Crocin (C₄₄H₆₄O₂₄) is an isolated bioactive molecule of saffron extract. It has different pharmacological effects such as antioxidant and anti-inflammatory activities. In the present study, radioprotective property of crocin was investigated in the rat liver. Thirty-two rats were equally divided into four groups: (1) control (normal saline), (2) crocin (200 mg/kg), (3) γ-rays (6Gy), and (4) crocin plus γ-rays-treated groups. The liver histopathology, serum transaminases (ALT and AST), alkaline phosphatase (ALP), tumor necrosis factor-α (TNF-α), interleukin-1β (IL-1β), and hepatic lipid peroxidation, superoxide dismutase (SOD), catalase (CAT), and glutathione peroxidase (GPX) have been assessed. The histopathological result of hepatic tissue in group 3 showed hydropic degeneration and this progressed to focal or spotty necrosis through the lobule. Moreover, some sinusoids are distended with blood or with leukocytic infiltrations. Other cases in group 3 showed periportal leukocytic infiltrations and necrosis extended out from the portal tract to involve hepatic lobules with fibrinous necrosis in portal vessels, while the examination of hepatic tissues of group 4 showed reduced deformities, irregular arrangement, congested hepatic vessels, and necrosis in hepatocytes. The results also showed significant decreased level of liver function activities, inflammatory markers, lipid peroxidation, and increased levels of liver antioxidants enzymes in group 4. Crocin showed moderate protective effect against γ-rays-induced liver toxicity. The antioxidant effect of crocin may be a major reason for its positive impact on liver parameters. Graphical abstract .

With the spread of the concept of sustainable development, people have gained awareness about the problem of massive illegal dumping of construction waste. In this research, a questionnaire survey was carried out in the USA and China. The results indicated the following. (1) Workers in both the countries had positive minimisation attitudes, and the attitude of Chinese construction workers was not significantly different from that of American construction workers. Furthermore, their average values were 3.9 and 4.07, respectively. (2) Business owners had a poor understanding of the obligations that should be fulfilled by contractors and construction workers, which greatly reduced (a) construction workers’ and contractors’ motivation to implement waste minimisation management and (b) the benefit-driven effect. (3) In terms of perceived behavioural control, Chinese construction workers had poorer minimisation technologies and knowledge than American construction workers, and it was very difficult for them to implement construction waste minimisation. The research conclusions and relevant suggestions may be used to improve the construction waste minimisation behaviour and awareness of Chinese people and promote China’s construction waste minimisation management.

A hydroponics experiment was conducted to investigate the effect of iron plaque on root surfaces and selenium (Se) on the uptake and transfer of mercury (Hg) in rice seedlings by adding in the EDTA-Fe (0, 10, 30, 50, 70 mg Fe l⁻¹) into the solution to produce a different amount of iron plaque outside rice root. After 24 h, the red-brown iron plaque was formed on the root surface, and the amount of iron plaques was positively correlated with the amount of Fe in the solution. The iron plaque deposited on the root surface has a strong adsorption effect on the inorganic Hg. The addition of Se could promote the adsorption of Hg²⁺ on the iron plaque of rice, and the introduction of Se could increase the adsorption capacity of Hg on iron plaque on average by 1.42 times. The Hg was extracted by DCB (Dithionite-citrate-bicarbonate) up to between 66.2 and 67.8% of the total Hg when the roots with iron plaque (Fe70) were incubated with the combination of 5 μmol L⁻¹ of HgCl₂ and 5 μmol L⁻¹ of Na₂SeO₃ for an hour. After 3 days, the content of Hg in the iron plaque decreased to 6.3–33.9%, indicating that part of the inorganic Hg adsorbed by the iron plaque could be reabsorbed and used. Besides that, the iron plaque allowed the Hg to stay longer in the iron plaque, which hindered the transfer of Hg to the shoot significantly. Hg adsorbed in the iron plaque can be desorbed by low-molecular-weight organic acids, which was equivalent to desorption of Hg from ferric hydroxide oxides. Hg adsorbed on the iron plaque can be moved back to the rest of the plant. These results suggest that the iron plaque and Se in the root surface might play a role as “physical buffer” in the absorption and transfer of Hg.

