Production of acid mine drainage (AMD) and acid sulfate soils is one of the most concerning environmental consequences associated with mining activities. Implementation of appropriate post-mining AMD management practices is very important to minimize environmental impacts such as high soil acidity, soil erosion, and metal leachability. The objective of this study was to develop a cost-effective and environment-friendly “green” technology for the treatment of AMD-impacted soils. This study utilized the metal-binding and acid-neutralizing capacity of an industrial by-product, namely drinking water treatment residuals (WTRs), and the extensive root system of a metal hyper-accumulating, fast-growing, non-invasive, high-biomass perennial grass, vetiver (Chrysopogon zizanioides L.) to prevent soil erosion. Aluminum (Al)-based and calcium (Ca)-based WTRs were used to treat AMD-impacted soil collected from the Tab-Simco coal mine in Carbondale, IL. Tab-Simco is an abandoned coal mine, with very acidic soil containing a number of metals and metalloids such as Fe, Ni, Zn, Pb, and As at high concentrations. A 4-month-long greenhouse column study was performed using 5% and 10% w/w WTR application rates. Vetiver grass was grown on the soil-WTR mixed media. Turbidity and total suspended solid (TSS) analysis of leachates showed that soil erosion decreased in the soil-WTR-vetiver treatments. Difference in pH of leachate samples collected from control (3.06) and treatment (6.71) columns at day 120 indicated acidity removal potential of this technology. A scaled-up simulated field study was performed using 5% WTR application rate and vetiver. Soil pH increased from 2.69 to 7.2, and soil erosion indicators such as turbidity (99%) and TSS (95%) in leachates were significantly reduced. Results from the study showed that this “green” reclamation technique has the potential to effectively treat AMD-impacted soils.

The degradation mechanism of the pollutant hexachloroethane (HCA) by a suspension of Pd-doped zerovalent iron microparticles (Pd-mZVI) in dissolved lactic acid polymers and oligomers (referred to as PLA) was investigated using gas chromatography and the indirect monitoring of iron corrosion by continuous measurements of pH, oxidation-reduction potential (ORP), and conductivity. The first experiments took place in the absence of HCA, to understand the evolution of the Pd-mZVI/PLA/H₂O system. This showed that the evolution of pH, ORP, and conductivity is related to changes in solution chemistry due to iron corrosion and that the system is initially cathodically controlled by H⁺ mass transport to Pd surfaces because of the presence of an extensive PLA layer. We then investigated the effects of Pd-mZVI particles, temperature, initial HCA concentration, and PLA content on the Pd-mZVI/PLA/HCA/H₂O system, to obtain a better understanding of the degradation mechanism. In all cases, HCA dechlorination first requires the production of atomic hydrogen H*—involving the accumulation of tetrachloroethylene (PCE) as an intermediate—before its subsequent reduction to non-chlorinated C₂ and C₄ compounds. The ratio between Pd-mZVI dosage, initial HCA concentration, and PLA content affects the rate of H* generation as well as the rate-determining step of the process. A pseudo-first-order equation can be applied when Pd-mZVI dosage is much higher than the theoretical stoichiometry (600 mg for [HCA]₀ = 5–20 mg L⁻¹). Our results indicate that the HCA degradation mechanism includes mass transfer, sorption, surface reaction with H*, and desorption of the product.

Lignin-based activated carbon fibers (LCFK) were prepared by electrospinning method and evaluated in adsorption of volatile organic compounds (VOCs). Batch adsorption experiments for various component were carried out in a fixed-bed reactor. The molecular polarity of VOCs plays a pivotal role in the monocomponent dynamic adsorption. As a result, the adsorption capacity of toluene was larger than that of methanol or acetone. In the various multicomponent atmospheres (without water), the components interact with each other and competitive adsorption phenomenon occurs, resulting in the adsorption capacity of each component decreased significantly. Also, the samples before and after adsorption were characterized via Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and Boehm titration. The results reveal that methanol and acetone, controlled by physical adsorption, prefer to be adsorbed on polar groups on the surface of LCFK through the dipole–dipole interactions (i.e., van der Waals’ forces). Differently, the adsorption of toluene onto LCFK was controlled by physical and chemical processes, and the lactone groups have a positive contribution to the adsorption of toluene. It was also observed that water vapor can enhance the negative effect on the adsorption of VOCs, especially for toluene. The results from this study will be valuable for explaining the mechanisms of competitive adsorption among each component in the various multicomponent atmospheres and understanding the contribution of chemical functional groups on the surface of LCFK in the adsorption process.

