Chlorpheniramine is a pharmaceutical pollutant and a precursor of carcinogenic nitrosamines during disinfection/oxidation. In our previous study, graphene oxide coated with magnetite (GO-Fe₃O₄) was capable of removing chlorpheniramine in deionized water by adsorption. This study investigated the removal of chlorpheniramine and its nitrosamine formation potentials (FPs) by adsorption onto magnetic GO-Fe₃O₄, with respect to the influence by using real municipal wastewaters as the background. In the results, the adsorption performances of chlorpheniramine in wastewaters decreased in the order: GO-Fe₃O₄ suspension > GO-Fe₃O₄ particles > activated carbon. Chlorpheniramine adsorptions on GO-Fe₃O₄ particles and activated carbon were reduced by using real wastewaters as the background, whereas chlorpheniramine adsorption on GO-Fe₃O₄ suspension was enhanced due to the effects of surface charge on GO-Fe₃O₄ and ionic strength variation in water. The fittings of adsorption isotherms indicated that the wastewater background reduced the surface heterogeneity of GO-Fe₃O₄ suspension and improved the adsorption performance. Appreciable removal efficiencies of NDMA and other nitrosamine FPs were observed when GO-Fe₃O₄ particles were added in real wastewaters. However, when chlorpheniramine was present in wastewaters, chlorpheniramine adsorption and degradation reaction simultaneously occurred on the surface of GO-Fe₃O₄, increasing NDMA and other nitrosamine FPs in wastewaters after GO-Fe₃O₄ addition for chlorpheniramine adsorption. The assumption was further demonstrated by observing the NDMA-FP increase during chlorpheniramine adsorption on GO-Fe₃O₄ in deionized water. GO-Fe₃O₄ is a potential adsorbent for chlorpheniramine removal. Nevertheless, the low treatment efficiencies at high doses limit its application for nitrosamine FP adsorptions in real wastewaters.

In order to study the radon release behavior when heap leaching uranium ores with dilute sulfuric acid, unleached uranium ores from a uranium mine in southern China were selected as test samples. Adopting parameters from leaching processes commonly used in uranium mines, a laboratory experiment was carried out for 21 days with a one-dimensional acid heap leaching experimental column. The surface radon exhalation rate of uranium ore column was determined by static accumulation method while spraying with deionized water and dilute sulfuric acid. The uranium leaching rate and ore column height for all 21 days of the experiment were also measured. The results show that (1) when sprayed with a leaching agent, the surface radon exhalation rate of uranium ore column initially increased with time sharply. After a maximum value was reached, the rate gradually decreased and stabilized. When the spraying stopped, the surface radon exhalation rate of uranium ore column initially decreased, before increasing until it tended to stabilize. (2) During the entirety of the 21-day leaching experiment, the cumulative leaching rate of uranium increased gradually with time. On the other hand, the surface radon exhalation rate of uranium ore column fluctuated, but the leaching of uranium from uranium ores had almost no effect on the radon exhalation rate. (3) There was no linear correlation between the surface radon exhalation rate and the residual height of ore column during leaching, but the collapsing event of ore column was the direct inducing factor of the fluctuation of surface radon exhalation rate.

The current study investigated the influence of organic amendments on cadmium (Cd) uptake and its effects on biochemical attributes of young and old leaves of bean. Bean seedlings were exposed to two levels of Cd (25 and 100 μM) in the presence and absence of different levels of ethylenediaminetetraacetic acid (EDTA) and citric acid (CA). An increase in Cd concentration in growth medium significantly enhanced Cd accumulation in bean roots and shoot. Cadmium stress increased the production of H₂O₂ which resulted in lipid peroxidation and decreased chlorophyll contents. The presence of organic amendments significantly affected Cd accumulation and toxicity to bean plants. Application of EDTA alleviated Cd toxicity in terms of chlorophyll contents, H₂O₂ contents, and lipid peroxidation possibly by chelating toxic Cd ions, and as such forming Cd-EDTA complexes. The presence of CA decreased Cd toxicity by decreasing its uptake. The biochemical responses (H₂O₂ contents, lipid peroxidation, and chlorophyll contents) of bean plants were more severely affected by Cd treatments in old leaves compared to young leaves. This study shows that the effect of CA and EDTA on biochemical behavior of Cd varies greatly with applied levels of Cd and amendments as well as the age of leaves. Based on the results, it is proposed that the presence of organic amendments can greatly affect biogeochemical behavior of Cd in the soil-plant system (ecosystem).

