The current study assesses critical condition of oil dispassion, considering the unsaturated soil condition dispersity behavior for oil dispersion. The numerical model is used as a finite element method to model the oil spill pollution with two different saturated and unsaturated soil conditions chosen and their pollution dispersion results compared. Extracted results from numerical model show that considering the form of unsaturated soil, by changing the matric suction its soil conductivity ratio will differ. Regarding the current study analysis, it has been observed that the pattern of oil dispersion in case of unsaturated soil can be changed, in comparison to saturated soil condition. The vertical penetration of oil pollution in both cases of saturated and unsaturated soil condition will be more than horizontal dispersion pollution speed.  As for oil pollution control in soil domain, the condition of unsaturated soil may be controllable, compared to the saturated one. Extracted results show that oil dispersion velocity, considering saturated soil, is more than 10 times greater than unsaturated one.

Due to the persistent pollution of soils by an organochlorine, chlordecone (CLD also known as Kepone ©) in the French West Indies, some crops may be contaminated beyond the European regulatory threshold, the maximum residue limit (MRL). Farmers need to be able to foresee the risk of not complying with the regulatory threshold in each field and for each crop, if not, farmers whose fields are contaminated would have to stop cultivating certain crops in the fields concerned. To help farmers make the right choices, we studied the relationship between contamination of the soil and contamination of crops. We showed that contamination of a crop by CLD depended on the crop concerned, the soil CLD content and the type of soil. We grouped crop products in three categories: (i) non-uptakers and low-uptakers, (ii) medium-uptakers, and (iii) high-uptakers, according to their level of contamination and the resulting risk of exceeding MRL. Using a simulation model, we computed the soil threshold required to ensure the risk of not complying with MRL was sufficiently low for each crop product and soil type. Threshold values ranged from 0.02 ?gkg?1 for dasheen grown in nitisol to 1.7 ?gkg?1 for yam grown in andosol in the high-uptake category, and from 1 ?gkg?1 for lettuce grown in nitisol to 45 ?gkg?1 for the leaves of spring onions grown in andosol in the medium-uptake category. Contamination of non-uptakers and low-uptakers did not depend on soil contamination. With these results, we built an easy-to-use decision support tool based on two soil thresholds (0.1 and 1 ?gkg?1) to enable growers to adapt their cropping system and hence to be able to continue farming. (Résumé d'auteur)tttttt

Spreading livestock manure as fertilizer on farmlands is a widespread practice. It represents the major source of heavy metal(loid)s (HM) input in agricultural soils. Since zinc (Zn) is present at high concentrations in manure, it poses special environmental concerns related to phytotoxicity, groundwater contamination, and introduction in the food chain. Therefore, investigations on the fate and behavior of manure-borne Zn, when it enters the soil environment, are necessary to predict the environmental effects. Nevertheless, long-term field studies assessing Zn speciation in the organic waste matrix, as well as within the soil after manure application, are lacking. This study was designed to fill this gap. Using SEM-EDS and XAS analysis, we reported the following new results: (i) ZnS made up 100% of the Zn speciation in the pig slurry (the highest proportion of ZnS ever observed in organic waste); and (ii) ZnS aggregates were about 1-?m diameter (the smallest particle size ever reported in pig slurry). Moreover, the pig slurry containing ZnS was spread on the soil over an 11-year period, totaling 22 applications, and the resulting Zn speciation within the amended soil was analyzed. Surprisingly, ZnS, i.e. the only species responsible for a nearly 2-fold increase in the Zn concentration within the amended soil, was not detected in this soil. Based on SEM-EDS and XAS observations, we put forward the hypothesis that Zn in the pig slurry consisted of nano-sized ZnS crystallites that further aggregated. The low stability of ZnS nanoparticles within oxic and complex environments such as the studied soil was the key explanation for the radical change in pig slurry-borne Zn speciation after long-term amendments. (Résumé d'auteur)

