Metal–organic frameworks (MOFs) are attractive novel classes of porous materials with diverse potentiality and easily tailored structures. It is desirable to evaluate the performance of MOFs as photocatalysts for organic contaminant removal in aqueous matrixes. In this study, iron-based MIL-101(Fe) was synthesized and a photo-Fenton reaction system (multiple wavelength light + MIL-101(Fe) + H₂O₂) was developed for elimination of tris(2-chloroethyl) phosphate (TCEP). Degradation pattern of TCEP followed an S-shape curve, which included a slow induction period and a rapid radical oxidation process. Transport of reactants into MIL-101(Fe) and the activation of electron transport within Fe–O clusters of MIL-101(Fe) may be the dominant mechanisms in the induction period, while a pseudo-first-order kinetics was observed in the hydroxyl radical oxidation process. Removal efficiencies in these two stages highly depended on the reaction conditions. Irradiation at 420 nm and acid condition were conductive, while high temperature and high [H₂O₂]:[MIL-101(Fe)] mass ratio accelerated the reaction. Before complete mineralization, eleven degradation products were generated, and the dominant degradation pathways included cleavage, hydroxylation, carbonylation, and carboxylation. Under acid condition (pH = 3), only 1% mass loss was observed after 60-min reaction, but the iron leakage was aggravated when pH increased. Furthermore, this MOF-photo-Fenton system demonstrated a robust performance on TCEP degradation in actual wastewater matrixes under acid condition. Generally, the MOF-photo-Fenton system is a potential technology for elimination of organic pollutants in aqueous solution.

Arsenic (As) is often found naturally as the co-contaminant in the uranium (U)-contaminated area, obstructing the bioremediation process. Although the U-contaminated environment harbors microorganisms capable of interacting with U which could be exploited in bioremediation. However, they might be unable to perform with their full potential due to As toxicity. Therefore, potential in arsenic resistance and oxidation is greatly desired among the microorganisms for a continued bioremediation process. In this study, arsenic-resistant bacteria were isolated from U ore collected from Bundugurang U mine, characterized and their As oxidation and U removal potentials were determined. 16S rRNA gene sequencing and phylogenetic analysis showed the affiliation of isolated bacteria with Microbacterium, Micrococcus, Shinella, and Bacillus. Except Bacillus sp. EIKU7, Microbacterium sp. EIKU5, Shinella sp. EIKU6, and Micrococcus sp. EIKU8 were found to resist more than 400 mM As(V); however, all the isolates could survive in 8 mM As(III). The isolates were found to readily oxidize As under different culture conditions and are also resistant towards Cd, Cr, Co, Ni, and Zn. All the isolates could remove more than 350 mg U/g dry cells within 48 h which were found to be highly dependent upon the concentration of U, biomass added initially, and on the time of exposure. Ability of the isolates to grow in nitrogen-free medium indicated that they can flourish in the nutrition deprived environment. Therefore, the recovery of isolates with the potent ability to resist and oxidize As from U ore might play an important role in toxic metal bioremediation including U.

In this paper, a crosslinked carboxymethyl starch (CCMS) was prepared with corn starch as the raw material, epichlorohydrin as the crosslinking agent, and chloroacetic acid as the etherifying agent through a series of crosslinking, alkalization, and etherification reactions, respectively. Nano-TiO₂ was loaded onto the surface of the CCMS by the sol-gel method to obtain a TiO₂/CCMS composite. The TiO₂/CCMS composite was characterized by XPS, XRD, SEM, and BET. XPS showed that the surface chemical composition of the TiO₂/CCMS composite material contained titanium; XRD diffraction patterns indicated that the crystal form of the TiO₂/CCMS composite was a combination of the CCMS and anatase TiO₂. The surface morphology obtained by SEM showed that there were nano-TiO₂ particles on the surface of the CCMS. The specific surface area of the TiO₂/CCMS composite was larger than that of CCMS. The adsorption-photodegradation performance of the TiO₂/CCMS composite was also studied under UV irradiation, and the results showed that significant adsorption-photodegradation synergies occurred.

