The partition coefficients (K ow) of benzoic acid and sorbic acid in systems of fish oil (sand eel)-water, fish oil-buffer solution, rape oil-water and olive oil-water were experimentally determined in a temperature range from 5 to 43°C and pH from 4.5 to 6.5°C. The dimerization of benzoic acid in fish oil-water system was observed at 25°C. Two modifications have been made to the Nordic Food Analysis Standard for the determination of sorbic acid by HPLC. The experimental results show that the K ow of benzoic acid and sorbic acid in fish oil-buffer system is ca. 100 times lower than that in fish oil-water system. The K ow values of benzoic acid and sorbic acid in fish oil and water system decrease with increasing system pH values. The partition coefficients of plant origin and fish origin oils are in the same order of magnitude even though their molecular structures are very different.

In the present investigation, emulsifying potential of galactan exopolysaccharide (EPS) extracted from Weissella confusa KR780676 has been evaluated with various food grade flavours (vanilla, cardamom and pineapple). Concentration of EPS was optimized as 1% with these flavours, in addition to the effect of salinity (NaCl), monovalent ion (KCl) and temperature on emulsion activity (EA), and emulsion stability (ES) was also inspected. Filter paper wetting test exhibited water-in-oil-in-water (w/o/w) and oil-in-water (o/w) type emulsions. The extent in granule disintegration and the retrogradation process of flavour emulsions were studied with pasting properties. Electron micrography and particle size analysis revealed the morphology and the size of emulsion droplets. Thermal stability of emulsions has found 100% at various temperatures (−20 to 60 °C) for vanilla and pineapple flavour, whereas, it was varying for cardamom as per the temperature disparity. Emulsion stability of vanilla and pineapple flavour was retained as such for various concentrations of NaCl whereas decreased for cardamom in direct proportion. In case of KCl all the three flavours showed greater stability. These emulsifying properties indicate that galactan EPS can be a prospective alternative to commercial biopolymers in food and pharmaceuticals industries.

Nowadays people demand for healthy, convenient, and wholesome foods. Double emulsions have attracted widespread attention in the food industry owing to their capability of encapsulating the compounds, fabricating polymersomes, and acting as fat replacers or sweetness enhancers in different foods. In this review, properties and their importance in the fabrication of double emulsions along with their advantages and disadvantages are discussed. In the lateral part of the manuscript, the instability mechanism and the effect of different variables on the stability of the double emulsions are reviewed. Finally, this review provides a glimpse of the recent food application of W/O/W double emulsions. Double emulsions have a better profile on the encapsulation of nutrients along with maintenance of the organoleptic quality of the food. The conventional emulsification techniques result in low encapsulation efficiency and poor monodispersity. With recent developments, different novel methods for the fabrication of double-emulsions have been developed such as glass capillary microfluidic devices, membrane emulsification, phase inversion techniques, etc. However, findings thus far indicate that the long-term stability of double emulsions remains a crucial issue that limits their wide application in food formulations. Therefore, further research should focus on finding innovative approaches to improve the stability of double emulsions.

This work deals with the manufacture of oil-in-water food emulsions stabilised by tuna proteins. The influence of protein and oil concentrations on the linear viscoelastic properties and microstructure of these emulsions was analysed. Stable emulsions with suitable linear viscoelastic response and microstructural characteristics were formulated with 70 wt.% oil and, at least, 0.25 wt.% tuna protein. Similarly, emulsions with oil concentrations between 45 and 70 wt.% were prepared using 0.50 wt.% protein. All these emulsions showed a predominantly elastic response in the linear viscoelastic region and a well-developed plateau region in its mechanical spectrum. Rheological and droplet size distribution results pointed out an extensive droplet flocculation, due to interactions among emulsifier molecules located at the oil–water interface of adjacent droplets. As a result, the linear viscoelastic behaviour was controlled by protein–protein interactions, allowing the use of the plateau modulus to successfully normalise both the storage and loss moduli as a function of frequency onto a master curve, irrespective of the selected emulsion formulation.

