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Bioremediation of diesel from a rocky shoreline in an arid tropical climate Texte intégral
2015
Guerin, Turlough F.
A non invasive sampling and remediation strategy was developed and implemented at shoreline contaminated with spilt diesel. To treat the contamination, in a practical, cost-effective, and safe manner (to personnel working on the stockpiles and their ship loading activity), a non-invasive sampling and remediation strategy was designed and implemented since the location and nature of the impacted geology (rock fill) and sediment, precluded conventional ex-situ and any in-situ treatment where drilling is required. A bioremediation process using surfactant, and added N & P and increased aeration, increased the degradation rate allowing the site owner to meet their regulatory obligations. Petroleum hydrocarbons decreased from saturation concentrations to less than detectable amounts at the completion of treatment.
Afficher plus [+] Moins [-]Metal concentrations and soluble iron speciation in fine particulate matter from light rail activity in the Denver-Metropolitan area Texte intégral
2015
Cartledge, Benton T. | Majestic, Brian J.
Fine particulate matter samples (PM2.5) were collected from three locations around the Denver–Metropolitan area to study the impacts of the ground–level light rail on airborne metal concentrations. Size–segregated PM was collected on board the trains, at the side of the tracks, and at a background location in downtown Denver. Results from this study showed highest crustal enrichment factors of metals in samples collected on board the train, despite lower concentrations of total PM2.5. Metals commonly found in steel such as Fe, Cr, Mn, and Ni, all exhibited elevated concentrations relating to train activity over the background site. Iron in the PM2.5 at track–side and on board the trains was above the background by a factor of 1.89 and 1.54, respectively. For Mn, the ratios were 1.34 for the track–side and 0.94 for the on board samples. Cr and Ni exhibited higher ratios over the background only in samples collected on board the trains at 1.59 (Cr) and 1.26 (Ni). Soluble metals were measured with Ni (53–71%), Cu (52–81%), and Zn (30–81%) exhibiting the highest solubilities across the different sites. Soluble Fe ranged from 8–15% for the total measured Fe, indicating a non–crustal source of Fe. Soluble Fe was also characterized as Fe(II) and Fe(III) with 87–90% of the soluble Fe being Fe(II), similar to results from studies in Los Angeles, CA and East St. Louis, IL but higher than in Atlanta, GA and Waukesha, WI.
Afficher plus [+] Moins [-]Variation of dissolved organic carbon transported by two Chinese rivers: The Changjiang River and Yellow River Texte intégral
2015
Liu, Dong | Pan, Delu | Bai, Yan | He, Xianqiang | Wang, Difeng | Zhang, Lin
Real-time monitoring of riverine dissolved organic carbon (DOC) and the associated controlling factors is essential to coastal ocean management. This study was the first to simulate the monthly DOC concentrations at the Datong Hydrometric Station for the Changjiang River and at the Lijin Hydrometric Station for the Yellow River from 2000 to 2013 using a multilayer back-propagation neural network (MBPNN), along with basin remote-sensing products and river in situ data. The average absolute error between the modeled values and in situ values was 9.98% for the Changjiang River and 10.84% for the Yellow River. As an effect of water dilution, the variations of DOC concentrations in the two rivers were significantly negatively affected by discharge, with lower values reported during the wet season. Moreover, vegetation growth status and agricultural activities, represented by the gross primary product (GPP) and cropland area percent (CropPer) in the river basin, respectively, also significantly affected the DOC concentration in the Changjiang River, but not the Yellow River. The monthly riverine DOC flux was calculated using modeled DOC concentrations. In particular, the riverine DOC fluxes were affected by discharge, with 71.06% being reported for the Changjiang River and 90.71% for the Yellow River. Over the past decade, both DOC concentration and flux in the two rivers have not shown significant changes.
