Compressed natural gas is an alternative green fuel for automobile industry. Recently, the Indian government is targeting to replace all the conventional fuel vehicles by compressed natural gas (CNG) automobiles due to its several merits. Still, the presence of a significant amount of CO, CH₄, and NOₓ gases in the CNG vehicle exhaust are quiet a matter of concern. Thus, to control the emissions from CNG engines, the major advances are under development of and oxidation is one of them in catalytic converter. In literature, the catalysts such as noble and non-noble metals have been reported for separate oxidation of CO and CH₄.. Experimentally, it was found that non-noble metal catalysts are preferred due to its low cost, good thermal stability, and molding tractability. In literature, several articles have been published for CO and CH₄ oxidation but no review paper is still available. Thus, the present review provides a comprehensive overview of separate as well as simultaneous CO and CH₄ oxidation reactions for CNG vehicular emission control.

Heavy metals (HMs) being the notorious and toxic are being introduced into the environment credited to natural and anthropogenic activities. The use of ornamental plants is being ignored as potential candidates for HMs phytoremediation. In this study, pot experiments were conducted on Catharanthus roseus (L.) G.Don to evaluate selected heavy metals tolerance and accumulation potential with reference to the bacterial endophyte (Bacillus cereus) and organic amendments (moss and compost at 5% v/v). Results indicated improvement in uptake of Cd (230 mg kg⁻¹), Cu (229 mg kg⁻¹), and Cr (458 mg kg⁻¹) by C. roseus with B. cereus. The concentration of Ni and Pb was found highest in controls (without strain) that were 420 and 904 mg kg⁻¹, respectively. Conversely, the addition of organic amendments enhanced biomass production, as compared to controls, 441, 471, and 763% by peat moss (T3), compost (T4), and peat moss + compost + inoculum treatments (T6), respectively, while reduction of plant HMs content was observed. Microbial-aided phytoremediation/phytoextraction could be a potential method for removal of Cd, Cr, and Cu, while organic amendments can significantly improve plant growth in the presence of heavy metals.

The nitrogen removal efficiency in constructed wetlands (CWs) was largely affected by the dissolved oxygen (DO). In this study, micro-aeration with different numbers of hollow fiber membrane modules (HFMEs) was adopted to increase the oxygen availability and improve the nitrogen removal efficiency in CWs under different air temperatures and different hydraulic retention time (HRT). Compared to the plant oxygen release (ROL) of wetland plants and traditional mechanical aeration, HFME increased the oxygen availability and enhanced the nitrogen removal efficiency in CWs. The COD and NH₄⁺–N removal efficiencies increased with the increase of the HMFE. TN removal efficiency was increased by 8~16% after the application of HFME in CWs in the high-temperature stage. However, less HFME in CW-M1 realized the highest TN removal efficiency in low- and medium-temperature stages. At low temperature after 4-day HRT, the DO concentration respectively reached 6.25 mg L⁻¹ and 3.25 mg L⁻¹ in the upper zone and the bottom of CW-M1. The TN removal efficiencies in the upper zone of CW-M1 (60.69%) and the bottom of CW-M1 (64.98%) were all significantly higher than those in the upper zone of CK (35.98%) and the bottom of CK (39.9%). In addition, the microbial biomass and community analyses revealed that CW-M1 showed the most nitrifying bacteria and the best metabolic activity of bacteria. HEMF in CW-M1 also increased the nitrifying capacity from 0.12 to 0.46 mg kg⁻¹ h⁻¹. The application of HFME in CWs accelerated the nitrification process by enhancing nitrifying bacteria and less HFME realized the highest TN removal efficiency through nitrification-denitrification processes. Graphical abstract The application of hollow fiber membrane modules in CWs enhanced the pollutants (TN and COD) removal efficiency in the process of biological nitrification-denitrification and increased the number of nitrifying bacteria.

