Atmospheric mercury exits primarily as gaseous mercury and particulate mercury (PHg). Change in the species of atmospheric mercury will pose significant impact on the biogeochemical process of mercury. Here total gaseous mercury (TGM) and total particulate mercury (TPM) were measured from heating season in wintertime to springtime with frequent dust storm during February to May 2009 in the suburban of Hefei, central China, where atmospheric mercury measurements were completely absent. The average concentrations of TGM and TPM were 2.57±1.37ng/m3 and 0.32±0.10ng/m3, respectively. Variations in the TGM were affected by both emissions and meteorological parameters. In the heating period (February), due to coal combustion TGM concentrations were significantly higher than those in the spring (March, April and May). A clear different diurnal variation in TGM concentration was also observed both in late winter and in spring, accompanying with the advance of sunrise. The percentage of total particulate mercury (TPM) in total atmospheric Hg ranged from 5.8%–19.2%, with relatively high levels appeared in March and April. PHg was mainly derived from direct emissions by coal combustion in February and May, while it was dominated by transformation from gaseous Hg on particles in March and April due to dust storms, which may result in more deposition of mercury to ecosystem.

Long–range transport of the Saharan dust plumes during May–August of each year is a prominent feature over the tropical North Atlantic. Observations of temperature profiles are highly desirable in clarifying the impacts of the Saharan dust plumes over the tropical North Atlantic. In this work we evaluate positive temperature anomalies (inversions in the lower troposphere) in the North Atlantic low troposphere originating from Western Africa, and to examine the correspondence of these events to Saharan dust plumes, using several temperature sources and satellite–detected measurements of Aerosol Index. We combine profiles of temperature observations from FORMOSAT–3/COSMIC (F3C) with aerosol observations from Ozone Monitoring Instrument (OMI) to provide direct evidence of the Saharan dust plumes modifying environmental stability. The F3C observations show good profile measurements compared with the radiosondes in the lower troposphere, with the average temperature differences less than 0.5K. The F3C results were also compared with the Aqua Advanced Infrared Radiation Sounder (AIRS) and meteorological analyses from the National Centers for Environmental Predictions (NCEP), the United Kingdom Met Office (UKMO), and the European Centre for Medium Range Weather Forecast (ECMWF). Our results show that hot air plumes are associated with the Saharan dust plumes during their transport across the tropical North Atlantic. There were eleven distinctive hot air plumes during May–August 2007 and 2008, respectively. These hot air plumes increase environmental temperatures below 5–km altitudes, with the maximum increase of 1–2K around 2–km. This leads to increase of environmental stability below 2–km altitudes and decrease of environmental stability between 2– and 5–km altitudes. By changing the vertical distribution of environmental stability, the Saharan dust plumes act to stabilize environmental air below 2–km while destabilize environmental air from 2– to 5–km altitudes. These results are distinctively presented in the F3C and AIRS observations but less obvious in the meteorological analyses.

Continuous measurement of fine particulate black carbon (BC) was conducted at an urban site of Guangzhou in South China from December 2007 to December 2008. The daily average BC concentrations ranged from 0.6 to 20.5μg m−3, with an average value of 4.7μg m−3, which was substantially higher than those observed in the urban areas of other developed countries. Diurnal fluctuations of BC were marked with two peaks, one in the morning rush hour (08:00LT) and the other in the late evening hour (21:00–22:00LT), while the lowest BC concentrations were observed in the afternoon. Ambient BC concentrations displayed significant seasonal and diurnal variations with higher values in winter and spring, followed by lower concentrations during autumn and summer. Wind speed, wind direction and temperature were important meteorological factors that affected BC concentrations. A clearly negative correlation (r=−0.50, p<0.01) between BC concentrations and wind speed was found during the study period. A specific investigation was conducted to determine the relationship between optical BC and thermal–optical–reflectance elemental carbon (TOR EC) in distinct seasons. Although significant correlations between BC and EC were obtained (r>0.92, p<0.01), the regression slopes (ΔBC/ΔEC) slightly deviated from each other with values of 0.79, 1.18, and 0.81 in winter, spring and summer, respectively, possibly due to the distinct mixing states and source variations in different seasons. The calculated experimental attenuation coefficient showed a higher value (19.3m2g−1) in Guangzhou than the one recommended for typical Aethalometer measurements.

Derelict fishing gear is a source of mortality for target and non-target marine species. A program employing commercial watermen to remove marine debris provided a novel opportunity to collect extensive spatially-explicit information for four consecutive winters (2008–2012) on the type, distribution, and abundance of derelict fishing gear and bycatch in Virginia waters of Chesapeake Bay. The most abundant form of derelict gear recovered was blue crab pots with almost 32,000 recovered. Derelict pots were widely distributed, but with notable hotspot areas, capturing 40 species and over 31,000 marine organisms. The target species, blue crab, experienced the highest mortality from lost pots with an estimated 900,000 animals killed each year, a potential annual economic loss to the fishery of $300,000. Important fishery species were captured and killed in derelict pots including Atlantic croaker and black sea bass. While some causes of gear loss are unavoidable, others can be managed to minimize loss.

