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Eco-Engineered Low-Cost Carbosorbent Derived from Biodegradable Domestic Waste for Efficient Total Chromium Removal from Aqueous Environment: Spectroscopic and Adsorption Study
2024
Vandana Saxena, Ashish Kumar Singh, Atul Srivastava and Anushree Srivastava
Chromium contamination in water bodies poses severe risks to both the environment and human health. This research introduces an innovative solution to this challenge by creating a vapor-activated carbosorbent from biodegradable household waste. The efficacy of this adsorbent in removing total chromium through batch methods from aqueous solutions was investigated. Surface analysis using scanning electron microscopy (SEM) exhibited a porous structure, while Fourier-transform infrared spectroscopy (FTIR) identified distinct functional groups on the surface. The point of zero charge (PZC), determined at 6.95, revealed the adsorbent’s surface chemistry. Impressively, the synthesized carbosorbent exhibited significant adsorption capacities of 23.08 mg.g-1 for Cr(III) and 24.84 mg.g-1 for Cr(VI) under optimal conditions. The Langmuir isotherm model illustrated a monolayer adsorption mechanism aligned with the pseudo-second-order kinetic model, confirming chemisorption. Thermodynamic analysis disclosed favorable and spontaneous chromium adsorption. Negative ΔG° values affirmed the spontaneity, while the exothermic nature of the process was signified by the positive ΔH° value, indicating heat release. Increased randomness at the solid-liquid interface, indicated by the positive ΔS° value, underscored the enhanced affinity between the adsorbent and adsorbate. This study exemplifies the potential of the vapor-activated carbosorbent as an efficient and sustainable remedy for chromium-contaminated water bodies.
Afficher plus [+] Moins [-]Coal Mining and MSME: Is it Mutually Beneficial?
2024
S. Bintariningtyas, T. Mulyaningsih and Y. Purwaningsih
The existence of a coal mining company in the vicinity of the community is something to be feared related to environmental damage due to coal mining. On the other hand, coal mining can have a positive impact on the economy of communities around the mine through corporate social responsibility programs. The problem in this research is that MSMEs need help to improve their performance. Therefore, this research aims to examine how the role of mining companies through corporate social responsibility (CSR) programs can contribute to the development of MSMEs in communities around mining areas. The company provides promotional assistance, funding, and capacity building. This research conducted surveys and interviews with respondents, namely MSMEs, around mining locations. The findings show that corporate social responsibility programs in coal mining companies have a positive impact on empowering MSMEs in communities around the mine. By providing training and promotion facilities to MSMEs, mining companies can also improve MSME performance compared to providing access to financial assistance programs. The company not only takes advantage of mining and focuses on its environmental impact but also the company’s role in empowering MSMEs.
Afficher plus [+] Moins [-]Detection of Sulfur Oxidizing Bacteria to Oxidize Hydrogen Sulfide in Biogas from Pig Farm by NGS and DNA Microarray Technique
2024
Siriorn Boonyawanich, Peerada Prommeenate, Sukunya Oaew, Wantanasak Suksong, Nipon Pisutpaisal and Saowaluck Haosagul
A high concentration of hydrogen sulfide (H2S) released from pig farming is one of the major environmental problems affecting surrounding communities. In modern pig farms, the bioscrubber is used to eliminate H2S, which is found to be driven mainly by the sulfur-oxidizing bacteria (SOB) community. Therefore, in this study, molecular biology techniques such as next-generation sequencing (NGS) and DNA microarray are proposed to study the linkage between enzyme activity and the abundance of the SOB community. The starting sludge (SFP1) and recirculating sludge (SFP2) samples were collected from the bioscrubber reactor in the pig farm. The abundance of microbial populations between the two sampling sites was considered together with the gene expression results of both soxABXYZ and fccAB. Based on the NGS analysis, the members of phylum Proteobacteria such as Halothiobacillus, Acidithiobacillus, Thiothrix, Novosphingobium, Sulfuricurvum, Sulfurovum, Sulfurimonas, Acinetobacter, Thiobacillus, Magnetospirillum, Arcobacter, and Paracoccus were predominantly found in SFP2. The presence of Cyanobacteria in SFP pig farms is associated with increased biogas yields. The microarray results showed that the expression of soxAXBYZ and fccAB genes involved in the oxidation of sulfide to sulfate was increased in Halothiobacillus, Paracoccus, Acidithiobacillus, Magnetospirillum, Sphingobium, Thiobacillus, Sulfuricurvum, Sulfuricurvum, Arcobacter, and Thiothrix. Both NGS and DNA microarray data supported the functional roles of SOB in odor elimination and the oxidation of H2S through the function of soxABXYZ and fccAB. The results also identified the key microbes for H2S odor treatment, which can be utilized to monitor the stability of biological treatment systems and the toxicity of sulfide minerals by oxidation.
