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Personal exposure to benzene of selected population groups and impact of commuting modes in Ho Chi Minh, Vietnam Texte intégral
2013
Lan, Tran Thi Ngoc | Liem, Ngo Quang | Binh, Nguyen Thi Thanh
Personal exposure to benzene of selected population groups, and impacts of traffic on commuters in Ho Chi Minh City were investigated. The study was carried out in June, July and November 2010. The preliminary data showed that on average, personal exposure to benzene for non-occupational people in Ho Chi Minh is ∼18 μg/m3 and most of the exposure is due to commuting. Benzene exposure during travelling by bus, taxi and motorcycle is, respectively, 22–30, 22–39 and 185–240 μg/m3. Motorcycle–taxi drivers, petrol filling employees and street vendors suffer high daily exposures at 116, 52, 32 μg/m3, respectively. Further measurements are needed for a better risk assessment and finding effective measures to reduce exposure.
Afficher plus [+] Moins [-]Chronic exposure to volcanogenic air pollution as cause of lung injury Texte intégral
2013
Camarinho, Ricardo | Garcia, Patrícia Ventura | Rodrigues, Armindo Santos
Few studies were made regarding the pulmonary effects of exposure to volcanogenic air pollution, representing an unrecognized health risk for humans inhabiting non-eruptive volcanically active areas (10% of world human population). We tested the hypothesis whether chronic exposure to air pollution of volcanogenic origin causes lung injury, using wild mice (Mus musculus) as model. Lung injury was determined using histological morphometric parameters, inflammatory status (InfS) and the amount of black silver deposits (BSD). Mice exposed to volcanogenic air pollution have decreased percentage of alveolar space, alveolar perimeter and lung structural functionality (LSF) ratio and, increased alveolar septal thickness, amount of BSD and InfS. For the first time it is evidenced that non-eruptive active volcanism has a high potential to cause lung injury. This study also highlights the usefulness of M. musculus as bioindicator species, and of the developed biomarker of effect LSF ratio, for future animal and/or human biomonitoring programs.
Afficher plus [+] Moins [-]An SPE LC–MS/MS method for the analysis of human and veterinary chemical markers within surface waters: An environmental forensics application Texte intégral
2013
Fenech, Cecilia | Nolan, Kieran | Rock, Luc | Morrissey, Anne
In this study, the use of co-occurring discriminators of sewage and manure was assessed as a potential way to disentangle sewage and manure sources. A suite of human and veterinary derived chemical markers, which includes pharmaceuticals and compound such as food additives, has been identified for this purpose. The suite was selected in such a manner as to provide additional source characterisation, e.g. differentiating raw versus treated sewage inputs. An SPE–LC–MS/MS method was developed and validated for the determined suite of chemical markers with a detection limit of up to 50 pg L−1. This represents one of the lowest limits of detection for pharmaceuticals reported in literature. To illustrate the suitability of the proposed method to differentiate sewage and manure inputs to surface water bodies, results from surface water samples collected at monitoring sites corresponding to specific land use types within Ireland are discussed.
Afficher plus [+] Moins [-]Expression of zinc and cadmium responsive genes in leaves of willow (Salix caprea L.) genotypes with different accumulation characteristics Texte intégral
2013
Konlechner, Cornelia | Türktaş, Mine | Langer, Ingrid | Vaculík, Marek | Wenzel, Walter W. | Puschenreiter, Markus | Hauser, Marie-Theres
Salix caprea is well suited for phytoextraction strategies. In a previous survey we showed that genetically distinct S. caprea plants isolated from metal-polluted and unpolluted sites differed in their zinc (Zn) and cadmium (Cd) tolerance and accumulation abilities. To determine the molecular basis of this difference we examined putative homologues of genes involved in heavy metal responses and identified over 200 new candidates with a suppression subtractive hybridization (SSH) screen. Quantitative expression analyses of 20 genes in leaves revealed that some metallothioneins and cell wall modifying genes were induced irrespective of the genotype's origin and metal uptake capacity while a cysteine biosynthesis gene was expressed constitutively higher in the metallicolous genotype. The third and largest group of genes was only induced in the metallicolous genotype. These data demonstrate that naturally adapted woody non-model species can help to discover potential novel molecular mechanisms for metal accumulation and tolerance.
