The purpose of this study is to evaluate cost-effective reduction strategies for nitrogen oxides (NO x ) in the Asian region. The source-receptor relationships of the Lagrangian “puff” model of long-range transportation, ATMOS-N, were used to calculate the wet/dry deposition of the nitrogen (N) in Asia. Critical loads of N deposition in Asia were calculated from the relationships between the critical load of sulfur (S) and balance of N in and out using the data of S critical load of RAINS-ASIA. The cost functions of N reduction of Asian countries were derived by the regression analysis with the data of cost functions of European countries used in RAINS. In order to assess the environmental impact, the gaps between N deposition and critical load of N were calculated. The emission of NO x was reduced in some cases of this model, and the changes of gaps between N deposition and critical load were observed as well as the changes of the reduction cost. It is shown that a uniform reduction of NO x emissions by countries in Asia is not cost-effective strategy.

The consequences of nitrogen (N) enrichment for terrestrial and freshwater ecosystems are of increasing concern in many areas due to continued or increasing high emission rates of reactive N. Within terrestrial ecosystems various conceptual frameworks and modelling approaches have been developed which have enhanced our understanding of the sequence of changes associated with increased N availability and help us predict their future impacts. Here, some recent findings are described and their implications for these conceptual frameworks and modelling approaches discussed. They are: (a) an early loss of plant species that are characteristic of low N conditions as N availability increases and a loss of species with high N retention efficiencies (so called N 'filters'), (b) suppression of microbial immobilisation of deposited [graphic removed] due to increased [graphic removed] availability in the early stages of N saturation, (c) the early onset of [graphic removed] leaching due to these changes (a and b above) in both plant and microbial functioning, (d) reduced sensitivity of vegetation to N additions in areas with high historical N deposition, (e) delayed changes in soil C:N changes due to increased net primary productivity and reduced decomposition of soil organic matter. Some suggestions of early indicators of N saturation are suggested (occurrence of mosses; [graphic removed] ratio in surface soils) which indicate either a shift in ecosystem function and/or structure.

The long-term monitoring of precipitation and its chemical composition are important for identifying trends in rain quality and for assessing the effectiveness of pollution control strategies. A statistical test has been used to the atmospheric concentrations measured in the French rural monitoring network (MERA) in order to bring out spatio-temporal trends in precipitation quality in France over the period 1990-2003. The non-parametric Mann-Kendall test which has been developed for detecting and estimating monotonic trends in the time series was used and applied in our study at annual values of wet-only precipitation concentrations. The emission data suggest that SO₂ and NO x emissions decreased (-3.3 and -2.0% year-¹, respectively) contrary to NH₃ emissions that increased slightly (+0.2% year-¹) over the period 1990-2002 in France. On the national scale, the pH values have a significant decreasing trend of -0.025 ± 0.02 unit pH year-¹. [graphic removed] and [graphic removed] concentrations in precipitation have a significant decreasing trend, -3.0 ± 1.6 and -3.3 ± 0.6% year-¹, respectively, corresponding with the downward trends in SO₂ emissions in France (-3.3% year-¹). A good correlation (R ² = 0.84) between SO₂ emissions and [graphic removed] concentrations was obtained. The decreasing trend of [graphic removed] was more significant (-5.4 ± 5.2% year-¹) than that of [graphic removed] (-1.3 ± 2.4% year-¹). Globally, the concentration of the major ions showed a clear downward trend including marine and alkaline ions. In addition, the relative contribution of HNO₃ to acidity precipitation increased by 51% over the studied period.

Since 1983, the Ministry of the Environment of Japan has conducted nation-wide acid deposition surveys. To investigate the effects of acid deposition on surface water, we used the nonparametric Mann-Kendall test to find temporal trends in pH, alkalinity, and electrical conductivity (EC) in more than 10 years of data collected from five lakes and their catchments (Lake Kuttara: northernmost; Lake Kamakita: near Tokyo; Lake Ijira: central; Lake Banryu: western; and Lake Unagiike: southernmost). The pH of Lake Ijira water has declined slightly since the mid-1990s, corresponding with the downward trends seen in the pH and alkalinity of the river water flowing into the lake. There were significant upward trends in the EC of both the lake and stream water; the same trends were also found for [graphic removed] concentrations. These trends show evidence of acidification due to atmospheric deposition, and this is the first such finding in Japan based on significant long-term trends. Lake Ijira is located about 40 km north of the Chukyo industrial area near Nagoya. The annual depositions of H⁺, nss- [graphic removed] , and [graphic removed] in Lake Ijira were among the highest of all deposition monitoring sites, suggesting that this is the main cause of the significant acidification observed in Lake Ijira. No significant trends suggesting acidification were observed in any of the other lake catchments in spite of the significant upward trends in EC. Upward trends in pH and alkalinity at Lake Banryu and upward trends in alkalinity at Lake Kamakita were detected, but no change in pH or alkalinity at Lake Kuttara and Lake Unagiike was observed.

CH₄ concentrations in both the surface and bottom waters of Jiaozhou Bay were determined during four surveys in 2003, which showed variability with both seasons and tidal cycles. Atmospheric fluxes of CH₄ in Jiaozhou Bay showed obvious seasonal and spatial variations, with the highest values occurring in summer and the lowest in winter. The annual emission of CH₄ from Jiaozhou Bay was estimated to be [graphic removed] . CH₄ in the water column of Jiaozhou Bay was found to come from several land-sources including riverine water input, sewage water input and groundwater input. The spatial and temporal variation in distributions and atmospheric fluxes of CH₄ in Jiaozhou Bay was influenced mainly by the input of polluted river waters and the sewage effluents along the eastern coast, which highlights the effects of human impacts on CH₄ emission rates.