Surface sediments collected along the entire continental shelf of China, including Yellow Sea, the East China Sea (ECS) inner shelf and the South China Sea (SCS), were analyzed for linear alkylbenzenes (LABs), from which regional anthropogenic influences on the marine environment were assessed. The occurrence of LABs (5.6–77ng/g; mean: 25ng/g; median: 20ng/g) implied light sewage contamination in coast sediment off China. Specifically, the SCS had higher sedimentary LAB levels than Yellow Sea and the ECS inner shelf, which was mainly related to the intensity of domestic wastewater discharge and marine fishing activities. Values of L/S and C13/C12 (defined in the main text) suggested certain degradation while I/E indicated limited degradation of LABs. Also, additional input sources and congener inter-conversions may have contributed to the inconsistent results for degradation of LABs in offshore sediments. Atmospheric inputs and wastewater discharge from marine fishing vessels predominantly contributed to sedimentary LABs in Yellow Sea and the SCS, while riverine input was mainly responsible for LABs along the ECS inner shelf.

The North-East Atlantic porbeagle (Lamna nasus) population has declined dramatically over the last few decades and is currently classified as ‘Critically Endangered’. As long-lived, apex predators, they may be vulnerable to bioaccumulation of contaminants. In this study organohalogen compounds and trace elements were analysed in 12 specimens caught as incidental bycatch in commercial gillnet fisheries in the Celtic Sea in 2011. Levels of organohalogen contaminants were low or undetectable (summed CB and BDE concentrations 0.04–0.85mgkg−1wet weight). A notably high Cd concentration (7.2mgkg−1wet weight) was observed in one mature male, whereas the range observed in the other samples was much lower (0.04–0.26mgkg−1wet weight). Hg and Pb concentrations were detected only in single animals, at 0.34 and 0.08mgkg−1wet weight, respectively. These contaminant levels were low in comparison to other published studies for shark species.

A chassis dynamometer study was conducted to compare the characteristics of particle emissions from a port fuel injection (PFI) and a gasoline direct injection (GDI) car, both of which comply with Euro 4 exhaust emission standards. Experiments were carried out over the New European Driving Cycle (NEDC), the ECE–15 segments, the period from 0 to 49 s within the NEDC procedure (FSE) and the Extra Urban Driving Cycle segment. Exhaust particles were characterized in terms of the particle number, surface area, volume and size distributions between 30nm and 1μm. Under the NEDC, the GDI car had particle emissions weighted by particle number, surface area and volume that were 56–2 739% higher than the emissions from the PFI car in the range of particle size measured, and the particle number, volume and surface area emissions per km for the GDI car are respectively 5.3, 9.0 and 14.6 times higher than those for the PFI car. Among the testing conditions employed, the highest concentrations of average particle number, surface area and volume were found in the FSE, and the particle number, surface area and volume for the GDI car were respectively 9.5, 33.2 and 39.8 times higher than those for the PFI car. Moreover, the peak of the particle size distributions for the PFI car was toward a smaller size, while that for the GDI was toward a larger size, indicating that particles emitted by the PFI car are much smaller than those emitted by the GDI car.

The use of bivalves such as the brown mussel (Perna perna) and the black mussel (Choromytilus meridionalis) is common in the study of marine pollution and the effect of these pollutants on ecosystems and are important in both economic and ecological roles. Namibian marine ecosystems are threatened by pollution from mining, commercial fishing and population growth. The aims of this study were to determine baseline metal concentrations, spatial variation and variation between species. Metal levels in C. meridionalis from Guano Platform (GP) are the lowest of all the sites. The most polluted sites are Rocky Point (RP), Halifax Island (HIL) and between Walvis Bay and Swakopmund (WS). The bioaccumulation of metals between P. perna and C. meridionalis were not uniform for all metals. Overall the study indicates the condition of the coastline to be mostly normal, with Cd and Pb levels being of concern.

Lipid and fatty acid (FA) composition and selected oxidative stress parameters of freshwater clams (Dipolodon chilensis), from a sewage-polluted (SMA) and a clean site, were compared. Trophic markers FA were analyzed in clams and sediment. Saturated FA (SAFA), and bacteria and sewage markers were abundant in SMA sediments, while diatom markers were 50% lower. Proportions of SAFA, branched FA, 20:5n−3 (EPA) and 22:6n−3 (DHA) were higher in SMA clams. Chronic exposure of D. chilensis to increasing eutrophication affected its lipid and FA composition. The increase in EPA and DHA proportions could be an adaptive response, which increases stress resistance but could also lead to higher susceptibility to lipid peroxidation TBARS, lipofuscins (20-fold) and GSH concentrations were higher in SMA clams. FA markers indicated terrestrial plant detritus and bacteria are important items in D. chilensis diet. Anthropogenic input in their food could be traced using specific FA as trophic markers.