Afficher plus [+] Moins [-]Assessing the combined risks of PAHs and metals in urban soils by urbanization indicators Texte intégral
2013
Peng, Chi | Ouyang, Z. (Zhiyun) | Wang, Meie | Chen, Weiping | Li, Xiaoma | Crittenden, John C.
We quantitatively describe the impacts of urbanization on the accumulation of polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs) in urban soils as well as their health risks to residents. Residential building age, population density, road density, and distance from urban center were used as urbanization level indicators. Significant correlations were found between those urbanization indicators and the amounts of PAHs, Cu, Cd, Pb, Zn and As in residential soils. The exposure time of soils to urban air was the primary factor affecting soil pollution, followed by local road density and population density. Factor analysis suggested that 59.0% of the elevated pollutant concentrations were caused by citywide uniform deposition, and 15.3% were resulted from short-range deposition and/or non-combustion processes. The combined health risks posed by soil PAHs and HMs were aggravated with time and can be expressed as functions of residence age, road density, and other urbanization indicators.
Afficher plus [+] Moins [-]Assessment of exposure to heavy metals and health risks among residents near abandoned metal mines in Goseong, Korea Texte intégral
2013
Ji, Kyunghee | Kim, Jungkon | Lee, Minjung | Park, Soyoung | Kwon, Ho-Jang | Cheong, Hae-Kwan | Jang, Jae-Yeon | Kim, Dae-Seon | Yu, Seungdo | Kim, Young Wook | Lee, Kwang-Young | Yang, Seoung-Oh | Jhung, Ik Jae | Yang, Won-Ho | Paek, Do-Hyun | Hong, Yun-Chul | Choi, Kyungho
Metal contamination from mining activity is of great concern because of potential health risks to the local inhabitants. In the present study, we investigated the levels of Cd, Cu, As, Pb, and Zn in environmental samples and foodstuffs grown in the vicinity of the mines in Goseong, Korea, and evaluated potential health risks among local residents. Soils near the mines exceeded the soil quality standard values of Cu, As, and Zn contamination. The concentrations of Cd, Cu, Pb, and Zn in crop samples collected from the study area were significantly higher than those of the reference area. Some rice samples collected from the study area exceeded the maximum permissible level of 0.2 mg Cd/kg. The intake of rice was identified as a major contributor (≥75%) to the estimated daily intake among the residents. The average estimated daily intakes of metals were, however, below the provisional tolerable daily intake.
Afficher plus [+] Moins [-]Assessment of potential climate change impacts on peatland dissolved organic carbon release and drinking water treatment from laboratory experiments Texte intégral
2013
Tang, R. | Clark, J.M. | Bond, T. | Graham, N. | Hughes, D. | Freeman, C.
Assessment of potential climate change impacts on peatland dissolved organic carbon release and drinking water treatment from laboratory experiments Texte intégral
2013
Tang, R. | Clark, J.M. | Bond, T. | Graham, N. | Hughes, D. | Freeman, C.
Catchments draining peat soils provide the majority of drinking water in the UK. Over the past decades, concentrations of dissolved organic carbon (DOC) have increased in surface waters. Residual DOC can cause harmful carcinogenic disinfection by-products to form during water treatment processes. Increased frequency and severity of droughts combined with and increased temperatures expected as the climate changes, have potentials to change water quality. We used a novel approach to investigate links between climate change, DOC release and subsequent effects on drinking water treatment. We designed a climate manipulation experiment to simulate projected climate changes and monitored releases from peat soil and litter, then simulated coagulation used in water treatment. We showed that the ‘drought’ simulation was the dominant factor altering DOC release and affected the ability to remove DOC. Our results imply that future short-term drought events could have a greater impact than increased temperature on DOC treatability.
Afficher plus [+] Moins [-]Assessment of potential climate change impacts on peatland dissolved organic carbon release and drinking water treatment from laboratory experiments Texte intégral
2013
Tang, R. | Clark, Joanna M. | Bond, T. | Graham, N. | Hughes, D. | Freeman, C.
Catchments draining peat soils provide the majority of drinking water in the UK. Over the past decades, concentrations of dissolved organic carbon (DOC) have increased in surface waters. Residual DOC can cause harmful carcinogenic disinfection by-products to form during water treatment processes. Increased frequency and severity of droughts combined with and increased temperatures expected as the climate changes, have potentials to change water quality. We used a novel approach to investigate links between climate change, DOC release and subsequent effects on drinking water treatment. We designed a climate manipulation experiment to simulate projected climate changes and monitored releases from peat soil and litter, then simulated coagulation used in water treatment. We showed that the ‘drought’ simulation was the dominant factor altering DOC release and affected the ability to remove DOC. Our results imply that future short-term drought events could have a greater impact than increased temperature on DOC treatability.
