3D hierarchical porous biochar (HPBC) was synthesized by a thermally removable template without post-activation. Zn(NO₃)₂ decomposition produced gases and ZnO in situ to activate and expand the three-dimensional micro-and mesopores. Compared with pristine biochar (BC), the specific surface area and pore volume of HPBC were increased by 223 and 75 times, respectively. The abundant pore structure of HPBC significantly enhanced the diffusion rate of heavy metals. For example, compared to BC, the time required for HPBC to adsorb Pb²⁺ reach adsorption equilibrium was reduced by 87.5% (40 min vs 5min). Such an adsorption performance of HPBC was also insensitive to different background ions (K⁺, Na⁺, Ca²⁺, and Mg²⁺) with a much higher concentration than that of heavy metals. When applied to treat desulfurization wastewater from power plants, HPBC yielded 100% removal of Pb²⁺ and Cd²⁺, much higher than that by using commercial activated carbon (28%). Molecular dynamics simulation revealed different locations preferred by the adsorption of Pb²⁺ (micropores) and Cd²⁺ (mesopores) in the hierarchical pore structures. The adsorption of Pb²⁺ and Cd²⁺ on HPBC was mainly achieved by diffusion, oxygen functional group complexation, and precipitation. These results provided better knowledge to understand the microscopic adsorption mechanisms of heavy metals in hierarchical pores and a facile yet robust strategy to design such structures in biochar for efficient wastewater treatment.

Catalytic pyrolysis is a promising chemical recycling technology to supplement mechanical recycling since plastics can be broken down into monomers or converted to the required fuels and chemicals. In this study, a microwave (MW) -responsive SiC foam@zeoltie core-shell structured catalyst was proposed for the catalytic pyrolysis of polyolefins. Under microwave irradiation, the SiC foam core works as both microwave adsorber and catalyst support, thus concentrating the generated heat energy on the ZSM-5 zeolite shell, where the catalytic reaction takes place. SiC foam with an open cellular structure can also improve the global transport of mass and heat during plastics pyrolysis. In this work, the effects of the SiO₂/Al₂O₃ ratio and alkaline treatment of ZSM-5 zeolite coated SiC foam under MW irradiation on the variations in product distribution from low-density polyethylene (LDPE) pyrolysis were investigated at 450 °C. The results indicated that the appropriate acidity and pore structure were crucial to upgrading gas and liquid products. Particularly, the creation of a mesoporous structure in ZSM-5 zeolite via alkaline treatment could improve the diffusion of large molecules and products, thus significantly increasing the selectivity of high-valued light olefins and aromatics while inhibiting the formation of unwanted alkanes, which are expected in the chemical industry. Concretely, the concentration of olefins in gas increased to 51.0 vol% for ZSM-5(50)-0.25AT, and 65.6 vol% for ZSM-5 (50)-0.50AT, compared with 45.2 vol% for the parent ZSM-5(50). The relative concentration of aromatics in liquid decreased from 96.6% for ZSM-5(50) to 75.9% for ZSM-5(50)-0.25AT, and 71.1% for ZSM-5(50)-0.50AT. Given the respective yield of gas and liquid, the total selectivity of C2–C4 olefins and aromatics for mesoporous ZSM-5 zeolites could reach 58.6–64.9% during LDPE pyrolysis, which were higher than that for the parent ZSM-5 zeolite.

In this study, we firstly used alginate to enhance an electrokinetic technology to remediate soil contaminated with divalent heavy metals (Pb²⁺, Cu²⁺, Zn²⁺). The mechanisms of alginate-associated migration of metal ions in electric field were confirmed. Alginate resulted in a high electrical current during electrokinetic process, and soil conductivity also increased after remediation. Obvious changes in both electroosmotic flow and soil pH were observed. Moreover, these factors were affected by increasing alginate dosage. The highest Cu (95.82%) and Zn (97.33%) removal efficiencies were obtained by introducing 1 wt% alginate. Alginate can desorb Cu²⁺ and Zn²⁺ ions from soil by forming unstable gels, which could be dissociated through electrolysis. However, Pb²⁺ ions did not easily migrate out of the contaminated soil. The density functional theory (DFT) calculations show Pb²⁺ ions could form a more stable coordination sphere in metal complexes than Cu²⁺ and Zn²⁺ ions. The metal removal efficiency was decreased by increasing alginate dosage at a high level. More alginate could provide more carboxyl ligands for divalent metal ions to stabilize gels, which were difficult to dissociate by electrolysis. In summary, the results indicate it is potential for introducing alginate into an electrokinetic system to remediate Cu- and Zn- contaminated soil.

