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Bioleaching of electronic waste Texte intégral
2021
Waghmode, M. S. | Gunjal, A. B. | Patil, N. N.
Increase in advanced electronic technology leads to environmental issues related with its disposal. Electronic waste i.e., video card and random access memory were used for studying extraction of precious metals using Paenibacillus sp. Metal contaminated soil was used for the isolation of exopolysaccharide producing strains. The isolate was identified as Paenibacillus sp. based on morphological, biochemical tests and 16S rRNA sequencing. Metal content analysis of soil and e-waste was carried out using X-ray Fluorescence spectroscopy. The vanadium element was more in the soil sample which was 0.487 mg/g and in electronic waste sample copper content was more which was 250 mg/g. Paenibacillus sp. produced capsule which was observed under bright, dark field and phase contrast microscope. Scanning electron microscopy was done for the study of morphological changes of exopolysaccharide producing Paenibacillus sp. in chitin broth and on chitin agar medium with and without e-waste. The Fourier Transform Infrared Spectroscopy analysis of exopolysaccharide produced by Paenibacillus sp. grown on chitin agar and chitin agar with e-waste showed presence of different functional groups. The one step and two step bioleaching experiments were carried out for testing efficacy of biomass on metal leaching. Paenibacillus sp. showed its potential for the extraction of precious metals viz., gold, silver and copper from electronic waste. Paenibacillus sp. recovered gold (0.001%), cadmium (45%), copper (50%), iron (46%), manganese (88%), palladium (56.9%) and zinc (87.12%) by two step fermentation. The study is useful for the bioleaching of precious metals from electronic waste.
Afficher plus [+] Moins [-]Determinants of Environmental Degradation in Thailand: Empirical Evidence from ARDL and Wavelet Coherence Approaches Texte intégral
2021
Adebayo, T. S. | Akinsola, G. D. | Odugbesan, J. A. | Olanrewaju, V. O.
This paper explores long-run and causal effects of financial development, real growth, urbanization, gross capital formation and energy consumption on CO2 emissions in Thailand by utilizing recent econometric techniques. The study employs ARDL technique to examine the long and short run interconnection between CO2 emissions and the regressors. Furthermore, we employ the FMOLS, DOLS and CCR as a robustness check to the ARDL long-run estimator. The study use time-series data spanning from 1971 to 2016. The study also utilizes the wavelet coherence technique to collect information on the association and causal interrelationship among these economic variables at different frequencies and timeframes in Thailand. The study objectives are structured to answer the following questions: (a) does the selected macroeconomic indicators impact CO2 emissions in Thailand? (b) if so, why? Findings reveal; (i) Negative and insignificant link between CO2 emissions and urbanization. (ii) GDP growth affects CO2 emissions positively. (iii) The interconnection between CO2 emissions and energy usage is positive. (iv) Gross capital formation impact CO2 emissions positively. (v) Positive interconnection exists between financial development and CO2 emissions in Thailand. Additionally, the wavelet coherence result provides a supportive evidence for the ARDL long run result. Based on these findings, policy directions were suggested.
Afficher plus [+] Moins [-]Chronological Study of Metallic Pollution Using Tree Rings at Tema Industrial Area Texte intégral
2021
Edusei, G. | Tandoh, J. B. | Edziah, R. | Gyampo, O. | Ahiamadjie, H.
Tree rings have been used to reconstruct past climates as well as to assess the effects of recent climatic and environmental changes on tree growth. Industrial emission is one of the major sources of pollutants in the atmosphere. This study determined heavy metals pollution chronologies from industrial emissions in the atmosphere of the Tema industrial area of Ghana using tree-rings as bio-indicators. Swietenia mahagoni (Mahogany) tree was bored and the rings counted and age determined to be 50 years spanning from 1968 to 2018. Tree growth rates were calculated through ring width measurements and related to annual precipitation data spanning over the sampling period. It was observed that wet seasons correlate with high growth rates of trees while low precipitation seasons correspond to low or no growth rate of trees. Energy Dispersive X-ray fluorescence (EDXRF) was used to investigate the presence and concentration of the four heavy metals (Cu, Zn, Fe and Pb). Concentration of Cu, Zn, Fe and Pb ranged from (1.92—6.70 mg/kg), (5.37 – 13.9 mg/kg), (0.10 – 0.36 mg/kg) and (12.13—90.13 mg/kg), respectively. Surprisingly, an increasing trend in concentration was observed for Zn and Cu with levels higher than the WHO guideline for heavy metals in the plant.
Afficher plus [+] Moins [-]Analysis of heavy metal concentration in some vegetables using atomic absorption spectroscopy Texte intégral
2021
Abrham, F. | Gholap, A.V.
