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Water Quality Assessment of Perak River, Malaysia
2019
Salam, M. A. | Kabir, M. M. | Yee, L. F. | A/l Eh Rak, A. | Khan, M. S.
The present investigation has been conducted to assess the status of physico-chemical parameters as well as the concentrations of some selected heavy metals to understand the present scenario of water quality at Perak River basin, Malaysia. The temperature, turbidity, pH, EC and DO values of all the examined samples have been within the range of 25.0 to 30.5 0C, 39.5 to 168.00 NTU, 6.8 to 7.33, 30.3 to 113.8 μs/cm and 3.62 to 7.01 mg/L, respectively. The concentrations of trace metallic constituents have been determined by means of Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES), giving the following ranges: Cr: 0.01 to 0.052 mg/L; Pb: 0.01 to 0.03 mg/L; Zn: 0.11 to 0.92 mg/L; Fe: 1.38 to 5.55 mg/L; Mn: 0.10 to 0.25 mg/L and Ca: 2.55-23.23 mg/L, respectively. The concentrations of heavy metals at downstream of Perak River water were higher than the concentrations of upstream. The order of heavy metallic constituents in the water samples was Fe > Zn > Mn > Cr > Pb. R mode Cluster Analysis (CA) suggests that multiple anthropogenic activities like urban runoff, agricultural runoff, discharges of vehicles washing and workshops, land use changes, unplanned settlements, domestic effluents, wastewater of livestock husbandry farms etc., are influencing the physico-chemical parameters and heavy metals concentrations of Perak River water. The present study is highly significant for providing baseline information of potential hazardous level of heavy metals to human health, environment, and sustainable water resources management for economically and environment friendly uses of Perak River.
Afficher plus [+] Moins [-]Monitoring of Zn and Cr in Downstream Water from Uzunçayır Dam in Turkey
2019
Topal, M. | Arslan Topal, E. I.
In this study, the concentrations of Zn and Cr in downstream waters from Uzunçayır Dam (Tunceli, Turkey) were monitored during spring (March, April, May) and summer (June, July, August) season. Zinc and Cr concentrations in surface water samples were detected using the ICP-MS device. According to the data obtained the lowest Zn and Cr concentrations in the spring season were 65.43±3.2 μg/L in March at 10th day for Zn and 0.28±0.02 μg/L in March at 10th and 20th day for Cr, the highest Zn and Cr concentrations were determined to be 83.12±4.1 μg/L in May at day 30 for Zn and 0.48±0.02 μg/L in May at day 30 for Cr. The lowest Zn and Cr concentrations in summer season were 55.48±2.7 μg/L at 30th day in August for Zn and 0.54±0.03 μg/L at 10th day in June for Cr. The highest Zn and Cr concentration in summer season were found as 69.48±3.5 μg/L in June at day 10 for Zn and 1.23±0.06 μg/L in August at day 30 for Cr. The Zn and Cr concentrations in the downstream of Uzunçayır Dam were found to be smaller than the Zn and Cr concentrations given by the Surface Water Quality Regulation (SWQR). As a result, it was determined that there was no harm in using water from the Uzunçayır Dam as irrigation water or drinking water in terms of Zn and Cr concentrations.
Afficher plus [+] Moins [-]Prioritization of Environmental Sensitive Spots in Studies of Environmental Impact Assessment to Select the Preferred Option, Based on AHP and GIS Compound in the Gas Pipeline Project
2019
Padash, A. | Ataee, S.
Environmental assessments are essential in order to align the process of country's progress towards sustainable development. It is important for the project to be implemented in direction of sustainable development, which is to carry out a project in such a way that in both short and long term, the greatest advantages and the least harm are inflicted on the environment, economy, communities, and culture. Environmental assessment of gas pipelines is classified as a linear projects; therefore, the design and implementation of an appropriate method in accordance with the project's linearity, due to the use of GIS tools and multi-criteria decision-making methods, can be a good innovation for this study, in comparison to previous similar projects. The purpose of this study is to identify the best option for gas pipelines. Once the project's study scope is specified, the study based the sensitive environmental parameters of the area (based on the requirements of environmental impact assessment reports) on two methods of Analyzing Hierarchical Process (AHP) and overlaying methods for sub-parameters, ranking and prioritizing the area of evaluation. Based on the results, the first and second priorities belong to the parameter of distance and position in the protected areas with a weight of 29.9% and hydrology with a weight of 24.7%, followed by slope, vegetation, land use, and fault, which are ranked third to seventh, respectively. After identifying the best map option, the study extracts the critical points for the construction of pipelines, identifies the negative effects of the project, and presents the environmental impacts and preventive measures, reduction and compensation of negative effects in both construction and operation phases, along with a summary of the Environmental Management Program (EMP).
Afficher plus [+] Moins [-]Remediation of Lead-Contaminated Soil, Using Clean Energy in Combination with Electro-Kinetic Methods
2019
Hussein, A. A. | Alatabe, M. J. A.
