To improve the electrocatalytic efficiency of the cathode and provide a wider pH range in the electro-Fenton process, N-doped multi-walled carbon nanotubes (NCNTs) and ferrous ion complexed with carboxylated carbon nanotubes (CNT-COOFe²⁺) were used to fabricate the diffusion layer and catalyst layer of a membrane cathode, respectively. The morphology, structure, and composition of CNT-COOFe²⁺ were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The oxygen reduction performance of NCNT was evaluated using cyclic voltammetry (CV) and the rotating disk electrode technique (RDE). In addition, a potential application of the cathode in sequential electro-Fenton degradation of p-nitrophenol (p-NP) was investigated. The results revealed that iron was successfully doped on the carboxylated carbon nanotubes in ionic complexation form and the content of iron atoms in CNT-COOFe²⁺ was 2.65%. Furthermore, the defects on the tube walls provided more reactive sites for the electro-Fenton process. A combination of CV and RDE data indicated that NCNT had better electrocatalytic H₂O₂ generation activity with a more positive onset potential and higher cathodic peak current response than CNT. A p-NP removal rate of 96.04% was achieved within 120 min, and a mineralization efficiency of 80.26% was obtained at 180 min in the sequential electro-Fenton process at a cathodic potential of − 0.7 V vs SCE and neutral pH. The activity of the used cathode was restored simply through electro-reduction at − 1.0 V vs SCE, and a p-NP removal rate of more than 70% was obtained at 60 min after six regeneration cycles.

This study was conducted to evaluate the ability of zinc oxide nanoparticles (ZONPs) with unique properties to protect tomato against the bacterial speck pathogen, caused by Pseudomonas syringae pv. tomato DC3000 (Pst). Protection of tomato against bacterial speck using ZONPS was evaluated by its direct antibacterial activity and its ability for inducing resistance in tomato plants. The results revealed that ZONPs showed significant direct antibacterial activity against Pseudomonas syringae pv. tomato under laboratory conditions. Moreover, tomato plants treated with ZONPs showed a significant reduction in disease severity and bacterial proliferation relative to non-treated plants. Furthermore, tomato plants treated with ZONPs showed higher self-defense enzyme activity relative to untreated plants. The regulatory and defense genes, LePR-1a and Lipoxygenase (LOX), involved in the salicylic acid (SA) and (JA) signaling pathways, respectively, were highly expressed in tomato plants treated with ZONPs compared to untreated plants. Growth characters of tomato plants treated with ZONPs were significantly enhanced relative to untreated plants. The control of bacterial speck pathogen of tomato using ZONPs through its direct antibacterial and by developing of systemic resistance in treated tomatoes against the pathogen is considered the first report.

The environmental Kuznets curve (EKC) hypothesis is used to describe the relationship between economic development and environmental pollution. In this paper, an EKC-estimating method based on an improved nonlinear gray Bernoulli model (NGBM) is proposed from the perspective of gray system modeling. First, a non-equigap NGBM is established taking the GDP per capita and pollutant emission as the input and output of the gray system, respectively. Then, a particle swarm optimization algorithm is used to find the parameters in the nonlinear model. Finally, the EKC is validated by applying it to the per capita emission of wastewater, SO₂, CO₂, and soot in China. The results show that the new method proposed in this paper optimizes the exponent of the NGBM which allows it to describe the trends in the different morphological data very well, resulting in a higher fitting accuracy. China’s per capita emission of wastewater, SO₂, CO₂, and soot show trends corresponding to monotonically increasing, inverted U-shaped, S-shaped, and N-shaped changes, respectively.

Organophosphorus pesticides (OPs) are widely used for controlling pests worldwide. The inhibitory effects of these pesticides on acetylcholinesterase lead to neurotoxic damages. The oxidative stress is responsible for several neurological diseases, including Parkinson’s disease, seizure, depression, and Alzheimer’s disease. Strong evidence suggests that dysfunction of mitochondria and oxidative stress are involved in neurological diseases. OPs can disturb the function of mitochondria by inducing oxidative stress. In the present study, we tried to highlight the role of dysfunction of mitochondria and the induction of oxidative stress in the neurotoxicity induced by OPs. Additionally, the amelioration of OP-induced oxidative damage and mitochondrial dysfunctional through the chemical and natural antioxidants have been discussed.