Many lakes in the Adirondack Mountains, New York, have acidified over the past century due to acidic atmospheric deposition. More recently, most monitored lakes have shown signs of chemical recovery (increase in acid neutralizing capacity) as sulfur deposition levels have declined in response to the Clean Air Act and other emissions control legislation. We used measured and modeled trends in past lakewater acidification and projections of future recovery from acidification to extrapolate results from judgment samples of intensively studied lakes to the population of acid-sensitive Adirondack lakes. Simulations were developed for 70 watersheds using the Model of Acidification of Groundwater in Catchments (MAGIC) to classify lakes according to their sensitivity to change in atmospheric S and N deposition. MAGIC simulations suggested that the modeled Adirondack Long-Term Monitoring Project (ALTM) and Adirondack Effects Assessment Project (AEAP) lakes were largely among the lakes in the population that had acidified most between 1850 and 1990. Most of the modeled ALTM/AEAP lakes were within the top 36% of acid sensitivity, based on model projections of past acidification and future chemical recovery, compared with the 1,829 Adirondack lakes in EPA's Environmental Monitoring and Assessment Program (EMAP) statistical frame. Results of this research will allow fuller utilization of data from on-going chemical and biological monitoring and process-level studies by providing a basis for regionalization of findings and developing/refining relationships among watershed characteristics, chemical change, and biological responses to changing levels of acidic deposition.

Buffer capacity analysis of open atmospheric gas-liquid systems containing main acidic and basic atmospheric pollutants was carried out. Usually the buffer capacity is considered as a function of pH as an independent variable. In this work the buffer capacity is analysed including the dependence of pH on the composition of a system. Such an approach allows finding an important, from the viewpoint of atmospheric water acidification, relationship between the gas phase composition and the buffer capacity. It was found that buffer capacity of the open gas-liquid systems may be very high and it may cause the liquid phase pH to remain at low levels. The buffer capacity of the analysed systems is most strongly affected by the simultaneous presence of ammonia and strong acids in the gas phase. The higher concentrations of strong acid gases the lower NH₃ concentration is sufficient to achieve high buffer capacity. In the presence of strong acid gases, calcium ions affect both the buffer capacity and the liquid phase pH only at low NH₃ concentrations. High buffer capacity of open gas-liquid systems may be one of the reasons why the reduction in emissions of acidic gas pollutants has little effect on decrease in atmospheric water acidity.

Masu salmon Oncorhynchus masou masou divides into two life histories after a year of life in the river, the sea-run form and the fluvial form. Since salmons are anadromous, the sea-run form salmons are known to pollute the river sediments during spawning migration. In this study, we have studied the accumulation of organochlorines in the fluvial form as well as the sea-run form, and discussed their differences. In order to elucidate the accumulation patterns of organochlorines in both the fluvial and sea-run form masu salmons, the concentrations of organochlorines were determined in the muscle of both life histories. The organochlorines in the sea-run form were 7 to 21 times higher than those of fluvial form. Since salmons are semelparous, the carcasses of polluted sea-run form pollute the river sediments. The trans-nonachlor/trans-chlordane (N/C) ratio in the fluvial form (1.93) was significantly lower than that of sea-run form (23.8). This indicates that the fluvial form is polluted by comparatively newly input chemicals. These results suggest that sea-run form masu salmons have the potential to pollute the river sediments secondarily as vectors, but from the difference in N/C ratio between the two forms, the fluvial fish does not seem to be polluted by those organochlorine compounds of sea-run fish origin yet.

Reduced emissions of acidifying pollutants have changed the acidification process, and as a result, forest soils and surface waters are slowly recovering in Sweden. However, model calculations show that some areas may never recover completely unless further measures, such as liming, are undertaken. Liming of surface waters (lakes, rivers and wetlands) has been successfully practised in Sweden since the 1970s, but repeated treatments are necessary. A full recovery of acidified lakes and streams without frequent liming is however not possible until soil acidification is reversed in the most strongly affected areas. In this study, the recovery of acidified streams was examined using 'the total catchment approach' i.e. treatment of both recharge and discharge areas. The aim was to compare the quantitative effect of different treatments on run off chemistry and the recovery of brown trout. Catchments in southwest Sweden were treated with a combination of 2 tons of wood ash and 4, 6 or 12 tons of crushed limestone per hectare in 1998/1999. Treatment of both recharge and discharge areas resulted in fast and significant changes in stream water quality, e.g. increased concentrations of calcium, higher pH and ANC and a decreased concentration of inorganic aluminium. The initial changes were dependent on the distribution of the applied lime between discharge and recharge areas rather than the average dose on the total catchment. Treatment of recharge areas only, resulted in smaller but still significant effects on calcium, pH and ANC in stream water. Furthermore, there was an initial leaching of nitrate but it was only minor compared with the elevated leaching that occurs after a clear-cut. As a result of the treatments, brown trout is now successfully reproducing.

Four umbric A horizons from acid forest soils were acidified in a batch type experiment and its effect in the Al pools of the solid phase analysed by means of selective dissolution methods. The results showed that Al release accounted for the consumption of 85-99% of the added protons, and causes a decrease of 2-33% of the 'reactive' Al pool of the soil solid phase. In these A horizons, inorganic non-crystalline Al and high stability Al-humus complexes are the main sources of the dissolved Al. The contribution of the complexes with intermediate stability only was relevant in the more acid horizon developed from phyllites (P18-A). The increase of equilibration time from 96 to 720 h did not caused significant differences in the decrease of the 'reactive' Al pool suggesting the acid neutralising reactions occurred in less than 96 h. In most cases the quantity of released Al is in agreement with the decrease of the different reactive Al pools of the solid phase.