The present study aims at investigating the feasibility of using solar energy as a power source to run electro-kinetic remediation in order to clean-up lead from three types of Iraqi soil. In order to do so, it carries out six tests with enhancement conditions, involving pH control and injection wells. Conducted in the city of Baghdad, Iraq, the experiment, is divided into two groups so that the effect of applying continuous and constant voltage from solar panels study, by means of charge control and battery along with non-continuous and non-constant DC voltage from solar panel could be studied. The DC voltage has been generated by two Solar panels, each with a maximum voltage of 17 volts. All experiments have commenced in March 2017, wherein the soil has been contaminated with a concentration of Pb, equal to 1500 mg/kg as well as initial moisture content equal to 30%. The remediation lasts for seven days, with a potential gradient of about 1.2 V/cm. At the end, the experimental results show that the overall removal efficiencies of 90.7%, 63.3%, and 42.8% have been achieved for sandy, sandy loam, and silty loam soils, respectively, when using solar panels with charge control and battery.
Afficher plus [+] Moins [-]Optimization of significant factors on the microbial decolorization of azo dye in an aqueous medium by Design of Experiments
2019
Palanivelan, R. | Ayyasamy, P. M. | Ramya, S.
Currently, the reduction of reactive dyes present in the textile effluent is a big challenge due to the threat to the environment. Existing physical and chemical methods contains many drawbacks. In the present scenario microbial reduction pays much attention and current focus of research. Therefore, the present study isolated dye decolorizing bacterium Exiguiobacterium aurantiacum (TSL7) from activated sludge and identified by molecular techniques and 16S rDNA sequences. Decolorization was not established in Bushnell hass broth composition in accordance with absence of carbon and nitrogen source. The three environmental factors pH, starch and beef extract were selected from Plackett-Burman design experiments. The central composite design was employed to optimize the maximum removal of remazol golden yellow (91.83%) with pH, 6.89, starch, 0.49% (w/v) and beef extract 0.67% (w/v) respectively, These key factors playing a major role in the bacterial dye removal and the interactions were evaluated statistically. The optimal value of significant factors supports to maximize the dye removal competency of isolated bacterium. Thus results exhibited that local salt tolerant bacterium Exiguiobacterium aurantiacum (TSL7) could be a potential candidate for an in situ-bioremediation of inorganic salts abundant textile effluents in the textile industry.
Afficher plus [+] Moins [-]Convenient and Efficient Elimination of Heavy Metals from Wastewater Using Smart Pouch with Biomaterial
2019
Malik, R. | Saini, N. | Ahlawat, S. | Singhal, S. | Lata, S.
A newly developed Smart Pouch with enclosed biomaterial (Aloe vera and coconut husk powder) has been experimented for elimination of heavy metals i.e. (Pb2+, Cu2+, Ni2+ and Zn2+) from wastewater. The effect of concentration, pH, temperature, contact duration etc. was investigated using batch experiments which resulted that the Pouch may be accepted for convenient, efficient and low-cost accumulation of several heavy metals simultaneously from waste water. The maximum Pb removal was 99.99%, 93.21% for Cu, and for Ni, it was 91.97% whereas for Zn, 86.41% was obtained and also, the uptake capacity of pouch was quite sensitive towards initial metal concentration in the studied range of 10-200mg/L present in wastewater. The findings were further interpreted by quantum chemical study as theoretical support, various adsorption isotherms, FTIR, SEM, XRD, and physiochemical properties of metal ions to justify the synergized performance of new Pouch. A good correlation was found between experimental methods and theoretical findings.
Afficher plus [+] Moins [-]The Effects of Nitrogen Fixing Tree (Leucaena leucocephala) and Mushroom (Pleurotus tuber-regium) on Spent Engine Oil Polluted Soil
2019
Adanikin, B. A. | Kayode, J.
Greenhouse experiment was conducted for four months using Leucaena leucocephala and Pleurotus tuber-regium to determine their bioremediation potentials. Leucaena leucocephala, Pleurotus tuber-regium and Leucaena leucocephala combined with Pleurotus tuber-regium were tested for their ability to improve nutrient (N, P, K, total organic carbon) and reduce heavy metals (Zn, Ni, Pb, Cu) of soil polluted with spent engine oil [5% (w/v)] and soil without spent engine oil was used as control. Bioaccumulation of nutrients and heavy metals in Leucaena leucocephala and Pleurotus tuber-regium were also determined. The highest reduction in Zn, Ni, Pb and Cu (41%, 48.39%, 61.60 and 52.72% respectively) were recorded in soil remediated with Leucaena leucocephala alone, reduction of 30.40%, 26.53%, 48.07% and 39.60% respectively were recorded in soil remediated with Pleurotus tuber-regium alone while in soil remediated with combined Pleurotus tuber-regium and Leucaena leucocephala, reductions of 32.7%, 33.43%, 88.41% and 46.22% respectively were recorded. Bioaccumulation of Zn, Ni, Pb and Cu in Leucaena leucocephala increased by 73.41%, 85.46%, 3366.04% and 125.53% respectively, similarly in Pleurotus tuber-regium by 30.16%, 21.67%, 71.11% and 53.21% respectively. These studies have shown that Pleurotus tuber-regium and Leucaena leucocephala are capable of bioremediating spent engine oil polluted soil although, treatment with Leucaena leucocephala alone tends to be most effective of these treatments.