Urban forests are exposed to metals, such as manganese, copper, and zinc in the atmosphere that originate from anthropogenic activities, that include vehicle-related traffic, industries, construction sites, fossil fuel burning for heating and cooking purposes, and resuspension processes related to urban surfaces. Not only is the rich biodiversity of plant and animal species in forests under threat, but so are the biodiversity of soil, sustaining ecosystem functions, as well as human health. The objective of this study was therefore to determine the concentrations of manganese, copper, and zinc arising from urban, industrial, and traffic-related pollution in the remote and/or untouched urban indigenous forests using soil, leaf litter, and key forest organisms (mosses, lichens, and millipedes) in three forests (Platbos, Orange Kloof, and Newlands) in the Western Cape, South Africa. Elevated concentrations of these metals were found in the forests closest to the city, as well as at sites in close proximity of vehicle traffic.

The authors analyzed certain species and varieties of fruit tree in which applied crop technology is used and also undergoes the effects of climate change. The aim is to extend productive crop varieties, resistant to disease and pests, in order to obtain superior yields. The research was conducted in orchards located in northwestern Romania (on 8.59 ha), intensively cultivated with apple, plum, and almond species. The blooming period of the species and fruit production was studied in 2009, the first year of the farm’s commercial production, and then compared to figures from 2016 to see the changes that occurred. Climatic conditions were studied throughout the period of existence of the farm (2002–2016). To determine the influence of the climatic factor on the blooming and production periods, respectively, every year is considered having pre-blooming, blooming, and ripening periods. It was found that climate change influences the annual biological cycle of the trees: the vegetative rest period of the trees shortens, the tree vegetation begins earlier in the spring, and the blooming period is advanced by as much as 10 days compared to normal cultivated varieties. All these factors have direct repercussions on the quantity of production.

Millispherical nanocomposites are promising for water decontamination combining the high reactivity of the confined nanoparticles and the excellent hydrodynamic properties of the supporting host. However, the effect of three-dimensional (3-D) distribution of the nanoparticles inside the host on the performance of the nanocomposite was highly dependent on the specific decontamination process. In this study, four D201-ZVI nanocomposites from peripheral to uniform 3-D distributions of nZVI were prepared to evaluate the effect of 3-D distribution of the confined nanoparticles inside the host beads on the removal of EDTA-chelated Cu(II). The performance of Cu(II) removal increased with the 3-D distribution tailoring towards the peripheral region, which was also validated under various solution chemistry conditions in terms of initial pH, DO, and coexisting sulfate. The mechanism underlying the 3-D distribution effect may be ascribed to three perspectives. First, the dissolution of Fe was also higher from the peripherally distributed nZVI nanocomposites compared with the uniform ones. In addition, SEM-EDS analysis revealed the immobilization of Cu occurred at limited depth from the outermost surface of the composite beads, leading to the low spatial utilization of the inner core region. Furthermore, XRD and XPS analyses demonstrated the higher chemical utilization of nZVI for the outer-distributed nanocomposites owing to the shortened pathway for mass transfer. This study shed new light on the design and development of tunable nanocomposites of improved reactivity for water decontamination processes.

Chemicals released from anthropogenic activities such as industry and agriculture often end up in aquatic ecosystems. These substances can cause serious damage to these ecosystems, thus threatening the conservation of biodiversity. Among these substances are pesticides, such as oxyfluorfen, a herbicide used for the control of grasses and weeds. Considering its widespread use, it is important to investigate the possible toxicity of this compound to aquatic organisms, especially invertebrates. Hence, the use of biological systems able to detect such effects is of great importance. The mollusk Biomphalaria glabrata has been shown to be useful as an environmental indicator to assess the potential ecological effects of physical and chemical stressors in freshwater environments. The present study sought to detect mutagenic changes in hemocytes of B. glabrata exposed to oxyfluorfen. To perform these tests, this study used ten animals per group, exposed acutely (48 h) and chronically (15 days) to oxyfluorfen. The herbicide concentrations were 0.125, 0.25, and 0.5 mg/L. The results showed that oxyfluorfen induced significant frequencies of micronuclei, binucleated cells, and apoptosis in hemocytes of mollusks when compared to the control group. Unlike chronic exposure, acute exposure was dose-dependent. The present study’s results demonstrate the cytotoxic and genotoxic effects of oxyfluorfen on hemocytes of B. glabrata.

