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Spreading of waxy oils on calm water Texte intégral
2018
Brönner, Ute | Johansen, Øistein | Leirvik, Frode | Nordam, Tor | Sørheim, Kristin R.
Spreading of waxy oils on calm water Texte intégral
2018
Brönner, Ute | Johansen, Øistein | Leirvik, Frode | Nordam, Tor | Sørheim, Kristin R.
The objective of this paper is to provide a simple extension of the much-used gravity spreading model for oil on calm water to account for the spreading behavior of waxy crude oils in cold waters – including the observed retardation and eventual termination of spreading at certain oil film thicknesses. This peculiar behavior is not predicted by traditional spreading models for oil on calm water (i.e. viscous-gravity spreading models), but may occur due to non-Newtonian oil properties caused by precipitation of wax at low temperatures. To clarify the spreading behavior of such oils, SINTEF has conducted a series of laboratory experiments with a range of waxy oil mixtures. The present paper contains analyses of data from these experiments, including favorable comparisons with calculations by a proposed improved surface spreading model.
Afficher plus [+] Moins [-]Spreading of waxy Crude Oils on calm weather | Spreading of waxy Crude Oils on calm weather Texte intégral
2018
Brönner, Ute | Johansen, Øistein | Leirvik, Frode | Nordam, Tor | Sørheim, Kristin Rist
The objective of this paper is to provide a simple extension of the much-used gravity spreading model for oil on calm water to account for the spreading behavior of waxy crude oils in cold waters – including the observed retardation and eventual termination of spreading at certain oil film thicknesses. This peculiar behavior is not predicted by traditional spreading models for oil on calm water (i.e. viscous-gravity spreading models), but may occur due to non-Newtonian oil properties caused by precipitation of wax at low temperatures. To clarify the spreading behavior of such oils, SINTEF has conducted a series of laboratory experiments with a range of waxy oil mixtures. The present paper contains analyses of data from these experiments, including favorable comparisons with calculations by a proposed improved surface spreading model. | Spreading of waxy Crude Oils on calm weather | acceptedVersion
Afficher plus [+] Moins [-]Arsenic and five metal concentrations in the muscle tissue of bigeye tuna (Thunnus obesus) in the Atlantic and Indian Oceans Texte intégral
2018
Chen, Zhengyou | Chen, Y. T. | Cheng, Jingsun | Hsu, C.-C. | Liu, L.-L. | Chen, H.-S. | Chen, M.-H.
White muscle concentrations of As, Cd, Cu, Fe, Se, and Zn were investigated in Atlantic- and Indian-bigeye tuna (BET) (Thunnus obesus) from 6 regions. As and Cd muscle concentrations were significantly higher in the Indian-BET than in the Atlantic-BET, whereas the Indian-BET caught in the waters off South Africa revealed the highest As, Se, and Zn muscle concentrations. Accordingly, multidimensional scaling separated them into two oceanic groups. Positive linear relationships between muscle Cd concentration and fork length (FL) were established in both oceans. For the other elements, only muscle-Fe and FL relationship was found in the Atlantic-BET. 10.3% of BET > 145 cm FL from both oceans possessed muscle Cd concentrations exceeding the food safety limit (0.1 μg g−1 wet weight) set by the European Commission. Increased Cd, Cu and Zn pollution was found in the Atlantic Ocean compared with previous data, with higher levels found in the Indian Ocean.
Afficher plus [+] Moins [-]Loricate ciliates as an indicator of eutrophication status in the estuarine and coastal waters Texte intégral
2018
Sivasankar, R. | Ezhilarasan, P. | Sathish Kumar, P. | Naidu, S.A. | Rao, G.D. | Kanuri, Vishnu Vardhan | Ranga Rao, V. | Ramu, K.
Owing to the environmental sensitivity of ciliate species, the monitoring and assessment of these communities can indicate the health of the aquatic environment. Sampling for loricate ciliates was carried out during different seasons at three different locations in the estuarine and coastal waters of Kochi, Southwest coast of India. The loricate ciliate community comprising of 27 species belonging to 10 genera revealed significant differences among the three sampling locations. The maximum numerical abundance and less species diversity of loricate ciliates were recorded at the estuarine locations whereas the minimum abundance and more species diversity were encountered in the coastal waters. Multivariate statistical analyses revealed that Tintinnopsis beroidea and Tintinnopsis uruguayensis were correlated positively with nutrients in the estuarine environment, which receives large amount of anthropogenic inputs. Thus, we propose that these two loricate ciliates may be considered as a potential bioindicator of eutrophication status in marine ecosystems.