The microstructure and stability of oil-in-water emulsions, stabilized with non-protein emulsifiers (sorbitan esters), were analyzed as a function of emulsification time, rotor speed, hydrophilic-lipophilic balance (HLB), and ionic strength. Sauter average dia (D[3,2]) were determined from micrographs. Back-scattered light data were analyzed and a method to determine creaming rates of the systems was proposed. Creaming rates showed that the relationship between emulsion stability and HLB was non-linear. Addition of NaCl raised creaming rates, resulting in decreased stability, while micrographs showed the presence of flocs. Results were discussed taking account of interactions present in the system.

There has been a growing interest in developing effective strategies to inhibit lipid oxidation in emulsified food products by utilization of natural phenolic antioxidants owing to their growing popularity over the past decades. However, due to the complexity of emulsified systems, the inhibition mechanism of phenolic antioxidants against lipid oxidation is rather complicated and not yet fully understood. In order to highlight the importance of polarity of phenolic antioxidants in emulsified systems according to the polar paradox, this review covers the recent progress on chemical, enzymatic, and chemoenzymatic lipophilization techniques used to modify the polarity of antioxidants. The partitioning behavior of phenolic antioxidants at the oil–water interface, which can be influenced by the presence of synthetic surfactants and/or antioxidant emulsifiers (e.g., polysaccharides, proteins, and phospholipids), is discussed. In addition, the emerging phenolic antioxidants among phenolic acids, flavonoids, tocopherols, and stilbenes applied in food emulsions are elaborated. As well, the interactions of polar–nonpolar antioxidants are stressed as a promising strategy to induce synergistic interactions at oil–water interface for improved oxidative stability of emulsions.

In this study, the effect of high‐intensity ultrasound (HIUS) (200 and 400 W for 0, 5, 10 and 15 min respectively) on conformational changes, physicochemical, rheological and emulsifying properties of scallop (Patinopecten yessoensis) myofibrillar protein (SMP) was investigated. HIUS‐treated SMP had lower α‐helix content and higher β‐sheet content compared with the native SMP. HIUS treatment induced the unfolding of SMP and increased the surface hydrophobicity. The particle size of SMP decreased and the absolute zeta‐potential increased after ultrasonication, which in turn increased the solubility of SMP. The conformational changes and the improvement of physicochemical properties of SMP increased the ability for SMP to lower the interfacial tension at the oil–water interface and increased the percentage of adsorbed protein. As a result, the emulsifying properties, rheological properties of SMP and storage stability of emulsions were also improved. In conclusion, HIUS treatment has future potential for improving the emulsifying properties of SMP.

The aim of the present study was to assess the influence of pH (3, 7 and 9) as well as ionic strength of NaCl (0mmol/l, 100mmol/l, 200mmol/l and 400mmol/l) on the retention and release characteristics of diacetyl and (−)-α-pinene in oil-in-water (o/w) emulsions prepared with dried egg yolk (DEY) or starch sodium octenylsuccinate (SOE). Increase of pH from 3 to 9 progressively enhanced retention of diacetyl in emulsions prepared with both DEY and SOE. Whereas, in samples flavoured with (−)-α-pinene, the highest and lowest retention time-courses were detected at pH 9 and pH 7 as well as pH 7 and pH 3 regarding emulsions prepared with DEY as well as SOE, respectively. With increasing salt concentration, the retention of diacetyl was decreased, irrespectively of the applied emulsifier type, whereas generally opposite effects were observed in the case of (−)-α-pinene. The parameters of release characteristics i.e., release rate constants (k) and release mechanism factors (n), were calculated using Avrami’s equation. ANOVA revealed significant effects (p<0.001) of pH and NaCl concentration on k parameters, whereas relationship between applied environmental conditions and n factors was dependent on hydrophobicity of the odourant. Sensory evaluation revealed higher correlation values between odour intensity and aroma compound concentration in emulsions aromatized with (−)-α-pinene than with diacetyl.