Eutrophication has been a critical environmental issue due to soil nitrogen (N) and phosphorus (P) loss in runoff from agricultural lands. Plant hedgerow is an important measure to prevent soil erosion and reduce agricultural non-point source pollution (NPSP). In the present study, we searched 3683 research papers on plant hedgerows published from 1980 to March 2020. After screening, we used 53 effective papers on plant hedgerows for the meta-analysis by using Stata 15.1. The results showed that plant hedgerows significantly increased soil organic matter (SOM) (standardized mean difference (SMD) = 1.46; 95% confidence interval (CI) = 1.12–1.80 > 0), total N (TN) (SMD = 1.33; 95% CI 0.98–1.68 > 0), total P (SMD = 0.73; 95% CI 0.26–1.20 > 0), alkali N (SMD = 0.86; 95% CI 0.52–1.21 > 0), available P (SMD = 1.28; 95% CI 0.75–1.81 > 0) and readily available potassium (K) (SMD = 1.20; 95% CI 0.75–1.65 > 0) concentrations but exhibited no significant effects on soil total K concentration (SMD = 0.17; 95% CI − 0.13–0.47 < 0). Plant hedgerows showed a greater effect on SOM increase than soil N, P, and K, and soil TN increase than the available state, but the opposite trend was observed for P and K. This meta-analysis can clarify the influence of plant hedgerows on soil nutrients and provide ideas for the prevention and control of agricultural NPSP.

Recently, research on the biological effects of microplastics (MPs) has grown exponentially. However, effects of MPs on freshwater fishes and the mechanisms of the biological effects of MPs were limited. So, the purpose of the current study was to clarify the effects of microplastics on oxidative stress response, DNA fragmentation, and proteinogram of the early juvenile stage of Nile Tilapia (Oreochromis niloticus). The fishes were assigned into four groups: one control, three MPs-exposed groups as 1 mg/L of MPs, 10 mg/L of MPs, and 100 mg/L of MPs respectively for 15 days and 15 days of recovery. The activities of superoxide dismutase, catalase, total peroxides, and oxidative stress index (OSI), as well as lipid peroxidation and DNA fragmentation, increased in groups exposed to MPs compared to the control group in a dose-dependent manner. In contrast, the activity of total antioxidant capacity decreased in groups exposed to MPs compared to the control group in a dose-dependent manner. The electrophoretic pattern of muscle proteins revealed alteration in the proteinogram in the MPs-exposed groups compared to control. After the recovery period, the activities of superoxide dismutase, catalase, total peroxides, total antioxidant capacity, lipid peroxidation, DNA fragmentation, and the electrophoretic pattern of muscle proteins returned to normal levels in 1 mg/L of MPs-exposed group. Combined with our previous work, these results suggest that MPs cause the overproduction of reactive oxygen species (ROS) and alters the antioxidants parameters, resulting in oxidative stress and DNA damage. The present study fosters a better understanding of the toxic effects of MPs on Tilapia as a freshwater model. Graphical Abstract

The fate of carbaryl in the Seto Inland Sea (west Japan) was predicted using a mass distribution model using carbaryl concentrations in river and sea water samples, degradation data, and published data. The predicted carbaryl concentrations in water in Kurose River and the Seto Inland Sea were 4.320 and 0.2134 μg/L, respectively, and the predicted concentrations in plankton, fish, and sediment were 0.4140, 2.436, and 1.851 μg/g dry weight, respectively. The carbaryl photodegradation and biodegradation rates were higher for river water (0.330 and 0.029 day⁻¹, respectively) than sea water (0.23 and 0.001 day⁻¹, respectively). The carbaryl photodegradation rates for river and sea water (0.33 and 0.23 day⁻¹, respectively) were higher than the biodegradation rates (0.029 and 0.001 day⁻¹, respectively). The hydrolysis degradation rate for carbaryl in sea water was 0.003 day⁻¹, and the half-life was 231 days. Land (via rivers) was the main source of carbaryl to the Seto Inland Sea. The model confirmed carbaryl is distributed between sediment, plankton, and fish in the Seto Inland Sea. Degradation, loss to the Open Ocean, and sedimentation are the main carbaryl sinks in the Seto Inland Sea, accounting for 43.81, 27.90, and 17.68%, respectively, of total carbaryl inputs. Carbaryl source and sink data produced by the model could help in the management of the negative impacts of carbaryl on aquatic systems and human health.