Traffic contributes to fine particulate matter (PM₂.₅) in the atmosphere through engine exhaust emissions and road dust generation. However, the evolution of traffic related PM₂.₅ emission over recent years remains unclear, especially when various efforts to reduce emission e.g., aftertreatment technologies and high emission standards from China IV to China V, have been implemented. In this study, hourly elemental carbon (EC), a marker of primary engine exhaust emissions, and trace element of calcium (Ca), a marker of road dust, were measured at a nearby highway sampling site in Shanghai from 2016 to 2019. A random forest-based machine learning algorithm was applied to decouple the influences of meteorological variables on the measured EC and Ca, revealing the deweathered trend in exhaust emissions and road dust. After meteorological normalization, we showed that non-exhaust emissions, i.e., road dust from traffic, increased their fractional contribution to PM₂.₅ over recent years. In particular, road dust was found to be more important, as revealed by the deweathered trend of Ca fraction in PM₂.₅, increasing at 6.1% year⁻¹, more than twice that of EC (2.9% year⁻¹). This study suggests that while various efforts have been successful in reducing vehicular exhaust emissions, road dust will not abate at a similar rate. The results of this study provide insights into the trend of traffic-related emissions over recent years based on high temporal resolution monitoring data, with important implications for policymaking.

The use of membrane-based technology has evolved into an important strategy for supplying freshwater from seawater and wastewater to overcome the problems of water scarcity around the world. However, the presence of natural organic matter (NOM), including humic substances affects the performance of the process. Here, we present a systematic report on the mineralization of humic acid (HA), as a model for NOM, in high concentration of salts using the ultraviolet light-activated peroxymonosulfate (UV/PMS) system as a potential alternative for HA elimination during membrane-based seawater desalination and water treatment processes. Effects of various parameters such as PMS concentration, solution type, pH, anions, and anion-cation matrix on HA mineralization were assessed. The results show that 100%, 78% and 58% of HA (2 mg/L TOC) were mineralized with rate constants of 0.085 min⁻¹, 0.0073 min⁻¹, and 0.0041 min⁻¹ after 180 min reaction time at pH 7 when 0.5 mM PMS was used in deionized water, sodium chloride solution (35,000 ppm) and synthetic seawater, respectively. The reduced efficiency under saline conditions was attributed to the presence of anions in the system that acted as sulfate and hydroxyl radicals’ scavengers. Furthermore, the safety of the treated synthetic seawater was evaluated by analyzing the residual transformed products. Overall, pretreatment with the UV/PMS system mitigated fouling on the RO membrane.

Phytoextraction using hyperaccumulator, Pteris vittata, to extract arsenic (As) from soil has been applied to large areas to achieve an As removal rate of 18% per year. However, remarkable difference among different studies and field practices has led to difficulties in the standardization of phytoextraction technology. In this study, data on As concentration in P. vittata and related environmental conditions were collected through literature search. A conceptual framework was proposed to guide the improvement of phytoextraction efficiency in the field. The following influencing factors of As concentration in this hyperaccumulator were identified: total As concentration in soil, soil available As, organic matter in soil, total potassium (K) concentration in soil, and annual rainfall. The geodetection results show that the main factors that affect As concentration in P. vittata include soil organic matter (q = 0.75), soil available As (q = 0.67), total K (q = 0.54), and rainfall (q = 0.42). The predictive models of As concentration in P. vittata were established separately for greenhouse and field conditions through multivariate linear stepwise regression method. Under greenhouse condition, soil available As was the most important influencing factor and could explain 41.4% of As concentration in P. vittata. Two dominant factors were detected in the field: soil available As concentration and average annual rainfall. The combination of these two factors gave better prediction results with R² = 0.762. The establishment of the model might help predict phytoextraction efficiency and contribute to technological standardization. The strategies that were used to promote As removal from soil by P. vittata were summarized and analyzed. Intercropping with suitable plants or a combination of different measures (e.g., phosphate fertilizer and water retention) was recommended in practice to increase As concentration in P. vittata.