The health and environmental consciousness of waste tires has increased tremendously over the years. This has motivated efforts to develop secondary applications that will utilize tire when they reach the end of their life cycle and limit their disposal in landfills. Among the applications of waste tires which are discussed in this review, the use of rubber crumbs in artificial turf fields has gained worldwide attention and is increasing annually. However, there are serious concerns regarding chemicals that are used in the manufacturing process of tires, which ultimately end up in rubber crumbs. Chemicals such as polycyclic aromatic hydrocarbons (PAH) and heavy metals which are found in rubber crumbs have been identified as harmful to human health and the environment. This review paper is intended to highlight some of the methods which have been used to manage waste tire; it also looks at chemicals/materials used in tire compounding which are identified as possible carcinogenic.

This study aimed to determine the arsenic (As), copper (Cu), cadmium (Cd), and lead (Pb) concentrations in the soil at e-waste separating houses in Buriram province. Soil samples were collected from five e-waste separating and five non-separating houses in each of two neighboring communities and from six reference houses located approximately 4 km away from the e-waste community. At each selected house, the surface (0–15-cm depth) and the subsurface (15–30-cm depths) soils were taken to be digested by a microwave digester and then analyzed for the heavy metal contents by atomic absorption spectrophotometry. The As, Pb, and Cd levels in the e-waste separating sites ranged from < 0.012 to 1.380, 0.110 to 15.283, and < 0.014 to 0.284 mg/kg, respectively, which were not in excess of the Thai standard level for residential soil (As = 3.9, Pb = 400, and Cd = 37 mg/kg), while Cu ranged from 1.180 to 380.413 mg/kg and exceeded the intervention value (190 mg/kg) of contaminated soil at three sites from a total of ten sampling sites. The physical e-waste dismantling activity enhanced the As, Cd, and Cu contamination levels in the surface soils. Ecological risk assessment revealed that the risk posed by the heavy metals in soils was higher at the e-waste separating houses than those at the non-separating sites and was mainly attributed to the levels of Cu > As > Cd > Pb for the surface soils and Cd > Cu > As > Pb for the subsurface soil. The association of the heavy metal soil levels with e-waste activity showed that if the e-waste activities were continuously operated, the As and Cu levels in the surface soil were more likely to exceed those levels in the reference houses. A good procedure for e-waste dismantling is necessary to be developed and implemented to prevent soil contamination and other related environmental problems.

Polymer fiber, a kind of versatile material, has been widely used in many fields. However, emerging applications still urge us to develop some new kinds of fibers. Advanced oxidation processes (AOPs) have created a promising prospect for organic wastewater decontamination; thus, it is of important significance to design a kind of special fiber that can be applied in AOPs. In this work, a viable route is proposed to fabricate manganese oxide-supporting melt-spun modified poly (styrene-co-butyl acrylate) fiber, and the prepared fiber has an excellent activity to catalyze H₂O₂ and O₃ to decolorize dye-containing water. The results show that the decolorization of a cationic blue solution can be completely accomplished within 10 min with the prepared fiber as a catalyst, and its decolorization efficiency can reach up to 96.2% within 40 min. The concentration of total organic carbon can decrease from 20.3 to 12.3 mg/L. The prepared fiber can be reused five times without any loss in decolorization efficiency. Compared with other manganese oxide-based catalysts reported in the literature, the prepared fiber also shows many advantages in decolorizing methylene blue such as easy separation, mild reaction condition, and high decolorization efficiency. Therefore, we are confident that the fiber introduced in this study will exhibit a great application potential in the field of dye wastewater treatment.

A series of hydrogel nanocomposites was fabricated by in situ polymerization of 2-(dimethylamino)ethyl methacrylate (DMAEMA) in presence of different amounts of (amine- and alkyl-modified) nanocrystalline cellulose (NCC). Modification and nanocomposites properties were proved by different analysis methods such as Fourier-transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS), and field emission scanning electron microscopy (FE-SEM). The new hydrogel nanocomposites were applied for removing methyl orange (MO) used as anionic dye and presented in process water at different pH values. The effects of the fabrication process such as modification and content of NCC, contact time, and pH value on swelling ratio (SR), and equilibrium adsorption kinetics were studied. Results showed that the swelling ratio of PDMAEMA-based nanocomposites varied with the different types of nanoparticles showing the significant effect of the modification process. The MO adsorption into the hydrogel nanocomposites was affected by intermolecular and electrostatic interactions between functional groups of hydrogel and dye. The adsorption capacity decreased at high pH value, and it was significantly affected type of nanoparticles introduced into the hydrogel network. The addition of unmodified NCC did not affect adsorption kinetics significantly. Finally, adsorption kinetics was investigated by pseudo-first-order, pseudo-second-order and intraparticle diffusion models where pseudo-first-order model showed the best correlation with experimental results.

