocean (E–W SFO), and east–west spreading around the mountain front (E–W SAMF). The results indicate that when two prevailing flows meet and interact at their boundaries, they form a convergence zone. The convergence zone presents distinctive weather conditions and accumulates air pollutants. More than wind direction, the ozone concentration is dependent on the topography and surrounding conditions. The results clearly show that the ozone-spreading phenomena follow certain rules. The N–S SOO, N–S SAC, E–W SFO, and E–W SAMF phenomena are during the northeaster, fore-southwester, southwester, and fore-northeaster monsoon months, respectively. Wind fields are a major factor in the high concentration of ozone and ozone spreading, especially downdraft and onshore winds. The diversion of river valleys and the mountainous barrier between the basin/hill and mountains exert obvious influences on the local wind field, strongly affecting the ozone-spreading phenomena.

Whether oiled wildlife should be rehabilitated during an oil spill is internationally debated. Research on little penguins (LP, Eudyptula minor) rehabilitated and released back into a cleaned environment after the New Zealand C/V Rena grounding oil spill in 2011 found the rehabilitation process was effective at treating and reversing the negative effects of oil-contamination on penguin post-release survival, productivity and diving behaviour. Here we investigated the acute corticosterone stress response of LPs to determine if responses of rehabilitated birds differed from those of “control” birds. Corticosterone responses of LPs two years after an oil spill did not differ between rehabilitated and non-rehabilitated penguins. These results show that the rehabilitation process for LP did not affect their long-term physiological responses to humans. This indicates that wildlife can be rehabilitated and returned to the wild with similar human tolerance levels to non-rehabilitated birds and an absence of habituation.

Stable isotopes (δ15N, δ18O) can serve as tracers for sources of nitrogen in the receiving environment. Hong Kong discharges ~3×106m3d−1 of treated wastewater into the ocean from 68 facilities implementing preliminary to tertiary treatment. We sampled treated sewage from 18 plants across 5 treatment types and examined receiving seawater from northeast Hong Kong. We analyzed nitrate and nitrite (NO3−+NO2−, hereafter NOx) ammonium (NH4+), phosphate (PO4+) concentrations and δ15NNOx, δ18ONOx. Sewage effluents contained high mean nutrient concentrations (NO3−=260μmolL−1, NH4+=1400μmolL−1, PO4+=50μmolL−1) with some indication of nitrogen removal in advanced treatment types. Mean δ15NNOx of sewage effluents from all plants and treatment types (12‰) was higher than natural sources and varied spatially and seasonally. There was no overall effect of sewage treatment type on δ15NNOx. A mass balance model indicated that sewage (>68%) remains a dominant source of nitrate pollution in seawater in Tolo Harbor.

Squids are active and opportunistic predators that feed on a wide range of prey. Their active movements in the water column and their voracity promote a high consumption of food. In the pelagic environment off Ecuador, marine pollution is characterized by plastic debris with a mainland origin, including plastics trash of fishing gears. The objective of this work was to describe the presence of plastic remains in the stomach contents of Dosidicus gigas caught off the coast of Ecuador. Results demonstrated that 12% of the stomachs contained plastic remains. These plastics were identified as multifilament of polyethylene lines and polyvinyl chloride remains. Findings of this work could be related to an increase in the discharge of solid materials in the water column, increasing the probability to be ingested by the jumbo squid.

Due to the socio-economic impact and the consequences on human health, the pollution associated to Particulate Matter (PM) represents one of the main emergences at a global scale. For these reasons, in the last decade we assisted to a continuously increasing interest in the mobile monitoring of PM on a regional and a local scale. Here we summarize the current status in this field, outlining the critical issues and the perspectives. The growing availability of instruments designed and optimized to the real-time monitoring of the air quality, considerably increased the spatial and temporal resolution of available datasets, actually improving air pollution maps and forecast models. However, several issues are still unresolved, particularly in terms of data representativeness. Indeed, the future PM monitoring devices have to be designed to support the decisional process but also the management of environmental emergencies in urban and industrial areas. The future of these devices is certainly the development of compact systems that will make possible a real-time characterization of size distribution, morphology, and chemical composition of the airborne particles.