acceptedVersion

peer reviewed | Very few ecotoxicological studies have been performed on long-term exposure under controlled conditions, hence limiting the assessment of the impact of chronic and diffuse chemical pressures on the health of aquatic organisms. In this study, an ecotoxicoproteomic approach was used to assess the integrated response and possible acclimation mechanisms in Gammarus fossarum following chronic exposures to Cd, Cu or Pb, at environmentally realistic concentrations (i.e. 0.25, 1.5 and 5 µg/L respectively). After 10-week exposure, changes in protein expression were investigated in caeca of control and exposed males. Gel-free proteomic analyses allowed for the identification of 35 proteins involved in various biological functions, for which 23 were significantly deregulated by metal exposures. The protein deregulation profiles were specific to each metal, providing evidence for metal-specific action sites and responses of gammarids. Among the tested metals, Cu was the most toxic in terms of mortality, probably linked with persistent oxidative stress. Moulting and osmoregulation were the major biological functions affected by Cu in the long-term. In Pb-exposed gammarids, significant deregulations of proteins involved in immune response and cytoskeleton were observed. Reproduction appears to be strongly affected in gammarids chronically exposed to Cd or Pb. Besides, modified expressions of several proteins involved in energy transfer and metabolism highlighted important energetic reshuffling to cope with chronic metal exposures. These results support the fact that metallic pressures induce a functional and energetic cost for individuals of G. fossarum with potential repercussions on population dynamics. Furthermore, this ecotoxicoproteomic study offers promising lines of enquiry in the development of new biomarkers that could make evidence of long-term impacts of metals on the health of organisms.

La problématique air-climat-société est caractérisée à l’heure actuelle par une double propriété de transversalité (les polluants altérant la qualité de l’air et responsables des gaz à effet de serre sont souvent les mêmes) et de multiscalarité (de l’échelle du bâti à celle de la planète). À partir de ce point de départ et sous l’angle des sciences sociales, l’article interroge la place dévolue à ces enjeux au sein du répertoire de la « ville durable », qui marque de plus en plus les façons de faire et vivre la ville. Nous déplaçons le regard à partir de ce qui est souvent lu d’abord comme des questions techniques (mesure de la pollution atmosphérique, etc.), pour les restituer dans leur épaisseur sociale, celle de l’action publique autant que des modes de vie en ville. Méthodologiquement, nous procédons par une approche bibliométrique comparée, à partir d’un corpus de 18 revues scientifiques, francophones et anglophones. Une analyse statistique et textuelle a été conduite avec le logiciel libre IRaMuTeQ, spécifiant des univers de co-occurrence lexicale. Elle établit la portée de trois déclinaisons structurantes dans les lectures à la fois notionnelles, critiques et plus appliquées de la durabilité urbaine : le changement climatique et ses modèles, les déplacements et transports urbains, et le métabolisme urbain rapporté aux consommations d’énergie et aux flux de matières. Au final, c’est une double dimension théorique et pratique qui fait sens, et qu’atteste la démonstration à travers la force des liens entre les termes récurrents, les classes lexicales et les segments significatifs dégagés.

Telomeres are non-coding DNA repeats located at the termini of eukaryotic chromosomes, regulated by dynamic processes balancing shortening and maintenance. Despite a mechanism to slow-down telomere shortening, cell division leads to progressive attrition of chromosomes, leading to the onset of cellular senescence or apoptosis. However, telomere restoration based on telomerase activity is the primary mechanism for telomere maintenance. Telomere length is associated to health and survival and can be impacted by a broad panel of environmental factors. However, the effect of contaminants on telomeres is poorly known for living organisms. The aim of this study was to investigate relationships between some poly- and perfluoroalkyl substances (PFASs), body condition and telomere length by using both a crosssectional and longitudinal approach in adult breeding Black-legged kittiwakes (Rissa tridactyla) from Svalbard. First, we examined the associations between absolute telomere length and PFASs contamination in a given year (cross-sectional approach). Second, we investigated the relationships between telomere dynamics and PFASs contamination within a two years’ time frame (longitudinal approach). Our results did not show any significant relationships of PFASs and body condition with absolute telomere length in a given year. Surprisingly, we found a positive and significant relationship between PFASs and telomere dynamics in both sexes with elongated telomere in birds bearing the highest concentrations of PFASs. Our study underlines (i) the need to investigate PFAS effects on telomere dynamics with a longitudinal approach and (ii) a potential positive effect of these contaminants on telomere length, with the most contaminated birds showing the slowest rate of telomere shortening or even displaying elongated ones. Our study is the first to report a relationship between PFASs and telomere length in freeliving vertebrates. A possible underlying mechanism and other potential confounding factors are discussed. Organic contaminants PFASs Black-legged kittiwake Svalbard DNA | acceptedVersion

