A synbiotic product of combined Lactobacillus plantarum TISTR 875 with water extracts and crude fibers from corn, mungbean, and soybean was formulated to investigate the survival of L. plantarum during freeze-drying and storage. The impacts of those water extracts and crude fibers on probiotic survival were determined in both a cultural medium and a freeze-drying medium. L. plantarum cultivated in de Man, Rogosa, and Sharpe (MRS) broth containing 2 % of water extract from soybean with 2 % mungbean fiber showed only 0.11 log CFU/ml cell reduction. The survival of L. plantarum harvested at the late log phase, mid stationary, phase and late stationary phase did not show statistical significance (P > 0.05), whereas an initial pH of 6.5 and growth temperature of 37 °C showed greater impact (P < 0.05). The addition of corn extract to the freeze-drying medium as a cryoprotectant had a similar effect on L. plantarum survival as sucrose, but it was better (P < 0.05) than fructo-oligosaccharide and exopolysaccharides from Weissella cibaria A2, soybean extract, mungbean extract, soybean, corn, and mungbean fibers. A protective coating of corn extract was revealed and observed using scanning electron microscopy. The freeze-dried L. plantarum, cultivated in MRS broth containing soybean extract and mungbean fiber with corn extract as a cryoprotectant, retained high viability of 7.21 and 6.88 log CFU/ml after 8-week storage in a vacuum-packed aluminum foil-laminated polyethylene sachet and a nitrogen-flushed glass vial, respectively. ©Springer Science+Business Media New York 2012.

Three novel β-pinene-based fluorescent probes 2a–2c were designed and synthesized for the selective detection of Al³⁺. Probe 2a showed higher fluorescence intensity toward Al³⁺ than the other two compounds. Probe 2a determined the concentration of Al³⁺ with a rapid response time (45 s), wide pH range (pH = 1–9), excellent sensitivity (LOD = 8.1 × 10⁻⁸ M) and good selectivity. The recognition mechanism of probe 2a toward Al³⁺ was confirmed by ¹H NMR, HRMS and DFT analysis. Probe 2a was successfully used as a signal tool to quantitatively detect Al³⁺ in food samples and environmental water samples. Furthermore, probe 2a was successfully utilized to label intracellular Al³⁺, indicating its promising applications in living cells.

Preconcentration of aluminum Al³⁺ was carried out by a novel deep eutectic solvent based ultrasound-assisted liquid phase microextraction (DES-UALPME) method. The deep eutectic solvents (DESs), a green solvent was first time used for enrichment and quantification of very low concentration of Al³⁺ in water and food samples, prior to analysed by electrothermal atomic absorption spectrometry (ETAAS). In present method it was observed that % recovery of Al-8-hydroxyquinoline chelates efficiently extracted by DES solvent. Pre-enrichment factor and limit of detection were observed to be 50, and 0.032μgL⁻¹, respectively. Developed procedure was validated with the CRM (SLRS-5 river water) of Al and a good agreement was observed in results of measured value to the certified value. The RSD was calculated as 3.3%. The presented procedure was successfully carried out to different water and food samples.

Correction for ‘A highly sensitive and selective fluorescent probe for quantitative detection of Al³⁺ in food, water, and living cells’ by Qian Jiang et al., RSC Adv., 2019, 9, 10414–10419.