Plants are components of ecosystem that transfer elements from abiotic to biotic environments. Several elements, such as As, Cd, Hg, Pb, can be considered as food chain contaminants. Simultaneously, some essential micronutrients (e.g., Cu, Cr, Ni, Zn) at high concentrations may become toxic to both, plants and animals. To secure the aim to describe the uptake of metals by food crop species such vegetables, as radish Raphanus sativus L., leafy lettuce Lactuca sativa L. and dill Anethum graveolens L., were grown in soils of various grading composition and type. There were five soil types selected. A part of soils was contaminated with copper sulphate solution at different target concentrations, while another part was contaminated with mixture of metal (Pb, Cd, Cu, Zn) compounds. In half of treated soil samples the solution of humic substances was added. Harvested vegetables were dried, and after wet digestion with nitric acid quantitative analysis of metal concentrations was performed by use of atomic absorption spectrometry. The highest concentration of copper was detected in vegetable samples grown in soils with less organics, thereby indicating the importance of soil organic matter to metal transfer routes and accumulation rates in plants. Analysis of lettuce grown in soils contaminated with the mixture of metal compounds revealed that zinc was a metal absorbed more intensively, but metal uptake and accumulation was less intensive from peat if compared with other soils.

Contamination of urban areas is directly connected with the lack of adequate waste management planning. Problems mostly arise in former military bases, garages, warehouses and areas with other facilities. For many decades environmental problems caused by pollution in areas of military use were not managed in Latvia. The aim of this research is to assess visual environmental quality and study heavy metal contents in soil of ‘Jaunais Mežaparks’ after demolishing works in the capital of Latvia – Riga, as well as to provide comparison to the former military ‘Daugavgrīva’ site. Research was carried out from November 2011 to February 2012 by soil sampling and further analysis and comparison of the heavy metal content in soil with target and boundary levels in legislation. ‘Jaunais Mežaparks’ is a former military area which is planned to be reused in future. The former military site is planned to be used as the residential neighborhood and is situated close to important recreational object in Mežaparks area – Lake Ķīšezers. According to Riga Development Plan old military sites must be remediated in accordance with environmental legislation if the contamination exceeds critical concentration values. Thus, this case study includes assessment of visual pollution as well as soil heavy metal contamination study. Recommended actions as well as direct remediation technologies to reduce the poisonous impact of contamination to environment in this area are proposed.

Heavy metals as well as other pollutants are widespread and create deleterious impact to the environment and human health. There are different in situ and ex situ technologies of immobilization and removal of contaminants; electrokinetic remediation is one of such technologies. It can be applied for treatment of wide areas, e.g., former industrial and military firing-grounds. Technology is applicable to water soluble contaminants at sites with homogeneous soils that are fine-grained and exhibit both, high permeability and high moisture contents. The aim of the study was to test the efficiency of electrokinetic remediation for copper contaminated clayey soil in laboratory conditions. Pilot scale experiments were applied to test the efficiency of electrokinetic removal of contaminants from soil by application of low voltage direct current (DC). Experimental results show that the use of DC power can be selected for treatment of heavy metal contaminated soils. Batch scale experiments were done by using clayey soil with known physico-mechanical properties, spiked with copper solution of known concentrations. Electric force was changed by varying its parameters. The article gives batch experimental results for diffusion of copper ions in soil under the influence of the external electric field.

There are about 3,000-4,000 heavy metal contaminated sites across Lithuania. According to Lithuanian legal framework, the only way to manage this pollution is ex-situ cleaning which requires excavation, transporting, storage place and later monitoring. This indicates the urgent need of innovative technologies that would be not only costeffective but also environmentally friendly and have a public acceptance. Such technologies are natural and chemically enhanced phytoextractions. Both technologies incorporate plants that can accumulate excessive amounts of heavy metals. During continuous phytoextraction plants accumulate heavy metals throughout all vegetation period and are harvested together with heavy metals when desired biomass is gained. At chemically assisted phytoextraction metal binding chelates are added to increase heavy metal uptake by plants. Since phytoextraction is considered as promising green technology, many efforts are laid to find the most suitable hyperaccumulator plants as well as ecologically safe chelating agents. This paper intends to overview latest researches done at phytoextraction field and look over this kind of remediation possibilities in Lithuania.

Heavy metals are worldwide spread pollutants in soils of functioning as well as abandoned industrial territories, landfills, military areas with its historical contamination, and other sites contaminated by industrial activities. Development of soil and groundwater remediation technologies is a matter of great importance to diminish the hazardous impact of pollution to humans and environment. Sustainable solution can be found for remediation of industrial areas using the stabilization/solidification (S/S) technology, which refers to binding of waste contaminants to a more chemically stable form. Geotechnical properties of soil treated with Portland cement (PC) can be improved when municipal solid waste incineration (MSWI) ash is used as the combined additive. Ash is composed mainly of metals, so environmental impact must be evaluated if it is used as amendment in the cement industry. The use of MSWI ash in stabilization of contaminated soils would be useful for the sustainable environmental management in two ways: S/S contaminated soil gains better geotechnical stability and waste incineration industry gets rid of the ash with high metal content. The aim of research is to provide pilot batch experimental results for leaching of heavy metal compounds when S/S technology is used for contaminated soils using PC and MSWI bottom ash additives. Mineral soils were spiked with copper, PC and MSWI were added in known proportions and leaching tests applied. Main results show that PC addition allows to chemically stabilizing soil; thus, heavy metals are not leached out from combined mass of spiked soil and MSWI bottom ash.