Afficher plus [+] Moins [-]Solute Transport for Pulse Type Input Point Source along Temporally and Spatially Dependent Flow
2019
Yadav, R. R. | Kumar, L. K.
In the present study, analytical solutions are obtained for two-dimensional advection dispersion equation for conservative solute transport in a semi-infinite heterogeneous porous medium with pulse type input point source of uniform nature. The change in dispersion parameter due to heterogeneity is considered as linear multiple of spatially dependent function and seepage velocity whereas seepage velocity is nth power of spatially dependent function. Two forms of the seepage velocity namely exponentially decreasing and sinusoidal form are considered. First order decay and zero order production are also considered. The geological formation of the porous medium is considered of heterogeneous and adsorbing nature. Domain of the medium is uniformly polluted initially. Concentration gradient is considered zero at infinity. Certain new transformations are introduced to transform the variable coefficients of the advection diffusion equation into constant coefficients. Laplace Transform Technique (LTT) is used to obtain analytical solutions of advection-diffusion equation. The solutions in all possible combinations of temporally and spatially dependence dispersion are demonstrated with the help of graphs.
Afficher plus [+] Moins [-]Evaluating the effectiveness of Tamarindus indica partially activated seed coat biomass in removing of nitrates from aqueous solutions
2019
Srinivasulu, D. | Naidu, GRK | P. K., Pindi
Biomass derived from Tamarindus indica partially activated seed coat was investigated for the removal of nitrate ions from aqueous solutions. Batch experiments were performed to evaluate the parameters like pH, contact time, sorbent dose and initial nitrate concentration. pH of the solution played vital role. The maximum sorption observed at pH=7, sorbent dose 300mg, contact time at 120min, initial nitrate concentration 5mg. Physicochemical properties of the biomass were evaluated using scanning electron microscopy (SEM), energy dispersive X-ray analysis and Fourier Transform infra red (FTIR) spectroscopy. The SEM and FTIR data reveals the suitable surface and the presence of chemical functional groups such as hydroxyl, amide, carbonyl strong acid and primary amine on the biosorbent surface contributes to biosorption. The equilibrium isotherms and kinetics were deliberated. Biosorption equilibrium followed Langmuir isotherm. Pseudo second order kinetics provided better correlation of the experimental data in comparison with pseudo-first-order kinetic model. The study indicated that Tamarindus indica partially activated seed coat biomass found to be a novel biosorbent for the removal of nitrates from aqueous solutions.
Afficher plus [+] Moins [-]Model for the Treatment of Refinery Wastewater and expression of catabolic genes in Fluidized Bed Bioreactor using mixed bacterial consortium
2019
Ajao, A. T. | Mustapha, M. O. | Yakubu, S. E.
This study was undertaken to evaluate a novel aerobic wastewater treatment model for the remediation of refinery effluents and to assess the removal efficiency of Bulkholderia cepacia strain AJI and Corynebacterium kutscheri strain AJ2 to clean oil waste from petrochemical company. Wastewater quality parameters including pH, BOD5, COD, TDS, OIL & GREASE, PHENOL concentration, TPH and THC were monitored at 5, 10 and 15 days of treatment and the removal efficiencies were calculated. Results indicated that the raw oily wastewater effluents used during this study had extremely high levels of all the tested parameters. The mean values of all physicochemical parameters of the wastewater from primary tank at different treatment period were statistically different (P˂0.001) After 15 days of biological treatment, BOD5 ,COD, TDS, Phenol, TPH, Oil & grease level of the refinery wastewater were reduced by 95.60 %, 98.40 % , 66.34 % , 100 %, 97.60 % and 96.20 % respectively. The detection of the catabolic genes in the bacterial isolates recovered from primary tank using polymerase chain reaction revealed that both Bulkholderia cepacia strain AJ1 and Corynebacterium kutsheri strain AJ2 carried alk B and C23O but C12O was not detected in both isolates. Naphthalene dioxygenase was detected in Bulkholderia cepacia strain AJ1 but not found in Corynebacterium kutscheri strain AJ2. After treatment the waste water was filtered in the secondary tank. The results of physicochemical parameters in the outlet vessel essentially confirmed that the mixed culture in the two column model successfully carry out bioremediation of refinery wastewater. Therefore, aerobic treatment model for the bioremediation of refinery Petroleum refineries generate great amounts of wastewaters that may become seriously dangerous, leading to the accumulation of toxic products in the receiving water bodies with potentially serious long term effects to aquatic biota. Due to extreme toxicity of contaminants in refinery wastewater, there is a need to develop an economical technique to remove the pollutants from the wastewater is highly recommended owing its environmental friendliness.
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