Dust storms affect the primary productivity of the ocean by providing necessary micronutrients to the surface layer. One such dust storm during March 2012 led to a substantial reduction in visibility and enhancement in aerosol optical depth (AOD) up to ~ 0.8 (AOD increased from 0.1 to 0.9) over the Arabian Sea. We explored the possible effects and mechanisms through which this particular dust storm could impact the ocean’s primary productivity (phytoplankton concentration), using satellite-borne remote sensors and reanalysis model data (2003–2016). The climatological analyses revealed anomalous March 2012 in terms of dust deposition and enhancement in phytoplankton concentration in the month of March during 2003–2016 over this region. The studied dust storm accounts for increase in the daily average surface dust deposition rate from ~ 3 to ~53 mg m⁻² day⁻¹, which is followed by a significant enhancement in the chlorophyll-a (Chl_a) concentration (~ 2 to ~9 mg m⁻³). We show strong association between a dust storm and an event of anomalously high biological production (with a 4-day forward lag) in the Arabian Sea. We suggest that the increase in biological production results from the superposition of two complementary processes (deposition of atmospheric nutrients and deepening of the mixed layer due to dust-induced sea surface temperature cooling) that enhance nutrient availability in the euphotic layer.

In this paper, we synthesized a polyglycerol(PG)-mediated superparamagnetic graphene oxide nanocomposite called MGON, consisting of PG-modified superparamagnetic iron oxide nanoparticles (SPION) covalently bonded to PG-functionalized graphene oxide (GO). MGON exhibits better dispersibility and colloidal stability in aqueous solution than the magnetic graphene oxide reported in the literature. The physicochemical properties of MGON were analyzed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), and UV-vis spectroscopy. Applied to the adsorption of tetracycline (TC) in aqueous solution as an adsorbent, the MGON showed excellent adsorption performance with the maximum adsorption capacity of 684.93 mg/g at 298 K. Adsorption kinetics and isotherm results indicate that the adsorption process conforms to the pseudo-second-order kinetics and Langmuir isotherm models. Adsorption thermodynamics has confirmed that the adsorption process of TC on MGON is spontaneous and endothermic. With the increase of temperature, the adsorption capacity of MGON increases continuously, and the adsorption capacity of MGON is the largest when the pH value is 7. Furthermore, the π-π and cation-π interaction, amidation reaction, and hydrogen bonding can be used to explain the adsorption mechanism of TC on MGON. Desorption and regeneration experiments showed that MGON still had 67.65% regenerative performance after five cycles. Hence, MGON is a promising adsorbent in the removal of tetracycline from wastewater.

The presence of natural organic matter such as humic acid in water creates various problems in water purification. Humic acid can react with chlorine in the disinfection step and lead to the production of trihalomethanes and haloacetic acids that these compounds have carcinogenic and mutagenic properties; therefore, they must be removed before arriving to the disinfection stage. The purpose of this research was adsorption of humic acid from simulated wastewater by synthesized FeNi₃/SiO₂/TiO₂ magnetic nanocomposites. FeNi₃/SiO₂/TiO₂ magnetic nanocomposites were synthesized by sol-gel procedure and its characteristics were determined by TEM, VSM, BET, FESEM, and XRD techniques. Then, the effects of such pH (3–11), FeNi₃/SiO₂/TiO₂ dosage (0.005–0.1 g/L), contact time (0–200 min), and initial concentration (2–15 mg/L) were studied on humic acid adsorption using FeNi₃/SiO₂/TiO₂. The results of adsorption experiments revealed that the highest percentage of humic acid removal (94.4%) was achieved at pH 3, initial concentration of 5 ppm, FeNi₃/SiO₂/TiO₂ dose of 0.1 g/L, and contact time of 90 min. The analyses of experimental isotherm data showed that the humic acid adsorption was described by Langmuir model and also the kinetic studies represented that the process of adsorption of humic acid on FeNi₃/SiO₂/TiO₂ was followed by the pseudo-second kinetic. According to the results, it can be concluded that FeNi₃/SiO₂/TiO₂ magnetic nanocomposites have a high ability to absorb humic acid from simulated wastewater.