Radionuclides ¹³⁷Cs and ⁹⁰Sr and total beta activity were determined from air filters collected in Rovaniemi (Finnish Lapland) in 1965–2011. Nuclear contamination sources present in the air filter samples as well as temporal changes in radionuclide concentrations were examined. Ozone observations and meteorological modeling were used in combination with radionuclide analyses to study the reasons behind the observed seasonal concentration variation. In general, the magnitude and variation in activity concentrations of ¹³⁷Cs and ⁹⁰Sr and total beta activity in the surface air of Rovaniemi in 1965–2011 corresponded well with values from other countries. However, the obtained results prove in practice that hardly any refractory or intermediate radionuclides from the destroyed Chernobyl reactor fuel were introduced to Finnish Lapland. The main source of ¹³⁷Cs and ⁹⁰Sr and total beta activity in the surface air of Rovaniemi in 1965–2011 has been intense atmospheric nuclear weapon testing in 1950s–1960s and later tests performed in 1965–1980, as well as leakages from underground nuclear tests in Semipalatinsk, 1966, and Novaya Zemlya, 1987. For ¹³⁷Cs and total beta activity, the influence of Chernobyl and Fukushima accidents was detected.

In order to explore the research trends and hotspots related to the treatment of heavy metals in wastewater by graphene and its composites, this study collected information on 511 publications from the Science Citation Index-Expanded (SCIE) and conducted a quantitative and visual analysis. The article on the adsorption of heavy metals in wastewater by graphene and its composites first appeared in 2006 and continued to grow since 2011. It broke through 100 articles for the first time in 2016 and the overall trend is on the rise. The 511 articles were published in 185 journals, of which RSC Advances is the most dynamic journal, and Journal of Materials Chemistry A is the most authoritative journal. Asian authors published about 87.14% of papers, and China, Iran, and India played a leading role compared with other countries. The University of Chinese Academy of Sciences is the largest research institution for the adsorption of heavy metals in wastewater by graphene and its composites. Hot keywords are “heavy metal removal,” “water sample,” “recent advance,” “reusable adsorbent,” “graphene-based material,” and “composite nanosheet.” Combined with keywords and cluster analysis, the chemical modification of graphene oxide has become a hot research direction for graphene materials to remove heavy metals from wastewater. Among them, MnFe₂O₄-graphene composite is a hot spot for graphene modification. In general, HNO₃, HCl, and EDTA are desorption reagents for graphene and its composites.

The effects of patchouli essential oil (PEO) as an alternative to antibiotics on ruminal methanogenesis, feed degradability, and enzyme activities were evaluated. The basal substrate was incubated without additives (control, CTL) and with monensin (MON, 6 μM/g DM) or patchouli essential oil (PEO, 90 μg/g DM) for 24 h. In three different runs, the gas production (GP) was recorded at 2, 4, 8, 12, and 24 h of incubation using a semi-automatic system. The results revealed that MON had decreased (P < 0.05) the net GP and CH₄ production and digestible and metabolizable energy relative to PEO supplementation. The in vitro truly degraded organic matter was not influenced by PEO application, while was reduced (P = 0.027) with MON. Both PEO and MON had similar reducing effect on the activity of carboxymethylcellulase (P = 0.030), in vitro truly degraded neutral detergent fiber (P = 0.010), NH₃-N concentrations (P = 0.012), acetate proportion (C2, P = 0.046), C2 to C3 ratio (P = 0.023), and total protozoal count (P = 0.017). Both additives recorded similar elevating potential on the α-amylase activity (P = 0.012), propionate (C3) proportion (P = 0.011), and microbial protein (P = 0.034) compared with CTL. Effects of MON and PEO on ruminal feed degradability, microbial enzyme activities, and total protozoa counts may be responsible for modifying rumen fermentation ecology. Addition of PEO may act as a desirable alternative rumen modifier for MON in ruminant diets.

Acid mine discharge (AMD) has been demonstrated to have significant impacts on microbial community composition in the surrounding soil environment. However, their effect on adjacent soil has not been extensively studied. In this study, microbial community composition of 20 AMD-contaminated soil samples collected from an abandoned coal mine along an AMD creek was characterized using high-throughput sequencing. All samples were characterized as extremely low in pH (< 3) and relatively enriched in HCl-extractable Fe species. The dominant phylotypes were belonging to genera Ochrobactrum, Acidiphilium, Staphylococcus, Brevibacterium, and Corynebacterium. Canonical correspondence analysis results revealed that the HCl-extractable Fe(III) had a strong impact on the soil microbial assemblage. Co-occurrence network analysis revealed that Aquicella, Acidobacteriaceae, Ochrobactrum, Enhydrobacter, Sphingomonas, and Legionellales were actively correlated with other taxa. As expected, most of the abundant taxa have been reported as acidophilic Fe-metabolizing bacteria. Hence, a co-occurring sub-network and a phylogenetic tree related to microbial taxa responsible for Fe metabolism were constructed and described. The biotic interaction showed that Dechloromonas exhibited densely connections with Fe(III)-reducing bacteria of Comamonas, Burkholderia, Shewanella, Stenotrophomonas, Acidithiobacillus, and Pseudomonas. These results demonstrated that Fe-metabolizing bacteria could have an important role in the Fe biogeochemical cycling.