Afficher plus [+] Moins [-]Renewables-to-reefs? – Decommissioning options for the offshore wind power industry Texte intégral
2015
Smyth, K. (Katie) | Christie, Nikki | Burdon, Daryl | Atkins, Jonathan P. | Barnes, Richard | Elliott, Michael
The offshore wind power industry is relatively new but increasing globally, hence it is important that the whole life-cycle is managed. The construction–operation–decommissioning cycle is likely to take 20–30years and whilst decommissioning may not be undertaken for many years, its management needs to be addressed in both current and future marine management regimes. This can be defined within a Drivers–Activities–Pressures–State Changes–Impacts (on human Welfare)–Responses framework. This paper considers the main decommissioning options – partial or complete removal of all components. A SWOT analysis shows environmental and economic benefits in partial as opposed to complete removal, especially if habitat created on the structures has conservation or commercial value. Benefits (and repercussions) are defined in terms of losses and gains of ecosystem services and societal benefits. The legal precedents and repercussions of both options are considered in terms of the 10-tenets of sustainable marine management. Finally a ‘renewables-to-reefs’ programme is proposed.
Afficher plus [+] Moins [-]Field experimental observations of highly graded sediment plumes Texte intégral
2015
Jensen, Jacob Hjelmager | Saremi, Sina | Jimenez, Carlos | Hadjioannou, Louis
A field experiment in the waters off the south-eastern coast of Cyprus was carried out to study near-field formation of sediment plumes from dumping. Different loads of sediment were poured into calm and limpid waters one at the time from just above the sea surface. The associated plumes, gravitating towards the seafloor, were filmed simultaneously by four divers situated at different depths in the water column, and facing the plume at different angles. The processes were captured using GoPro-Hero-series cameras. The high-quality underwater footage from near-surface, mid-depth and near-bed positions gives unique insight into the dynamics of the descending plume and near-field dispersion processes, and enables good understanding of flow and sediment transport processes involved from-release-to-deposition of the load in a non-scaled environment. The high resolution images and footages are available through the link provided herein. Observations support the development of a detailed multi-fractional sediment plume model.
Afficher plus [+] Moins [-]Comparative analysis of modeled nitrogen removal by shellfish farms Texte intégral
2015
Rose, Julie M. | Bricker, Suzanne B. | Ferreira, Joao G.
The use of shellfish aquaculture for nutrient removal and reduction of coastal eutrophication has been proposed. Published literature has indicated that nitrogen contained in harvested shellfish can be accurately estimated from shell length:nitrogen content ratios. The range of nitrogen that could be removed by a typical farm in a specific estuarine or coastal setting is also of interest to regulators and planners. Farm Aquaculture Resource Management (FARM) model outputs of nitrogen removal at the shellfish farm scale have been summarized here, from 14 locations in 9 countries across 4 continents. Modeled nitrogen removal ranged from 105lbsacre−1year−1 (12gm−2year−1) to 1356lbsacre−1year−1 (152gm−2year−1). Mean nitrogen removal was 520lbsacre−1year−1 (58gm−2year−1). These model results are site-specific in nature, but compare favorably to reported nitrogen removal effectiveness of agricultural best management practices and stormwater control measures.
Afficher plus [+] Moins [-]Distribution of polychlorinated biphenyl residues in sediments and blue mussels (Mytilus galloprovincialis) from Port Elizabeth Harbour, South Africa Texte intégral
2015
Kampire, E. | Rubidge, G. | Adams, J.B.
Sediment and Mytilus galloprovincialis samples collected from the Port Elizabeth Harbour were analysed for six indicator PCB congeners to assess their contamination status. The concentrations of total PCBs in sediments and M. galloprovincialis ranged from 0.56 to 2.35ng/g dry weight and 14.48 to 21.37ng/g wet weight, respectively. Congeners 138 and 153 were dominant and accounted for an average of 29% and 24% of total PCBs in M. galloprovincialis; 32% and 30% in sediments, respectively. Sediments are home to a wide variety of aquatic life. None of the sediments analysed exceeded the PCB limits recommended the Canadian interim sediment quality guideline and the South African recommended sediment guidelines (21.6ng/g). Both humans and aquatic life are sensitive to the toxic effects of PCBs.