The growing economy with following industrialization and urbanization has led to environmental contamination with trace elements worldwide. In urban environment, the large inputs of anthropogenic contaminants in atmosphere are arising from mobile and stationary sources. The snow sample analysis is one of methods to monitor air contamination with heavy metals in urban areas. The aim of this research is to analyse heavy metal contamination and distribution in urban environment of Jelgava city. The samples were collected twice in January and February. Snow samples were collected in 20 urban area sampling plots and one natural area sampling plot with three repetitions taken from 1.0 to 1.5 kg of snow. The concentration of trace elements was estimated in 126 melted and filtrated snow water using inductively coupled plasma spectrometer (ICP-OES). The average heavy metals and nutrients concentrations were calculated for each sample. The concentrations data of trace elements were analysed using agglomerative hierarchical clustering method. The results show differences between results in January and February. The differences are related to anthropogenic impact intensity differences during the exposition periods of snow. The clustering results of snow samples taken in January show three clusters, but snow samples taken in February show four clusters.

This paper aims to deal with the phytoremediation approach for protection of environment and preventing the streaming of contaminant flows to hydrological systems. Phytoremediation is a cost-effective environmentally friendly clean-up technology, which uses plants and microorganisms in rhizosphere for soil and groundwater treatment. Phytoremediation is enhancing degradation of organic pollutants and improving stabilization of inorganic contaminants where plants can be used to treat soil and water polluted with hydrocarbons, chlorinated substances, pesticides, metals, explosives, radionuclides as well as to reduce the excess of nutrients. Selection of species for this type of treatment processes is based on evapotranspiration potential and ability to bioaccumulate contaminants. The project entitled “Phytoremediation Park for treatment and recreation at glassworks contaminated sites” (PHYTECO) aimed at cross-sector international partnership. The challenge of project was to develop remediation strategy where negative consequences from centuries long anthropogenic influence are turned to be something positive – development of the recreation park from the glass dump. New “Knowledge in Inter Baltic Partnership Exchange for Future Regional Circular Economy Cooperation” (PECEC) project is sequential continuation.

Soil and groundwater as the leachate may contaminate surrounding watersheds, thus different pollutants from closed dumps and landfills pose significant risks to human health and ecology. Pollution may lead to soil and water degradation however it might be diminished through sustainable dump site closure projects and processual management. Several decades of clays and clay minerals studies lead to modified clay composites concept that is one of the potential promising solutions for building the landfill covering material and serve as capping biocover layer at the same time. As humic substances are constituents of soil organic matter, pollutants can be sorbed on the surfaces of complex molecules. These kind of humic acid-clay mineral composite materials thus might become as low cost building material component − covering material. Construction of such layer is to be performed as a combination of clay-humic composites and landfill mined fine fraction of waste with small amendment of natural soil. Several hypotheses that are already proven has to be mentioned: a) Clay minerals produce composites with humic substances; 2) Clay-humic complexes reduce through sorption both organic and inorganic pollutants; 3) Low risk of toxic by-products from landfill mined waste fine fraction can be the problem; 4) Such composites mostly would trap toxic contaminants (e.g., pharmaceuticals) found in reworked fine fraction of waste. The aim of the work is to provide alternative solution for landfill closure by giving theoretical considerations from multidisciplinary knowledge of environmental engineering, chemistry and waste management.

The paper presents the results of investigations on wastewater formation and its treatment in constructed wetlands (CW) with horizontal flow. The investigations were carried out on a dairy farm in the period of 1995-2004. On farmsteads containing cattle sheds, the pollution of wastewater is 2-3 times higher compared with domestic wastewater. The largest amount of slowly decomposing organic pollutants is retained during wastewater filtration via a septic tank (62.7% according to CODCr). During wastewater filtration through a horizontal CW, the amount of retained organic pollutants biochemical oxygen demand (BOD5) and chemical oxygen demand (CODCr) is 93.6%. During wastewater filtration through CW, nutrients (Ntotal and Ptotal) treatment efficiency on the dairy farms, where Ntotal concentration is 101.0 mg lE-1, is one the average 61.4% of nutrient load, and 41.4% of P where Ptotal concentration is 21.5 mg lE-1. The analyzed wastewater treatment facilities (septic tank + CW) are distinct for their buffering capabilities. They are affective enough, however due to limited P removal processes in sustainable natural environment, additional P-removal means are to be used in wastewater treatment facilities arranged on dairy farms.

The processing of milk in dairy companies produces a certain amount of wastewater and liquid wastes. During the treatment process of such wastes sludge is accumulated in treatment facilities. The sludge is a rather valuable soil fertilizer; however, apart from plant available nutrients, it also contains large amounts of pollutants. The paper analyzes the quality of wastewater treatment process performed in treatment facilities of dairy companies, and specifies the amounts of plant available nutrients contained in sludge accumulated during the treatment process of wastewater and liquid wastes. The amounts of heavy metals contained in sludge are compared with their maximum allowable concentrations determined in the environmental requirements for soil fertilization (Aplinkosaugos reikalavimai..., 2001). On the basis of the study results and normative documents of environment protection, the article presents optimal rates and regime for sludge fertilization as well as analyzes the agro-technical and qualitative characteristics of sludge spreaders made at the Water management Institute of Lithuanian University of Agriculture and used during the technological process of fertilization.