Afficher plus [+] Moins [-]Study of Chlorella vulgaris from Different Growth Phases as Biosensor for Detection of Titanium and Silver Nanoparticles in Water
2024
Arularasi Thenarasu, Mee Kin Chai, Yeong Hwang Tan, Ling Shing Wong, Ranjithkumar Rajamani and Sinouvassane Djearamane
The increased use of metallic nanoparticles has led to concern for environmental contamination and disruption in water quality. Therefore, effective screening of metallic nanoparticles is important for detecting metallic nanoparticles in aquatic environments. Biosensors offer several advantages, including high sensitivity to pollutants, short response time, energy efficiency, and low waste generation. In this study, a whole-cell biosensor was developed using microalga Chlorella vulgaris as a recognition element, and its fluorescence response was used as a measuring parameter for detecting the presence of titanium dioxide (TiO2) and silver (Ag) nanoparticles in water. The responses of C. vulgaris at the lag, exponential, and stationary phases to different concentrations of TiO2 and Ag nanoparticles were studied. The results showed that in TiO2 and Ag nanoparticles exposures, the highest fluorescence change (50-150%) was observed at the lag phase, whereas the lowest fluorescence change (40-75%) was observed at the stationary phase. A significant fluorescence change was observed in 15 min. The immobilized C. vulgaris under TiO2 and Ag nanoparticles exposures showed 30-180% higher fluorescence change than the negative control, indicating the potential of C. vulgaris as a biosensor for rapid detection of TiO2 and Ag nanoparticles in water. The mathematical modeling of the responses of C. vulgaris to TiO2 and Ag nanoparticles at 15 min of exposure with high R2 indicated that this biosensor is sensitive to the concentration tested (0.010–10.000 mg.L-1). Taken together, these results reveal that, for the first time, it is possible to detect TiO2 and Ag nanoparticles in water within a very short time using a microalgae-based biosensor. Moreover, no genetic engineering requirement makes this biosensor simple, economical, and free from the restriction on genetically modified microorganisms for environmental applications.
Afficher plus [+] Moins [-]Transforming Energy Access: The Role of Micro Solar Dome in Providing Clean Energy Lighting in Rural India
2024
R. Karthik, Ramya Ranjan Behera, Uday Shankar, Priyadarshi Patnaik and Rudra Prakash Pradhan
Access to affordable and reliable energy sources can substantially enhance the lives of marginalized communities in rural areas. Unfortunately, numerous households in these communities rely upon unclean sources of energy such as kerosene to light the house even during daylight. To address this issue, solar off-grid technology - Micro Solar Dome (MSD) was implemented in various states across India, specifically benefiting the scheduled caste and scheduled tribe communities. The study, across the eight selected states, highlights the advantages of adopting off-grid technologies and their roles in promoting awareness of renewable energy solutions. The survey used purposive sampling to collect community members’ perceptions of the product’s benefits and their awareness of renewable technologies. The results indicated that the utilization of the product not only enhanced illumination levels within households but also contributed to improved safety, increased study hours for children, and facilitated economic activities during the evening hours. Furthermore, the study revealed that education plays a crucial role in adopting solar energy. However, interventions such as awareness programs and hands-on experiences with the products can also greatly enhance awareness and promote adoption in rural areas. Overall, the study provided compelling evidence of the significant and positive impact that small-scale initiatives like the MSD can have on the lives of marginalized communities. It also emphasized the potential of such solutions to empower these communities and improve their overall well-being.
Afficher plus [+] Moins [-]Farmers’ Perception and Adaptation Strategies Towards Climate Change: A Village Level Study in India
2024
Dharma Teja Ratakonda, Ajit Kumar Dash and Amritkant Mishra
The present study attempted to observe the perception and adaptation strategies of farmers in the context of climate change. It observes that the majority of the farmers are aware of climate change and understand that they are facing problems due to it. The major problems faced by the farmers are the long duration of dryness due to lack of rainfall, weed pressure, very high temperatures, and crop disease. However, farmers are not very aware of technological adaptation and have changed the cropping time due to changes in the time of monsoon. The study recommends that there is a need for intensive micro and macro policy initiatives in terms of modern green sustainable technology along with awareness and skill development of the farmers. The government should also focus more on policy initiatives for sustainable agricultural practices in line with sustainable development goals.
Afficher plus [+] Moins [-]Determinants Influencing the Environmental Impact Assessment Compliance Rate by Industries in Aba City, Southeast, Nigeria
2024
C. Sam-Amobi, O. J. Ubani, K. Efobi and Nathan Ajukwara
A United Nations (UN) report on the severity of pollution in cities around the world in 2020 rated Aba City, Nigeria, as the most polluted city in the world. This has become a source of worry and embarrassment for environmental policymakers in the country. The matter of whether industries are efficiently managing their wastes came to the fore, and policymakers questioned the compliance of these industries with environmental laws and Environmental Impact Assessment (EIA) guidelines and the reasons behind the seemingly non-compliance of the industries with these guidelines. The study aimed to investigate the determinants that influence compliance with EIA guidelines by industries in Aba. A survey research method was employed in the study. Questionnaires and interviews were also used to elicit data from industrialists and environmentalists in the study area. 384 industries were sampled in the study. Principal Component Analysis was used to test the hypothesis. The study revealed seven factors that influenced the compliance rate of EIA guidelines by industries, and they include weak public participation (65.5%), ignorance (54.5%), an effective legal system and legislation (42.4%), the cost of compliance (40.5%), weak coordination along the line of departments (town planning officers and consultants) (35.5%), delay in approval (30.5%), and limited scope (28.9%). It was recommended that the government strengthen the legal system as it relates to the implementation of EIA; then, there is a need to involve affected stakeholders in the preparation of EIA documents.