Afficher plus [+] Moins [-]Design and field-scale implementation of an “on site” bioremediation treatment in PAH-polluted soil Texte intégral
2013
Pelaez, A.I. | Lores, I. | Sotres, A. | Mendez-Garcia, C. | Fernandez-Velarde, C. | Santos, J.A. | Gallego, J.L.R. | Sanchez, J.
Design and field-scale implementation of an “on site” bioremediation treatment in PAH-polluted soil Texte intégral
2013
Pelaez, A.I. | Lores, I. | Sotres, A. | Mendez-Garcia, C. | Fernandez-Velarde, C. | Santos, J.A. | Gallego, J.L.R. | Sanchez, J.
An “on site” bioremediation program was designed and implemented in soil polluted with polycyclic aromatic hydrocarbons (PAHs), especially naphthalene. We began by characterizing the soil's physical and chemical properties. A microbiological screening corroborated the presence of microorganisms capable of metabolizing PAHs. We then analyzed the viability of bioremediation by developing laboratory microcosms and pilot scale studies, to optimize the costs and time associated with remediation. The treatment assays were based on different types of biostimulants, such as a slow or fast-release fertilizer, combined with commercial surfactants. Once the feasibility of the biostimulation was confirmed, a real-scale bioremediation program was undertaken in 900 m3 of contaminated soil. The three-step design reduced PAH contamination by 94.4% at the end of treatment (161 days). The decrease in pollutants was concomitant with the selection of autochthonous bacteria capable of degrading PAHs, with Bacillus and Pseudomonas the most abundant genera.
Afficher plus [+] Moins [-]Design and field-scale implementation of an "on site" bioremediation treatment in PAH-polluted soil Texte intégral
2013
Peláez Andrés, Ana Isabel | Lores Ovies, Iván | Sotres, A. | Méndez García, Celia | Fernández Velarde, C. | Santos, J. A. | Rodríguez Gallego, José Luis | Sánchez Martín, Jesús
Feasibility of using low density polyethylene sheets to detect atmospheric organochlorine pesticides in Alexandria, Egypt Texte intégral
2013
Khairy, Mohammed A. | Lohmann, Rainer
Egypt is a major agricultural country in Africa with a known past of organochlorine pesticides (OCPs) application, yet data on atmospheric levels of OCPs in Egypt is sparse. Low density polyethylene (LDPE) passive samplers were therefore deployed for 3 weeks each at 11 locations in July, 2010 and January, 2011 in Alexandria to screen for gas-phase OCPs. Performance reference compounds were used to investigate the uptake kinetics. Field-derived sampler-air partitioning coefficients (KPE-As) for OCPs were significantly correlated against the compounds' subcooled liquid vapor pressure (log PL): [log KPE-A = −0.77 ± 0.07*log PL + 6.35 ± 0.13 (R2 = 0.90; n = 17; SE = 0.19; p < 0.001)]. Estimated and measured OCP concentrations in Alexandria agreed well (factor difference ≤ 2) indicating the feasibility of monitoring OCPs using LDPEs. OCP concentrations ranged from <LOD to 168 pg/m3. Calculated isomeric ratios indicated recent usage of chlordanes and endosulfans.
Afficher plus [+] Moins [-]Occurrence and dynamics of micropollutants in a karst aquifer Texte intégral
2013
Morasch, Barbara
Karst systems represent important yet vulnerable drinking water resources. A wide spectrum of pollutants may be released into karst groundwater from agriculture, livestock farming, private households, and industry. This work provides an overview on the occurrence and dynamics of micropollutants in a karst system of the Swiss Jura. Ten months of intensive monitoring for micropollutants confirmed that the swallow hole draining an agricultural plain was the main entry path for pesticides into the karst system and the two connected springs. Elevated fungicide concentrations in winter and occasional quantification of pharmaceuticals suggested wood- or façade treatment and domestic sewer as additional sources of contamination. A continuous atrazine signal in the low ng/L range might affect the autochthonous endokarst microbial community and represents a potential risk for the human population through karst groundwater.
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