The influences of weather and air pollutants on chronic obstructive pulmonary disease (COPD) have been well-studied. However, the heterogeneous effects of different influenza viral infections, air pollution and weather on COPD admissions and re-admissions have not been thoroughly examined. In this study, we aimed to elucidate the relationships between meteorological variables, air pollutants, seasonal influenza, and hospital admissions and re-admissions due to COPD in Hong Kong, a non-industrial influenza epicenter. A total number of 507703 hospital admissions (i.e., index admissions) and 301728 re-admission episodes (i.e., episodes within 30 days after the previous discharge) for COPD over 14 years (1998–2011) were obtained from all public hospitals. The aggregated weekly numbers were matched with meteorological records and outdoor air pollutant concentrations. Type-specific and all-type influenza-like illness positive (ILI+) rates were used as proxies for influenza activity. Generalized additive models were used in conjunction with distributed-lag non-linear models to estimate the associations of interest. According to the results, high concentrations of fine particulate matter, oxidant gases, and cold weather were strong independent risk factors of COPD outcomes. The cumulative adjusted relative risks exhibited a monotone increasing trend except for ILI+ B, and the numbers were statistically significant over the entire observed range of ILI+ total and ILI+ A/H3N2 when the reference rate was zero. COPD hospitalization risk from influenza infection was higher in the elderly than that in the general population. In conclusion, our results suggest that health administrators should impose clean air policies, such as strengthening emissions control on petrol vehicles, to reduce pollution from oxidant gases and particulates. An extension of the influenza vaccination program for patients with COPD may need to be encouraged: for example, vaccination may be included in hospital discharge planning, particularly before the winter epidemic.

Estuaries are subject to intense human use globally, with impacts from multiple stressors, such as metal contaminants. A key challenge is extending beyond traditional monitoring approaches to understand effects to biota and system function. To explore the metabolic effects of complex metal contaminants to sediment dwelling (benthic) fauna, we apply a multiple-lines-of-evidence approach, coupling environmental monitoring, benthic sampling, total metals analysis and targeted metabolomics.We characterise metabolic signatures of metal exposure in three benthic invertebrate taxa, which differed in distribution across sites and severity of metal exposure: sipunculid (very high), amphipod (high), maldanid polychaete (moderate). We observed sediment and tissue metal loads far exceeding sediment guidelines where toxicity-related adverse effects may be expected, for metals including, As, Cd, Pb, Zn and Hg.Change in site- and taxa-specific metabolite profiles was highly correlated with natural environmental drivers (sediment total organic carbon and water temperature). At the most metal influenced sites, metabolite variation was also correlated with sediment metal loads. Using supervised multivariate regression, taxa-specific metabolic signatures of increased exposure and possibility of toxic effects were characterised against multiple reference sites. Metabolic signatures varied according to each taxon and degree of metal exposure, but primarily indicated altered cysteine and methionine metabolism, metal-binding and elimination (lysosomal) activity, coupled to change in complex biosynthesis pathways, responses to oxidative stress, and cellular damage.This novel multiple-lines-of-evidence approach combining metabolomics with traditional environmental monitoring, enabled detection and characterisation of chronic metal exposure effects in situ in multiple invertebrate taxa. With capacity for application to rapid and effective monitoring of non-model species in complex environments, these approaches are critical for improved assessment and management of systems that are increasingly subject to anthropogenic drivers of change.

To study the early colonization processes, polyethylene terephthalate (PET) microfragments were immersed in Lake Sakadaš and the Drava River and sampled weekly together with the surrounding biotic communities - phytoplankton, zooplankton, epixylon in the lake and epilithon in the river. At the end of the study, a rise in water level occurred in the river, which altered the environmental conditions and plankton communities. In studied environments, all of the sampled biotic communities were diverse and abundant. Plastispheres formed in both waters by the seventh day of incubation and developed rapidly, reaching a peak in abundance on the last day of the study. Initial colonization was supported equally by planktonic and periphytic taxa in both environments, but after initial settlement, plastisphere assemblages were affected differently in the river and lake. This study suggests that PET microfragments are a suitable substrate for microphyte settlement and may provide an important pathway for their transport in dynamic freshwater floodplains and river systems.