Breastfeeding is a gold standard of neonate nutrition because human milk contains a lot of essential compounds crucial for proper development of a child. However, milk is also a biofluid which can contain environmental pollution, which can have effects on immune system and consequently on the various body organs. Polychlorinated biphenyls are organic pollutants which have been detected in human milk. They have lipophilic properties, so they can penetrate to fatty milk and ultimately to neonate digestive track. Another problem of interest is the presence in milk of heavy metals—arsenic, lead, cadmium, and mercury—as these compounds can lead to disorders in production of cytokines, which are important immunomodulators. The toxicants cause stimulation or suppression of this compounds. This can lead to health problems in children as allergy, disorders in the endocrine system, end even neurodevelopment delay and disorder. Consequently, correlations between pollutants and bioactive components in milk should be investigated. This article provides an overview of environmental pollutants found in human milk as well as of the consequences of cytokine disorder correlated with presence of heavy metals. Graphical abstract

Exposure assessment is an important part in environmental epidemiology for determining the associations of environmental factors with health effects. One of the greatest challenges for personal exposure assessment is associated with peoples’ mobility during the day and spatial and temporal dynamics of air pollution. In this study, the impact of PM₁₀ (particulate matter less than 10 μm) on allergy risk among adults was assessed using objective methods of exposure assessment. The primary objective of the present study was to estimate personal exposure to PM₁₀ based on individual daily movement patterns. Significant differences between the concentration of PM₁₀ in different microenvironments (MEs) and personal exposure to PM₁₀ were determined. Home exposure accounted for the largest part of PM₁₀ exposure. Thirty-five percent of PM₁₀ exposure was received in other non-home MEs. Allergy risk increased significantly with increasing exposure to PM₁₀. Adults exposed to the highest levels of PM₁₀ exposure had a twice-higher risk of allergies than adults exposed to the lowest levels of PM₁₀ exposure. The study results have practical relevance for exposure assessment to environmental factors and its impact on health effects.

A field survey was conducted to investigate metal(loid) concentration in soils and native plants in the Baoshan mining area for potential application in phytoremediation. Total concentrations of arsenic (As), cadmium (Cd), lead (Pb), and zinc (Zn) in soil varied from 125 to 6656, 5.10 to 1061, 568 to 49294, and 241 to 17296 mg kg⁻¹, respectively, showing severe contamination. Among 20 species native to this area, Pteris ensiformis accumulated 1091 mg kg⁻¹ As in the shoot, and its translocation factor (TF) was greater than 1, suggesting potential capacity for As phytoextraction. Boehmeria nivea, Aster prorerus, and Hydrocotyle sibthorpioides showed potential for phytoextraction of Cd due to their high accumulation of Cd in shoots (490.3, 175.4, and 128.5 mg kg⁻¹, respectively) and high TFs (92.0, 22.1, and 6.7, respectively). Eleusine indica and P. ensiformis were found to contain high concentrations of Pb (7474 mg kg⁻¹) and Zn (1662 mg kg⁻¹) in roots, but with low TFs for Pb (0.4) and Zn (0.2), suggesting potential capability for phytostabilization. There was a positive correlation (p < 0.01, N = 25) of TFs between the metal(loid)s, indicating a synergic interaction in the uptake of metal(loid)s by these plants. According to metal(loid) concentrations in shoots, bioconcentration factors (BFs), and TFs, as well as the botanical features such as wide occurrence, high biomass yield, and rapid growth of the plants, the five native species identified above have the potential for phytoremediation in the Baoshan mining area.

The efficiency of heavy metal (HM) phytoextraction from contaminated soil directly depends on the pollutant bioavailability, which can be increased by some soil amendments. In field test, the impacts of soil-applied ethylenediaminetetraacetic acid (EDTA) and amorphous silicon dioxide (ASD) and foliar-applied monosilicic acid (MS) on cadmium (Cd) uptake by rice plants from contaminated paddy soil were investigated. Without EDTA, the solid or liquid Si materials reduced the Cd accumulation in the aboveground part of rice by 26 to 52%. If EDTA was applied, the Cd accumulation by plants was increased by 60 to 92%; however, the biomass was reduced by 16 to 35%. The combined application of Si-rich materials and EDTA provided enhanced plant tolerance to a negative influence of EDTA, while kept high Cd content in the rice stems and leaves. As a result, the Cd amounts extracted by the stems and leaves from the unit area of contaminated paddy soil were greater by 25 and 37% in comparison with those for only EDTA treatment.