Afficher plus [+] Moins [-]First report of occurrence, distribution, and composition of microplastics in surface waters of the Sea of Marmara, Turkey Texte intégral
2018
Plastic is produced today in large quantities and used for many purposes. At the end of use, a large part of it gets into the environment, often into the sea and there it is fragmented into the smallest fragments, so-called microplastic (MP). MPs pose a serious challenge to the marine environment such as the sources and properties of MP particles, their impact on marine organisms, and the challenges of environmental pollution. This work, carried out in the fourteen sites in the area, is the first reference to the detection of MP distribution at surface waters in the Sea of Marmara, Turkey. As a result of this study, the average level of MP in the surface was determined to be 1.263 item/m2. The results were higher compared of the most other adjacent regions and show that the Sea of Marmara started to face that problem.
Afficher plus [+] Moins [-]Spatial and temporal analysis of biliary 1-hydroxypyrene, hepatic ethoxyresorufin-O-deethylase and muscle acetylcholinesterase activity in UK flatfish Texte intégral
2018
(Craig D.),
Chemical pollution of the marine environment from anthropogenic sources is a global concern due to the potential for long term effects on the ecosystem. Chemical monitoring schemes can detect harmful substances in water, sediment or biota. However, the presence of specific determinants gives no information on how individual species or the ecosystem are impacted. Biological effects techniques are therefore used in environmental monitoring schemes to provide a clearer picture of whether the chemicals present are causing deleterious effects on the species sampled, or whether organisms have been exposed to certain classes of organic contaminants that they may be able to metabolise. Using these techniques, we can provide an assessment of the health of our marine environment (Thain et al., 2008).
Afficher plus [+] Moins [-]Assessment of potentially toxic metal (PTM) pollution in mangrove habitats using biochemical markers: A case study on Avicennia officinalis L. in and around Sundarban, India Texte intégral
2018
Bakshi, Madhurima | Ghosh, Somdeep | Chakraborty, Debarati | Hazra, Sugata | Chaudhuri, Punarbasu
Spatial distribution of potentially toxic metals (PTMs) and their accumulation in mangrove Avicennia officinalis L. were studied along 8 locations in and around Sundarban mangrove wetland, India. Among 8 locations, S3 (Chemaguri) and S5 (Ghushighata) showed higher concentration of PTMs (Cd, Cr, Cu, Ni, Pb, Zn) characterized by higher enrichment factors (3.45–10.03), geo-accumulation indices (0.04–1.22), contamination factors (1.14–3.51) and pollution load indices (1.3–1.45) indicating progressive deterioration of estuarine quality and considerable ecotoxicological risk. Metal concentration in A. officinalis leaves showed significant correlation with sediment metals implying elevated level of bioaccumulation. Significant statistical correlation between photosynthetic pigments (Chlorophyll a, Chlorophyll b), antioxidant response (free radical scavenging and reducing ability) and stress enzymatic activity (Peroxidase, Catalase, Super-oxide dismutase) of A. officinalis with increasing metal concentration in the contaminated locations reflects active detoxification mechanism of the plant. The study indicates the potentiality of biomonitoring metal pollution using studied biochemical markers in mangrove habitats.
Afficher plus [+] Moins [-]A Review of Socio-acoustic Surveys for Soundscape Studies Texte intégral
2018
Engel, Margret Sibylle | Fiebig, André | Pfaffenbach, Carmella | Fels, Janina
PURPOSE OF REVIEW: This article reviews the literature and presents the current status of the use of socio-acoustic surveys in soundscape studies, through the indication of appropriate question formats, types, and topics for each data collection method (soundwalks, interviews, listening tests, and focus group) for the involved public and acoustic stimuli. RECENT FINDINGS: The ISO 12913-2 establishes ways of data collection and reporting requirements for soundscape studies (International Organization for Standartization 2017), including the triangulation technique. This standard recommends some data collection methods, like soundwalks and interviews. Even so, some authors are using different methods to collect data, such as focus group and listening tests. This study investigated through 52 peer-reviewed papers published on the last 20 years the current status of socio-acoustic studies regarding question topics and types, used stimuli, and characteristics about the participants, using the four major adopted data collection methods in soundscape studies: soundwalks, interviews, listening tests, and focus group. Some topics like “soundscape quality” and “sound sources identification and evaluation” are common in the recent studies, as well as the adoption of some question types such as semantic differential scale, the staple scale, and ranking order scale.