Biofuel is a renewable energy source for transportation. Given the toxicity associated with particulate polycyclic aromatic hydrocarbons (PAHs) is not fully understood, investigating the difference of adverse health risks posed between vapor and particulate PAH emissions from biodiesel-fueled engine combustion was the objective of this study. Three different fuel types, including typical diesel, emulsified diesel with a water fraction from 10 to 19% (v/v), and emulsified biodiesel with water (10%) and biofuel fractions from 10 to 40% (v/v), were studied. The fugacity model and risk assessment were conducted to predict the health risks when different fuels were used. In the results, the addition of water and biofuel elevated and reduced the total PAH emissions in the exhausts, respectively. After the emission, chrysene and benzo(a)anthracene were two dominant carcinogenic species in the environment. The excess cancer risk of the PAH emission significantly decreased (e.g., up to two orders of magnitude) while the emulsified biodiesel was applied, with limiting the formation of benzo(a)pyrene being the explanation. The PAH emissions with molecular weights ranging from 166 to 255 g/mol were significantly different between the vapor and particulate phases during the emulsified biodiesel combustion (p < 0.01). From the viewpoint of cancer risk, the contribution posed by the particulate PAHs was significantly greater than those by the vapor PAHs (e.g., from 54% (benzo(a)pyrene) to 76% (benzo(b)fluoranthene)). Benzo(a)pyrene and chrysene represent the species with the highest and lowest risks, respectively. The multi-ringed PAHs with four or five rings were more indicative of potential cancer risk posed by the PAHs associated with particulate matters during combustion of the emulsified biodiesel.

Ambient air pollution is nowadays one of the most crucial contributors to deteriorating health status worldwide. The components of air pollution include PM₂.₅ and PM₁₀, NO₂, SO₂, CO, O₃, and organic compounds. They are attributed to several health outcomes, for instance, cardiovascular diseases (CVD), respiratory diseases, birth outcomes, neurologic diseases, and psychiatric diseases. The objective of this study is to evaluate the association between different ambient air pollutants and the above-mentioned health outcomes. In this systematic review, a total of 76 articles was ultimately selected from 2653 articles, through multiple screening steps by the aid of a set of exclusion criteria as non-English articles, indoor air pollution assessment, work-related, occupational and home-attributed pollution, animal studies, tobacco smoking effects, letters to editors, commentaries, animal experiments, reviews, case reports and case series, out of 19,862 published articles through a systematic search in PubMed, Web of Science, and Scopus. Then, the associations between air pollution and different health outcomes were measured as relative risks and odds ratios. The association between air pollutants, PM₂.₅ and PM₁₀, NO₂, SO₂, CO, O₃, and VOC with major organ systems health was investigated through the gathered studies. Relative risks and/or odds ratios attributed to each air pollutant/outcome were ultimately reported. In this study, a thorough and comprehensive discussion of all aspects of the contribution of ambient air pollutants in health outcomes was proposed. To our knowledge up to now, there is no such comprehensive outlook on this issue. Growing concerns in concert with air pollution-induced health risks impose a great danger on the life of billions of people worldwide. Should we propose ideas and schemes to reduce ambient air pollutant, there will be dramatic reductions in the prevalence and occurrence of health-threatening conditions.

Using quantum chemistry methods, mechanisms and products of the CHBr₂O₂ + HO₂ reaction in the atmosphere were investigated theoretically. Computational result indicates that the dominant product is CHBr₂OOH + O₂ formed on the triplet potential energy surface (PES). While CBr₂O + OH + HO₂ produced on the singlet PES is subdominant to the overall reaction under the typical atmospheric condition below 300 K. Due to higher energy barriers surmounted, other products including CBr₂O₂ + H₂O₂, CBr₂O + HO₃H, CH₂O + HO₃Br, CHBrO + HO₃ + Br, and CHBr₂OH + O₃ make minor contributions to the overall reaction. In the presence of OH radical, CHBr₂OOH generates CHBr₂O₂ and CBr₂O₂ + H₂O subsequently, which enters into new Br-cycle in the atmosphere. The substitution effect of alkyl group and halogens plays negligible roles to the dominant products in the RO₂ + HO₂ (X = H, CH₃, CH₂OH, CH₂F, CH₂Cl, CH₂Br, CH₂Cl, and CH₂Br) reactions in the atmosphere.