This study assesses heavy metal levels in water, soil, and vegetables (swiss chard, lettuce, cabbage, collard green, tomato, green pepper and carrot) irrigated with waste water in Gamo, Ethiopia. The samples of soils, water, and vegetables were randomly collected, processed, and analyzed for heavy metals using atomic absorption spectrophotometry. The results obtained show that the irrigational water is profoundly contaminated with heavy metals Cd, Cr and Ni and Pb, Zn and Cu had the lowest concentration in irrigation water. The levels of Cd in Kulfo river area and Chamo Lake area and Ni in most of the farm soils were also found to be higher than the guideline values. The study also revealed that the mean levels of Cd in most vegetables and Cr and Pb in some vegetables were higher than the maximum recommended limits set by WHO/FAO. In general the results show that the highest concentration of the heavy metals was obtained from Kulfo river area compared to the Arbaminch textile share company area, Abaya Lake area, and Chamo Lake area. Cabbage was maximally contaminated with potential toxic elements followed by Swiss-chard, carrot, tomato, collard green, green pepper and lettuce. Hence, from kulfo river area frequent consumption of cabbage and Swiss chard may cause serious health risks to consumers. The levels of many elements were found to vary with location, suggesting localized inputs of the various contaminants related to industrial and other activities that generate wastewater. This study recommends regular monitoring of heavy metals in soils, waters, and foodstuffs to prevent excessive accrual in food chain.
Afficher plus [+] Moins [-]Modeling the Consequences of Benzene Leakage from Tank using ALOHA in Tar Refining Industrial of Kerman, Iran Texte intégral
2021
Shojaee Barjoee, S. | Nikbakht, M. | Malverdi, E. | Zarei Mahmoud Abadi, S. | Naghdi, M. R.
The emission and dispersion of pollutants from the tanks of coking and tar refining industries in the environment is always probable. This study aimed to evaluate the hazard radius of benzene release from the tank of one of the coking and tar refining industries. Areal Location of Hazardouse Atmosphere (ALOHA) model Version 5.4.7 was used to predict the hazard radius of leakage and dispersion of benzene from a tank in different seasons. The maps of the toxic and flammable vapor cloud of benzene, evaporation rate from puddle and the concentration of toxic and flammable vapor cloud inside and outside of the office building were prepared. The results indicated that the maximum average benzene released from the tank was 282 Kg/min and the total amount of benzene leakage was 11997 kg in 60 min in summer. The maximum diameter of the created evaporating puddle was 71 m in autumn. The maximum toxic and flammable concentrations of benzene inside an office building were 772 and 936 ppm, respectively whilethey were 3720 and 3540 ppm outside a building in autumn. Based on the Acute Exposure Guideline Levels (AEGL) and Lower Explosive Limit (LEL) criterias, the maximum hazard radius was 1200 and 200 m in autumn. The toxic vapor cloud of benzene covered some parts of the adjacent coking plant. However, the boundaries of the flammable vapor cloud failed to reach the adjacent industries. The scenario of this study is safe for the adjacent residents and unsafe for the personnel. Thus, presenting a strategy to deal with this process incident is essential.
Afficher plus [+] Moins [-]Study of Pollutant Dispersion in Finite Layers of Semi-infinite Geological Formation Texte intégral
2021
Singh, Mritunjay Kumar | Rajput, Sohini
The present study deals with groundwater pollution in multilayer aquifer. The model is based on decomposition of finite layers in semi-infinite groundwater reservoir. A constant pollutant source is injected at the input boundary of the uppermost layer (UML) of the landfill. At the intermediate inlet boundary, some average value for the longitudinal exchange of the input source concentration in each sub-layer is considered from the previous layer. Initially, the aquifer is not solute free in each sub layer that means some constant background contaminant concentration exists. In each sub layer, concentration gradient is assumed to be zero at the extreme boundary. The linear sorption and first orders decay terms are considered to model the groundwater pollution in multilayer aquifer. The Laplace transform technique is adopted to solve one-dimensional (1D) advection-dispersion equation (ADE). This approach is helpful to understand the solute migration in finite sub layers. The results are elucidated for the different time periods to examine the peak of pollutant concentration level in geological formations.
Afficher plus [+] Moins [-]Do Technological Innovation And Renewable Energy Consumption in Japan Important For Consumption-Based Carbon Emissions? Texte intégral
2021
Adebayo, Tomiwa Sunday | Adesola, Ibrahim | Oyebanji, Modupe | Osemeahon, Oseyenbhin Sunday
With growing global warming issues, the association between technological innovation and environmental pollution has created significant debate in recent years. This paper examines the long-run and causal impact of technological innovation, economic growth, and renewable energy on consumption-based carbon emissions in Japan. The study utilized quarterly data spanning between 1990 and 2015. The study utilized recent econometrics techniques such as Maki co-integration, ARDL bunds test, FMOLS, DOLS, and frequency domain causality techniques. To the author's understanding, no prior studies have been conducted in Japan using consumption-based carbon emissions as a proxy of environmental degradation. Thus, this empirical analysis contributes to the literature. The findings from the ARDL bounds and Maki co-integration tests revealed evidence of co-integration among the series. The results of FMOLS and DOLS reveal that both renewable energy and technological innovation improve the environmental quality, while economic growth harms the quality of the environment. The results of the frequency-domain causality technique reveal that technological innovation, renewable energy, and economic growth can significantly predict consumption-based carbon emissions in Japan. Based on these outcomes, we suggested that Japan's government should be careful when formulating policies that trigger growth, which will have a detrimental impact on the environmental quality. Our empirical outcome also revealed that any policy that encourages renewable energy should be encouraged since it enhances environmental quality.