Formation dip angle and the distortion of salinity affect the spatial distribution and storage capacity of carbon dioxide (CO₂). In this numerical study, based on an actual CO₂ injection demonstration project (Shiqianfeng group in the Ordos Basin) in China, CO₂ was injected for a period of 20 years at four different formation dip angles (0°, 5°, 10°, 15°). In conjunction, some salinity values were chosen, ranging from saturation salinity to no salinity. A three-dimensional (3D) model was established to systematically explore the influence of different formation dip angles and salinities on the CO₂ spatial distribution and storage amount. The simulation results showed that larger salinity and higher pressure near the injection well will lead the CO₂ gas-phase saturation and mass fraction to be smaller for a given formation dip angle. When salinity is held constant at the saturation value, a larger dip angle will cause a smaller CO₂ gas saturation in the upper right units of the injection well, and a larger gas saturation in the lower left units at the 20th year of CO₂ injection. For large salinity values (full, half, and quarter saturation salinity), the larger the formation dip angle is, the greater the CO₂ total storage amount. For smaller salinity values (0.00 and 0.03), a transition point existed (at 8 and 18.2 years) during the 20-year injection period. Before the transition point, the CO₂ total storage amount also increases with the dip angle. After the transition point, however, the larger the formation dip angle is, the smaller the CO₂ total storage amount becomes. In addition, a lower salinity may lead to the earlier appearance of the transition point.

Pot experiment was conducted to study the difference of cadmium uptake and OAS and IRT genes’ expression between the two ryegrass varieties under cadmium stress. The results showed that with the increase of cadmium levels, the dry weights of roots of the two ryegrass varieties, and the dry weights of shoots and plants of Abbott first increased and then decreased. When exposed to 75 mg kg⁻¹ Cd, the dry weights of shoot and plant of Abbott reached the maximum, which increased by 11.13 and 10.67% compared with the control. At 75 mg kg⁻¹ Cd, cadmium concentrations in shoot of the two ryegrass varieties were higher than the critical value of Cd hyperaccumulator (100 mg kg⁻¹), 111.19 mg kg⁻¹ (Bond), and 133.69 mg kg⁻¹ (Abbott), respectively. The OAS gene expression in the leaves of the two ryegrass varieties showed a unimodal curve, which was up to the highest at the cadmium level of 150 mg kg⁻¹, but fell back at high cadmium levels of 300 and 600 mg kg⁻¹. The OAS gene expression in Bond and Abbott roots showed a bimodal curve. The OAS gene expression in Bond root and Abbott stem mainly showed a unimodal curve. The expression of IRT genes family in the leaves of ryegrass varieties was basically in line with the characteristics of unimodal curve, which was up to the highest at cadmium level of 75 or 150 mg kg⁻¹, respectively. The IRT expression in the ryegrass stems showed characteristics of bimodal and unimodal curves, while that in the roots was mainly unimodal. The expression of OAS and IRT genes was higher in Bond than that in Abbott due to genotype difference between the two varieties. The expression of OAS and IRT was greater in leaves than that in roots and stems. Ryegrass tolerance to cadmium can be increased by increasing the expression of OAS and IRT genes in roots and stems, and transfer of cadmium from roots and stems to the leaves can be enhanced by increasing expression OAS and IRT in leaves.

The low-cost Ca-bentonite was rapidly converted to a mesoporous adsorbent via microwave-assisted acidification and the obtained materials were employed for the removal of contaminants from waste lubricant oil. In order to understand the role of acid combinations on activation, the agent compositions were prepared according to the mixture design algorithm. The waste oil recovery was carried out in a batch system to determine the appropriate acid composition, optimum microwave power, radiation time, and powder/acid ratio. As power increased, the contaminant removal performance of the adsorbent was effectively raised to achieve appropriate clear base oil. The rise in power behind 600 W negatively affected the performance of the adsorbent in which the color of oil was changed from yellow to brown. The appropriate recovery of waste oil was readily achieved by employment of adsorbents in which the acidification was performed in 15 min. The microwave-assisted technique could shorten the residence time to achieve the maximum efficiency in comparison with the performance of those produced through the conventional method. Although sulfuric acid can be used for acidification of bentonite by microwave heat treatment, the combination of acetic acid, < 50 mol%, with the mentioned acid was identified as an efficient agent to improve the performance of adsorbents which is valuable from an engineering point of view.