A methodology is presented and applied to assess the oil contamination probability in the Gulf of Patras and the environmental impacts on the environmentally sensitive area of Mesolongi – Aitoliko coastal lagoons, and to examine the effectiveness of response systems. The procedure consists of the following steps: (1) Determination of the computational domain and the main areas of interest, (2) determination of the drilling sites and oil release characteristics, (3) selection of the simulation periods and collection of environmental data, (4) identification of the species of interest and their characteristics, (5) performance of stochastic calculations and oil contamination probability analysis, (6) determination of the worst-cases, (7) determination of the characteristics of response systems, (8) performance of deterministic calculations, and (9) assessment of the impact of oil spill in the areas of interest. Stochastic calculations that were performed for three typical seasonal weather variations of the year 2015, three oil release sites and specific oil characteristics, showed that there is a considerable probability of oil pollution that reaches 30% in the Mesolongi – Aitoliko lagoons. Based on a simplified approach regarding the characteristic of the sensitive birds and fish in the lagoons, deterministic calculations showed that 78–90% of the bird population and 2–4% of the fish population are expected to be contaminated in the case of an oil spill without any intervention. The use of dispersants reduced the amount of stranded oil by approximately 16–21% and the contaminated bird population of the lagoons to approximately 70%; however, the affected fish population increased to 6–8.5% due to the higher oil concentration in the water column. Mechanical recovery with skimmers “cleaned” almost 10% of the released oil quantity, but it did not have any noticeable effect on the stranded oil and the impacted bird and fish populations | acceptedVersion

Combined exposure to engineered nanoparticles (ENPs) and anthropogenic contaminants can lead to changes in bioavailability, uptake and thus effects of both groups of contaminants. In this study we investigated effects of single and combined exposures of silver (Ag) nanoparticles (AgNPs) and the synthetic hormone 17a-ethinylestradiol (EE2) on tissue uptake of both contaminants in juvenile turbot (Scophthalmus maximus). Silver uptake and tissue distribution (gills, liver, kidney, stomach, muscle and bile) were analyzed following a 14-day, 2-h daily pulsed exposure to AgNPs (2 mg L 1 and 200 mg L 1), Agþ (50 mg L 1), EE2 (50 ng L 1) and AgNP þ EE2 (2 or 200 mg L 1þ50 ng L 1). Effects of the exposures on plasma vitellogenin (Vtg) levels, EE2 and steroid hormone concentrations were investigated. The AgNP and AgNP þ EE2 exposures resulted in similar Ag concentrations in the tissues, indicating that combined exposure did not influence Ag uptake in tissues. The highest Ag concentrations were found in gills. For the Agþ exposed fish, the highest Ag concentrations were measured in the liver. Our results show dissolution processes of AgNPs in seawater, indicating that the tissue concentrations of Ag may partly originate from ionic release. Plasma EE2 concentrations and Vtg induction were similar in fish exposed to the single contaminants and the mixed contaminants, indicating that the presence of AgNPs did not significantly alter EE2 uptake. Similarly, concentrations of most steroid hormones were not significantly altered due to exposures to the combined contaminants versus the single compound exposures. However, high concentrations of AgNPs in combination with EE2 caused a drop of estrone (E1) (female fish) and androstenedione (AN) (male and female fish) levels in plasma below quantification limits. Our results indicate that the interactive effects between AgNPs and EE2 are limited, with only high concentrations of AgNPs triggering synergistic effects on plasma steroid hormone concentrations in juvenile turbots. | acceptedVersion