Afficher plus [+] Moins [-]Anthropogenic and natural variability in the composition of sedimentary organic matter of the urbanised coastal zone of Montevideo (Río de la Plata) Texte intégral
2018
Bueno, C. | Brugnoli, E. | Bergamino, L. | Muniz, P. | García-Rodríguez, F. | Figueira, R.
This study is aimed to identify the different sources of sedimentary organic matter (SOM) within Montevideo coastal zone (MCZ). To this end δ13C, δ15N and C/N ratio were analysed in surface sediments and a sediment core. Sediment core analysis showed that until ~1950CE SOM was mainly marine, observing a shift towards lower δ13C in recent sediments, evidencing an estuarine composition. This trend was associated to the climatic variability, which exerted a major influence on the SOM composition, leading to an increased input of terrigenous material and associated anthropogenic contaminants. Surface sediments collected during different El Niño South Oscillation (ENSO) phases did not show inter-annual variability in SOM composition, which was mainly marine in both eastern and western region of MCZ and estuarine in Montevideo Bay. This spatial pattern provides new insights on the dynamics and factors affecting organic matter sources available for primary consumers along the study region.
Afficher plus [+] Moins [-]Macondo oil in northern Gulf of Mexico waters – Part 2: Dispersant-accelerated PAH dissolution in the Deepwater Horizon plume Texte intégral
2018
Driskell, William B. | Payne, James R.
During the Deepwater Horizon blowout, unprecedented volumes of dispersant were applied both on the surface and at depth. Application at depth was intended to disperse the oil into smaller microdroplets that would increase biodegradation and also reduce the volumes buoyantly rising to the surface, thereby reducing surface exposures, recovery efforts, and potential stranding. In forensically examining 5300 offshore water samples for the Natural Resource Damage Assessment (NRDA) effort, profiles of deep-plume oil droplets (from filtered water samples) were compared with those also containing dispersant indicators to reveal a previously hypothesized but undocumented, accelerated dissolution of the polycyclic aromatic hydrocarbons (PAH) in the plume samples. We interpret these data in a fate-and-transport context and conclude that dispersant applications were functionally effective at depth.
Afficher plus [+] Moins [-]First observations of perfluorooctane sulfonate occurrence and depuration from Sydney Rock Oysters, Saccostrea glomerata, in Port Stephens NSW Australia Texte intégral
2018
O'Connor, Wayne A. | Zammit, Anthony | Dove, Michael C. | Stevenson, Gavin | Taylor, Matthew D.
Following the discovery of potential chronic perfluoroalkyl substances (PFAS) contamination of Tilligerry Creek, Port Stephens (New South Wales Australia), sampling was undertaken to confirm the presence, extent and levels of contamination in commercial oyster crops of Sydney Rock Oyster (Saccostrea glomerata) and Pacific Oyster (Crassostrea gigas) grown within the estuary. Among a range of PFAS tested, only perfluorooctane sulfonate (PFOS) was detected. Concentrations of PFOS in oyster tissues for S. glomerata ranged from 1.6μgkg⁻¹ ww (wet weight) to below the limit of reporting of 0.3μgkg⁻¹ ww, with concentrations generally decreasing toward the lower reaches of the estuary. The sample of C. gigas tested had a PFOS concentration of 0.71μgkg⁻¹ ww that was consistent with concentrations observed in nearby S. glomerata. For harvest size (50–60g) S. glomerata, both holding contaminated oysters in a depuration system, and relocation to a non-contaminated area, saw significant reductions in the tissue PFOS concentrations. For oysters held in a depuration system, PFOS depurated at a rate of 0.008h⁻¹ (0.004–0.019h⁻¹; 90% CI), which corresponded with a depuration half-life of 87h (35–155h; 90%). A more conservative model (fitted to data that assumed concentrations<LOR were equal 0.5·LOR) predicted a depuration half-life of 131h. PFOS concentrations had fallen to below detectable limits within 162h. Similar decreases were observed in relocated oysters.
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