In the present study, an underfloor air distribution (UFAD) system with a circular swirl diffuser was simulated in an office room using a three-dimensional model when thermal sources were present in the room. An Eulerian-Lagrangian model was used to predict the characteristics of air and particle phases. In the Lagrangian particle model, the effects of drag, lift, Brownian, and thermophoresis forces were considered. The results showed that the circular swirl diffuser has better airflow and thermal conditions compared with the circular direct diffusers. It was also shown that the studied UFAD system provides good thermal comfort condition. The local and mean normalized particle concentrations in different heights of the room were found reasonable, and the particle removal efficiency was between 55 and 65% for all the particle sizes. The results also showed that the large particles due to their large weight stayed in lower heights of the room and deposited on the floor. The particle concentration in the breathing zone of manikins was also investigated, and it showed that though the manikins seated close to inlet registers have appropriate thermal comfort, they encounter the highest particle concentration in their breathing zone.

Nonferrous metal smelting produces a large amount of Hg⁰ in flue gas, which has caused serious damage to the environment and human health. In this work, amorphous cobalt sulfide was synthesized by a liquid-phase precipitation method and was used for capturing gaseous Hg⁰ from simulated smelting flue gas at low temperatures (50~150 °C). In the adsorption process, Hg⁰ can be transformed into the stable mercury compound, which is confirmed to be HgS by X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of Hg (Hg-TPD) analysis. Meanwhile, XPS results also demonstrate that S₂²⁻ species on the surface of cobalt sulfide play an important role in Hg⁰ transformation. At the temperature of 50 °C (inlet Hg⁰ concentration of 214 μg·m⁻³), the Hg⁰ adsorption capacity of cobalt sulfide (penetration rate of 25%) is as high as 2.07 mg·g⁻¹, which is much higher than that of popular adsorbents such as activated carbons and metal oxides. In addition, it was found that the Hg⁰ removal efficiency by cobalt sulfide in the flue gas with high concentration of SO₂ (5%) remained more than 94%. The good adsorption and Hg⁰ removal performance guarantee cobalt sulfide the great superiority and application potential in the treatment of Hg⁰ in smelting flue gas with high concentration of SO₂.

Graphene oxide (GO) has been reported to possess antibacterial activity; therefore, its accumulation in the environment could affect microbial communities such as biofilms. The susceptibility of biofilms to antimicrobials is known to depend on the stage of biofilm maturity. The aim of this study was to investigate the effect of GO nano-particles on Pseudomonas putida KT2440 biofilm of variable age. FT-IR, UV-vis, and Raman spectroscopy confirmed the oxidation of graphene while XPS confirmed the high purity of the synthesised GO over 6 months. Biofilms varying in maturity (24, 48, and 72 h) were formed using a CDC reactor and were treated with GO (85 μg/mL or 8.5 μg/mL). The viability of P. putida was monitored by culture on media and the bacterial membrane integrity was assessed using flow cytometry. P. putida cells were observed using confocal microscopy and SEM. The results showed that GO significantly reduced the viability of 48-h biofilm and detached biofilm cells associated with membrane damage while the viability was not affected in 24- and 72-h biofilms and detached biofilm cells. The results showed that susceptibility of P. putida biofilm to GO varied according to age which may be due to changes in the physiological state of cells during maturation. Graphical abstract

With the spread of the concept of sustainable development, people have gained awareness about the problem of massive illegal dumping of construction waste. In this research, a questionnaire survey was carried out in the USA and China. The results indicated the following. (1) Workers in both the countries had positive minimisation attitudes, and the attitude of Chinese construction workers was not significantly different from that of American construction workers. Furthermore, their average values were 3.9 and 4.07, respectively. (2) Business owners had a poor understanding of the obligations that should be fulfilled by contractors and construction workers, which greatly reduced (a) construction workers’ and contractors’ motivation to implement waste minimisation management and (b) the benefit-driven effect. (3) In terms of perceived behavioural control, Chinese construction workers had poorer minimisation technologies and knowledge than American construction workers, and it was very difficult for them to implement construction waste minimisation. The research conclusions and relevant suggestions may be used to improve the construction waste minimisation behaviour and awareness of Chinese people and promote China’s construction waste minimisation management.