Fluoroquinolones (FQs) present in water environments pose threats to aquatic organisms. The concentration of FQs adsorbed onto sediments is generally higher than that in water. Here, we studied the toxicities of two FQ antibiotics, norfloxacin (NOR) and ofloxacin (OFL), on the snail Bellamya aeruginosa, an adaptable benthic animal. For this, we performed acute toxicity experiments on young snails and sub-chronic exposure experiments on adult snails by exposure to the FQs for 1–28 days. The 96 h median effective concentrations showed that NOR toxicity was higher than OFL toxicity, although both NOR and OFL were low-toxicity substances (EC₅₀ > 100 mg L⁻¹). Four concentrations were used in the sub-chronic exposure experiments. Results of the measurement of bioconcentration factors (BCF) showed that OFL accumulation was higher than NOR accumulation in snail tissues. During the depuration period (28–49 days), at low concentrations (2 and 20 μg L⁻¹), both FQs required at least 7 days to reach the maximum residue limit (50 μg kg⁻¹). Conversely, at high concentrations (200 and 2000 μg L⁻¹), 14 days (NOR) and 21 days (OFL) were required. Our results could facilitate management of the environmental risks of antibiotics and conservation of aquatic animals.

Numerous mitigation techniques have been incorporated to capture or remove SO₂ with flue gas desulfurization (FGD) being the most common method. Regenerative FGD method is advantageous over other methods due to high desulfurization efficiency, sorbent regenerability, and reduction in waste handling. The capital costs of regenerative methods are higher than those of commonly used once-through methods simply due to the inclusion of sorbent regeneration while operational and management costs depend on the operating hours and fuel composition. Regenerable sorbents like ionic liquids, deep eutectic solvents, ammonium halide solutions, alkyl-aniline solutions, amino acid solutions, activated carbons, mesoporous silica, zeolite, and metal-organic frameworks have been reported to successfully achieve high SO₂ removal. The presence of other gases in flue gas, e.g., O₂, CO₂, NOx, and water vapor, and the reaction temperature critically affect the sorption capacity and sorbent regenerability. To obtain optimal SO₂ removal performance, other parameters such as pH, inlet SO₂ concentration, and additives need to be adequately governed. Due to its high removal capacity, easy preparation, non-toxicity, and low regeneration temperature, the use of deep eutectic solvents is highly feasible for upscale utilization. Metal-organic frameworks demonstrated highest reported SO₂ removal capacity; however, it is not yet applicable at industrial level due to its high price, weak stability, and robust formulation.

Facilitated by a receding sea ice extent, new and shorter routes have led to increased maritime traffic in Arctic areas with an inherent risk for oil spills along Arctic rocky shorelines. To estimate natural oil removal under Arctic conditions, a crude oil and a heavy fuel oil were applied to slate tiles, mimicking rocky shore substratum, and placed at four levels within and just above the tidal zone on two rocky shorelines in West Greenland. Tiles were regularly sampled (within 95 days) to determine natural oil removal and chemical composition of the remaining oil. We found that natural oil removal on the rocky shorelines depends on (1) level position on the shoreline, i.e., within and above the tidal zone where ample exposure to water and wave-wash increases oil removal rate and efficiency, and (2) physical and chemical oil properties with the crude oil being removed more readily than the heavy fuel oil. These findings can help improve the risk assessment of oil spills in Arctic areas and facilitate the development of effective oil spill response strategies in Arctic seas.