Following an increasing number of artificial electromagnetic field (EMF) sources in human surrounding, a number of research studies have been devoted to the issue of environmental EMF pollution. A particular attention has been attributed to the highly sensitive EMF zones, where people can stay for a longer period of time, which, among others, includes university campuses. Thus, the modern approach of long-term EMF monitoring has been established, carrying out cumulative field strength measurements at locations that are most visited by student population and university staff. The goal was to establish periodic and systematic EMF investigation over such highly sensitive areas, through a standardized procedure for EMF monitoring. In this paper, details about two EMF monitoring campaigns over the University of Novi Sad campus were presented, performing comparative analysis of their results. The obtained results revealed the increase (up to four times) of the cumulative field strength values, as well as the general population exposure, at specific locations. Between these two campaigns, the emergence of the new base station, as well as numerous Wi-Fi networks, was noticed in the campus. Consequently, the highest field strength values were acquired at two locations, most directly exposed to the main beams of base station’s antennas, although all obtained values were at least five times lower than the minimal reference levels prescribed by the Serbian legislation. Even though such results are acceptable, the future monitoring campaigns should be planned, particularly since the installation of new EMF sources are expected in the campus of the University of Novi Sad.

Leakage of CO₂ from the geological storage is a serious issue for the sustainability of the receiving fresh soil–water systems. Subsurface water quality issues are no longer related to one type of pollution in many regions around the globe. Thus, an effort has been made to review studies performed to investigate supercritical CO₂ (scCO₂) and CO₂ enrich brine migration and it's leakage from geological storage formations. Further, the study also reviewed it's impacts on fresh soil–water systems, soil microbes, and vegetation. The first part of the study discussed scCO₂/CO₂ enrich brine migration and its leakage from storage formations along with it's impact on pore dynamics of hydrological regimes. Later, a state-of-the-art literature survey has been performed to understand the role of CO₂–brine leakage on groundwater dynamics and its quality along with soil microbes and plants. It is observed in the literature survey that most of the studies on CO₂–brine migration in storage formations reported significant CO₂–brine leakage due to over-pressurization through wells (injections and abandoned), fracture, and faults during CO₂ injection. Thus, changes in the groundwater flow and water table dynamics can be the first impact of the CO₂–brine leakage. Subsequently, three major alterations may also occur—(i) drop in pH of subsurface water, (ii) enhancement of organic compounds, and (iii) mobilization of metals and metalloids. Geochemical alteration depends on the amount of CO₂ leaked and interactions with host rocks. Therefore, such alteration may significantly affect soil microbial dynamics and vegetation in and around CO₂ leakage sites. In-depth analysis of the available literature fortifies that a proper subsurface characterization along with the bio-geochemical analysis is extremely important and should be mandatory to predict the more accurate risk of CO₂ capture and storage activities on soil–water systems.

Surface sediments can accumulate contaminants that affect microorganisms and invertebrates and disturb benthic ecological functions. However, effects of contaminants on ecological functions supported by sediment communities are understudied. Here, we tested the relevance of two simple tools to assess the ecotoxicological effects of metal contamination on natural sediment communities using particulate organic matter breakdown and decomposition as a functional descriptor. To this aim, we performed a 21-day laboratory microcosm experiment to assess the individual and combined effects of Cu and As (nominal concentration of 40 mg kg⁻¹ dw each) using the bait-lamina method (cellulose, bran flakes, and active coal in PVC strips) as well as artificial tablets (cellulose, bran flakes and active coal embedded in an agar matrix). Sediment toxicity was also evaluated using the standardized ostracod toxicity test. Both the bait-lamina and artificial tablet methods showed low effects of As on organic matter breakdown and decomposition but strong effects of Cu on this important ecological function. Both also showed that the presence of Cu and As in mixture in the sediment induced total inhibition of organic matter breakdown and decomposition. The ostracod toxicity test also showed high toxicity of Cu-spiked and Cu-plus-As-spiked sediments and low toxicity of As-spiked sediments. Besides confirming that artificial organic matter substrates are relevant and useful for assessing the functional effects of contaminants on sediment micro- and macro-organism communities, these results suggest that the proposed methods offer promising perspectives for developing tools for use in assessing functional ecotoxicology in the sediment compartment.