Ultrafine aerosol nanoparticles created from combustion were measured by using three types of dilutors: a simple mixing dilutor, an ejector dilutor, and a rotational disk dilutor. The original particle size distribution from combustion was compared to the estimated distribution from these dilutors. The results showed that ultrafine aerosol nanoparticles maintained their particle size distribution, while particle concentrations decreased 10–20 fold in the dilution processes. Therefore, the dilutors not only diluted the aerosol nanoparticle concentration to the level of the measurement devices, but also helped estimate the shape of aerosol particle size distribution, particularly for ultrafine aerosol nanoparticles from combustion.

Recent work has identified nitric acid (HNO3) as a potential precursor of nitrous acid (HONO), which is an important source of oxidants that regulate ozone and particulate pollution. Recent work in our laboratory has indicated that the reduction of HNO3 to HONO can occur homogeneously in the presence of surrogates for volatile organic compounds (VOCs) emitted by motor vehicles. This study focuses on the impact of environmental variables on the rate of formation of HONO in this process. The observed base case (25.0 °C and ∼20.0% relative humidity (RH)) HONO formation rate was 0.54 ± 0.09 ppb h−1, values comparable to enhancements observed in HONO during morning rush hour in Houston, TX. The rate was enhanced at lower temperatures of ∼20.0 °C, but the rate remained statistically similar (1σ) for experiments conducted at temperatures of 25 °C, 30 °C, and 35 °C. The assumption that multiple reactive components of the VOC mixture react with HNO3 is supported by this observation, and the relative importance of each reactive species in the reaction may vary with temperature. The enhanced rate at lower temperatures could make the proposed reaction mechanism more important at night. The formation rate of HONO does not change substantially when initial HNO3 concentration is varied between 400 and 4600 ppt, suggesting that the concentration of reactive VOCs was the limiting factor. The reduction of HNO3 to HONO appears not to occur heterogeneously on the aerosol surfaces tested. The presence of ∼120 ppb of ammonia has no observable impact on the reaction. However, it is likely that UV irradiation (λ = 350 nm) decreases the formation rate of HONO either by consuming the reactive VOCs involved or by directly interfering with the reaction. The “renoxification” of less reactive HNO3 to more reactive HONO has significant implications for daytime ozone and particulate pollution.

This paper contributes for the first time the seasonal mass size distribution of atmospheric aerosols and their possible health implications in a rural area of eastern central India. Size-segregated atmospheric aerosols were collected from July 2012 to June 2013 at rural site near Mahanadi riverside basin of Rajim (20° 59′N and 81°55′E), Chhattisgarh, India using nine-stage cascade impactor. Bimodal size distribution was found with stable peaks at 0.4–0.7 μm (fine mode) and 4.4–5.8 μm (coarse mode) during monsoon, winter, spring and summer seasons at study site. The mass median aerodynamic diameter of total impactor particle sizes was shifted from lower particle size in winter to higher particle size in summer. High concentrations of size-segregated aerosols were found during winter season with 45%, 55% and 36% of PM2.5–10, PM2.5 and PM1, respectively of the total PM10 aerosol. One unique observation was that the mass concentration of particulate matter increases abruptly in May and June during summer season, which was due to in situ burning of rice crop residues. The concentrations of upper respiratory tract and lungs particles were found to be highest during winter whereas respiratory airways particles showed maxima during summer season. The highest numbers of unfavorable days (i.e. value of air quality index > 101) were also observed during winter followed by summer season. The significant positive correlations found among particle in fine size bins (<0.43–2.5 μm) during winter and summer season was mainly due to the biomass burning activities during the study period at a rural site in eastern central India.