Afficher plus [+] Moins [-]Studying Some Blood Parameters of Otolithes ruber (Schneider, 1801) in Cold and Warm Seasons as an Indicator of Pollution in Musa Creek Texte intégral
2021
Ghasemi, Hamideh | Abdi, Rahim | Doraghi, Abdulmajed | Salamat, Negin | Salari-Aliabadi, Mohammad Ali
The present study attempts to investigate some blood parameters of Otolithes ruber during different seasons in terms of both temperature and pollution. For so doing it uses 10 specimens, for each station and season, collected from 5 polluted stations, including Petrochemical, Ghanam, Zangi, Douragh, Patil, and Sajafi as the control group, away from pollution in Musa Creek. The fish are anesthetized with 1ml of clove extract per liter. Their blood samples are taken immediately from the caudal vein, using a heparinized syringe. Afterwards, the serum is separated in a centrifuge with a speed of 6000 rpm for 2 minutes. The desired factors are measured by the Mindray BS200 auto-analyzer and the total protein level, by Bradford's usual laboratory methods. Results show that AST, ALT, ALP, Glucose, and Triglycerides have increased in more polluted stations (P≤0.05). In sheer contrast, total protein and Albumin have decreased as pollution grows (P≥0.05). According to this study, environmental water pollution of the fish has a large impact on the concentration of measured blood parameters, whereas the influence of seasonal changes on most of them is low.
Afficher plus [+] Moins [-]Batch and Column Studies on Nickle and Cadmium Removal Using Iranian Clay-based Geopolymer Texte intégral
2021
Bakhtiari, Somayeh | Zeidabadinejad, Asma | Abbaslou, Hanieh | Ghanizadeh, Alireza
The production rate of industrial and agricultural waste is increasing due to population growth. Soil is the most important receiver of industrial and agricultural waste. Contaminants such as heavy metals in various waste after reception by the soil, immediately become part of the cycle that has different impacts on the environment. Geopolymer, as a chemical stabilizer has the potential to stabilize heavy metals in the soil. In this research, several geopolymers for the stabilization of heavy metals in soil were synthesized. Silicon dioxide (SiO2) and aluminosilicate (Al2SiO4) must be used to produce the geopolymers. Rice husk ash was used as the SiO2 source. Also, Iranian zeolite and sepiolite, and red clay soil were utilized as the source of Al2SiO4. The synthesized geopolymers were investigated for the adsorption of nickel and cadmium. Also, batch and column studies of using geopolymers for the chemical stabilization of heavy metals in soil were conducted. The results revealed a high adsorption capacity of the geopolymers. The zeolite, sepiolite, and red clay geopolymer-soil samples adsorbed 100% of the heavy metals (i.e., Ni and Cd) at a concentration of 100 ppm. The zeolite geopolymer adsorbent adsorbed 57% and 96% of Ni and Cd at a concentration of 1000 ppm, respectively. In general, it was concluded that the use of geopolymer compounds in soils with high heavy metal adsorption capacity could be an efficient approach to prevent groundwater resource pollution.
Afficher plus [+] Moins [-]Effect of Biochar Amended Vermicomposting of Food and Beverage Industry Sludge along with Cow dung and Seed Germination Bioassay Texte intégral
2021
Tasnim, Umme Fariha | Shammi, Mashura | Uddin, Md. Khabir | Akbor., Md. Ahedul
Transformation of food and beverage industrial sludge into vermicompost into value-added product simultaneously can control gaseous emission. Addition of biochar in the vermicomposting as a bulking agent increases fertilizer value. This research aimed to investigate the effect of biochar amendment on vermicomposting of the food and beverage industry sludge (FBIS) and cow dung (CD) in a different ratio using earthworm Eisenia fetida. We had further investigated the survival rate of E. fetida and the cocoon productions after 35 days of the vermicomposting. Besides, we have also evaluated the seed germination bioassay using Malabar spinach (Basella alba) to determine the toxicity and maturity of produced compost. The survival and cocoon production of E. fetida were higher in vermicompost amended with 10% biochar. Vermicomposting with biochar resulted in a slight pH shift. Reduction in organic carbon (OC) percentage not so significant in biochar added FBIS and CD. An increase in phosphorus and potassium content and a decrease in nitrogen percentage observed; vermicomposting with biochar resulted in higher seed germination, root elongation, and germination index than vermicomposting without biochar.
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