This is a report on comprehensive characterization of cadmium (Cd)-exposed root proteomes in tomato using label-free quantitative proteomic approach. Two genotypes differing in Cd tolerance, Pusa Ruby (Cd-tolerant) and Calabash Rouge (Cd-sensitive), were exposed during 4 days to assess the Cd-induced effects on root proteome. The overall changes in both genotypes in terms of differentially accumulated proteins (DAPs) were mainly associated to cell wall, redox, and stress responses. The proteome of the sensitive genotype was more responsive to Cd excess, once it presented higher number of DAPs. Contrasting protein accumulation in cellular component was observed: Cd-sensitive enhanced intracellular components, while the Cd-tolerant increased proteins of extracellular and envelope regions. Protective and regulatory mechanisms were different between genotypes, once the tolerant showed alterations of various protein groups that lead to a more efficient system to cope with Cd challenge. These findings could shed some light on the molecular basis underlying the Cd stress response in tomato, providing fundamental insights for the development of Cd-safe cultivars. Graphical abstract

Iron (Fe) and manganese (Mn) are metals commonly found at high concentrations in underground water. These metals are essential for the good functioning of living organisms, but high concentrations lead to imbalance, potentiating the appearance of pathologies. This study aimed to evaluate the effect of exposure to naturally occurring metals in groundwater, using zebrafish (Danio rerio) as an experimental model. Thus, zebrafish were exposed to Fe (0.8 and 1.3 mg/L), Mn (0.2 and 0.4 mg/L), and groundwater collected from deep tube wells with Fe and Mn (Fe 0.8/Mn 0.2 mg/L and Fe 1.3/Mn 0.4 mg/L) for 30 days. Bioaccumulation of these metals has been demonstrated in the livers and muscles of zebrafish. Acetylcholinesterase activity changed only in zebrafish muscles in all groups. Sulfhydryl levels changed mainly in the group Mn 0.4. SOD/CAT ratio decreased in the groups Fe 0.8 and 1.3, Mn 0.4, and Fe 0.8/Mn 0.4. An increase in the frequency of micronucleus in all groups was shown as a consequence of these changes. Behavioral parameters (time and distance traveled, mean speed, turn angle, latency, and number of crossings between compartments) have also changed, mainly in the groups Fe 1.3, Mn 0.4, and Fe 1.3/Mn 0.4. Therefore, long-term exposure to Fe and Mn, even at not so high concentrations, may cause biochemical, genotoxic, and behavioral changes in zebrafish.

Breastfeeding is a gold standard of neonate nutrition because human milk contains a lot of essential compounds crucial for proper development of a child. However, milk is also a biofluid which can contain environmental pollution, which can have effects on immune system and consequently on the various body organs. Polychlorinated biphenyls are organic pollutants which have been detected in human milk. They have lipophilic properties, so they can penetrate to fatty milk and ultimately to neonate digestive track. Another problem of interest is the presence in milk of heavy metals—arsenic, lead, cadmium, and mercury—as these compounds can lead to disorders in production of cytokines, which are important immunomodulators. The toxicants cause stimulation or suppression of this compounds. This can lead to health problems in children as allergy, disorders in the endocrine system, end even neurodevelopment delay and disorder. Consequently, correlations between pollutants and bioactive components in milk should be investigated. This article provides an overview of environmental pollutants found in human milk as well as of the consequences of cytokine disorder correlated with presence of heavy metals. Graphical abstract