Afficher plus [+] Moins [-]Urban Indian Environment in the Context of a Pandemic
2024
Abhijith. S., Akshara S. N. and P. P. Nikhil Raj
The spread of the Coronavirus disease 2019 (COVID-19) has impacted human life severely since November 2019. The urban centers in the world, especially, were highly affected by the diseases. Several socioeconomic and environmental factors probably enhanced the spread of the pandemic and consequent mortality. Many studies examining environmental factors, such as air quality, in urban centers indicate the roles of those factors in the spread of diseases and consequent mortality. However, other socioeconomic factors that directly or indirectly elevate the mass death of people are seldom studied. The present study explores the socioeconomic factors and air quality influencing COVID-19 deaths in urban India. We randomly selected 19 Indian cities and collected each city’s socioeconomic and air quality data from reliable and open sources. The data were analyzed using multivariate data analysis techniques using R statistics. The results showed significant positive relationships, population, and total area of the urban centers.
Afficher plus [+] Moins [-]Mapping and Monitoring of Land Use/Land Cover Transformation Using Geospatial Techniques in Varanasi City Development Region, India
2024
Atul K. Tiwari, Anindita Pal and Rolee Kanchan
Assessing the dynamics and patterns of Land Use and Land Cover (LULC) and its transformation is an important practice of urban planners and environmentalists for a variety of applications, including land management, urban climate modeling, and sustainability of any urban region. Monitoring changes in LULC using geospatial techniques can help to identify areas at risk for indefensible land use, low-grade environment, and especially for sustainable urban planning. This study aims to analyze the changing pattern, dynamics, and alteration of LULC using Google Earth Engine (GEE) and Machine Learning Applications for the years 1991, 2001, 2011, and 2022 in the Varanasi City Development Region (VCDR). The LULC classification was divided into seven classes using random forest classification, and Landsat-5(TM) and 9(OLI-2) satellite data were used. Saga GIS has been utilized for the detection of LULC change during the 1991-2022 period. For validation of classification results, accuracy assessment was estimated using error matrices and through user, producer, and overall accuracy estimation. The Kappa statistics were applied for the reliability of the accuracy assessment result. As a result, the built-up area increased by 507.8 percent, and other classes like agricultural, barren, fallow land, and vegetation cover rapidly declined and altered into concrete areas over the period. Water bodies and river sand classes have been slightly converted into different classes. The finding explains that 114.8 km2 of fertile agricultural land, 14.81 km2 barren land, and 12.93 km2 of vegetation cover transformed into impervious surface, which is unsustainable and causes various problems like food scarcity, environmental degradation, and low quality of urban life. This study can be a useful guide for urban planners, academicians, and policymakers by providing a scientific background for sustainable urban planning and management of VCDR and other cities as well.
Afficher plus [+] Moins [-]Integrated Riverside Development Along Adyar River, Chennai
2024
S. Indhu Kirthika and R. Shanmuga Priyan
Integrated Riverside Development (IRD) is a planning approach that aims to achieve sustainable development of urban areas located along riverbanks. To implement this IRD with controlled regulations, the study is focused on developing a comprehensive riverside development and river zoning regulatory framework that integrates all five main elements, with particular emphasis on economic, ecological, and social factors, in order to reduce encroachment and pollution in the study area. The objectives of the study include analyzing the current land use, recreational parks, encroachments, pollution levels, sewage disposal patterns, and solid waste dumping zones in the study area, as well as studying the socio-economic and eco-environmental aspects of the area. Additionally, identifying and analyzing the major threats to the river and developing a river zoning regulatory framework using the land use matrix technique is also included in the study objectives. The study area (Adyar River) was chosen based on social, ecological, and economic factors, and data was collected through surveys and from government offices. Using the land use matrix method, proposals for riverside development were made, and the zones were classified into development-prohibited, development-restricted, and development-optimized zones. The zones were classified based on the calculated values of Eco sensitivity for each of the three zones. Proposals were then given based on these classified zones, and the levels of development potential were determined. The proposed zoning regulatory framework is expected to have a significant impact in reducing further encroachments and improving connectivity between the city and the river. By considering socio-economic, ecological, and environmental aspects, the study recommends appropriate zoning regulations for riverfront developments that promote sustainable growth.
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