Afficher plus [+] Moins [-]The English Channel: Contamination status of its transitional and coastal waters Texte intégral
2015
Tappin, A.D. | Millward, G.E.
The chemical contamination (organic compounds, metals, radionuclides, microplastics, nutrients) of English Channel waters has been reviewed, focussing on the sources, concentrations and impacts. River loads were only reliable for Pb, whereas atmospheric loads appeared robust for Cd, Pb, Hg, PCB-153 and γ-HCH. Temporal trends in atmospheric inputs were decreasing. Contaminant concentrations in biota were relatively constant or decreasing, but not for Cd, Hg and HBCDD, and deleterious impacts on fish and copepods were reported. However, data on ecotoxicological effects were generally sparse for legacy and emerging contaminants. Intercomparison of activity concentrations of artificial radionuclides in sediments and biota on both Channel coasts was hindered by differences in methodological approaches. Riverine phosphate loads decreased with time, while nitrate loads remained uniform. Increased biomass of algae, attributable to terrestrial inputs of nutrients, has affected benthic production and shellfisheries. A strategic approach to the identification of contaminant impacts on marine biota is recommended.
Afficher plus [+] Moins [-]Persistent organic pollutants and polycyclic aromatic hydrocarbons in mosses after fire at the Brazilian Antarctic Station Texte intégral
2015
Colabuono, Fernanda Imperatrice | Taniguchi, Satie | Cipro, Caio Vinícius Zecchin | da Silva, Josilene | Bícego, Márcia Caruso | Montone, Rosalinda Carmela
A fire at the Brazilian Antarctic Station on February 25th, 2012 led to the burning of material that produced organic pollutants. To evaluate the impact in the surrounding area, polycyclic aromatic hydrocarbons (PAHs) and persistent organic pollutants (POPs) were analyzed in moss samples collected in the vicinities of the station before and after the incident and compared to findings from previous studies in the same region. PCBs were on the same magnitude as that reported in previous studies, which could be associated to the global dispersion of these compounds and may not be related to the local fire. In contrast, concentrations of HCB and PAHs were higher than those reported in previous studies. No PBDEs were found above the method detection limit. Organic contaminant concentrations in mosses decreased a few months after the fire, which is an important characteristic when considering the use of mosses for monitoring recent exposure.
Afficher plus [+] Moins [-]Antibiotics in the coastal environment of the Hailing Bay region, South China Sea: Spatial distribution, source analysis and ecological risks Texte intégral
2015
Chen, Hui | Liu, Shan | Xu, Xiang-Rong | Zhou, Guang-Jie | Liu, Shuang-Shuang | Yue, Wei-Zhong | Sun, Kai-Feng | Ying, Guang-Guo
In this study, the occurrence and spatial distribution of 38 antibiotics in surface water and sediment samples of the Hailing Bay region, South China Sea, were investigated. Twenty-one, 16 and 15 of 38 antibiotics were detected with the concentrations ranging from <0.08 (clarithromycin) to 15,163ng/L (oxytetracycline), 2.12 (methacycline) to 1318ng/L (erythromycin–H2O), <1.95 (ciprofloxacin) to 184ng/g (chlortetracycline) in the seawater, discharged effluent and sediment samples, respectively. The concentrations of antibiotics in the water phase were correlated positively with chemical oxygen demand and nitrate. The source analysis indicated that untreated domestic sewage was the primary source of antibiotics in the study region. Fluoroquinolones showed strong sorption capacity onto sediments due to their high pseudo-partitioning coefficients. Risk assessment indicated that oxytetracycline, norfloxacin and erythromycin–H2O posed high risks to aquatic organisms.
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