In the southwestern United States, precipitation in the high mountains is a primary source of groundwater recharge. Precipitation patterns, soil properties and vegetation largely control the rate and timing of groundwater recharge. The interactions between climate, soil and mountain vegetation thus have important implications for the groundwater supply. This study took place in the Sacramento Mountains, which is the recharge area for multiple regional aquifers in southern New Mexico. The stable isotopes of oxygen and hydrogen were used to determine whether infiltration of precipitation is homogeneously distributed in the soil or whether it is partitioned among soil-water ‘compartments’, from which trees extract water for transpiration as a function of the season. The results indicate that “immobile” or “slow” soil water, which is derived primarily from snowmelt, infiltrates soils in a relatively uniform fashion, filling small pores in the shallow soils. “Mobile” or “fast” soil water, which is mostly associated with summer thunderstorms, infiltrates very quickly through macropores and along preferential flow paths, evading evaporative loss. It was found that throughout the entire year, trees principally use immobile water derived from snowmelt mixed to differing degrees with seasonally available mobile-water sources. The replenishment of these different water pools in soils appears to depend on initial soil-water content, the manner in which the water was introduced to the soil (snowmelt versus intense thunderstorms), and the seasonal variability of the precipitation and evapotranspiration. These results have important implications for the effect of climate change on recharge mechanisms in the Sacramento Mountains.

The Agua Negra drainage system (30 12'S, 69 50' W), in the Argentine Andes holds several ice- and rock-glaciers, which are distributed from 4200 up to 6300 m a.s.l. The geochemical study of meltwaters reveals that ice-glaciers deliver a HCO₃⁻----Ca²⁺ solution and rock-glaciers a SO₄²⁻----HCO₃⁻----Ca²⁺ solution. The site is presumably strongly influenced by sublimation and dry deposition. The main processes supplying solutes to meltwater are sulphide oxidation (i.e. abundant hydrothermal manifestations), and hydrolysis and dissolution of carbonates and silicates. Marine aerosols are the main source of NaCl. The fine-grained products of glacial comminution play a significant role in the control of dissolved minor and trace elements: transition metals (e.g. Mn, Zr, Cu, and Co) appear to be selectively removed from solution, whereas some LIL (large ion lithophile) elements, such as Sr, Cs, and major cations, are more concentrated in the lowermost reach. Daily concentration variation of dissolved rare earth elements (REE) tends to increase with discharge. Through PHREEQC inverse modelling, it is shown that gypsum dissolution (i.e. sulphide oxidation) is the most important geochemical mechanism delivering solutes to the Agua Negra drainage system, particularly in rock-glaciers. At the lowermost reach, the chemical signature appears to change depending on the relative significance of different meltwater sources: silicate weathering seems to be more important when meltwater has a longer residence time, and calcite and gypsum dissolution is more conspicuous in recently melted waters. A comparison with a non-glacierized semiarid drainage of comparable size shows that the glacierized basin has a higher specific denudation, but it is mostly accounted for by relatively soluble phases (i.e. gypsum and calcite). Meltwater chemistry in glacierized arid areas appears strongly influenced by sublimation/evaporation, in contrast with its humid counterparts.

The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.

In the unlined Tuxbach water transfer tunnel, running between Hintertux (1,500 m asl) and the Schlegeis Reservoir (Austria), a local geothermal anomaly with temperatures up to 14.6 °C exists. These temperatures are around 3 °C higher than expected, considering the tunnel’s shallow depth, together with its surrounding alpine environment and regional heat flow. This is especially noticeable because the temperatures have remained stable since the tunnel’s construction in 1969, although the tunnel is generally cooling the surrounding rock massive. The objective of this investigation is to explain the origin of the anomaly with hydrogeological methods and to evaluate the hydrogeological properties of the gneisses exposed in the tunnel. The anomaly is caused by the high hydraulic conductivity (~2.5∙10⁻⁵ m s⁻¹) within a narrow shear-zone core, part of the Tux Shear Zones in the Ahorn Gneiss Core. The zone triggers fast groundwater transport over 1.5 km from both sides towards the tunnel. One reason is that the morphology provides thicker overburden with growing distance from the tunnel and therefore higher temperatures on the same horizontal level in the directions of the fault plane. The second explanation is that the narrowness of the shear zone permits effective heat transfer similar to a heat exchanger. No hydrothermal water share is recognizable; instead, mainly cold glacial melt water and snow contribute to the section of the anomaly and all other runouts of the tunnel. Factually based results show the disproportionately high contribution of snow and glaciers to the groundwater recharge in this alpine hard-rock aquifer.

The use of snowmelt as an inexpensive multi-component tracer solution for active aquifer characterization is investigated, creating a valid alternative to existing artificial water isotope labelling using enriched deuterium oxide (²H₂O) and water-¹⁸O (H₂¹⁸O). The approach directly takes advantage of natural differences between groundwater and precipitation. It is shown, at laboratory-scale and small field-scale, that a direct injection of snowmelt into a porous medium allows for the tracing of water flow and, therefore, for the determination of transport parameters based on the stable isotope signatures (δ²H and δ¹⁸O) and on the sum parameter electrical conductivity (EC). The differences in the isotope signature between the snowmelt and groundwater applied in this study were significant, with ∆(δ²H) = 61.0‰ and ∆(δ¹⁸O) = 8.2‰, while the EC difference was ~0.5 mS/cm. Stable isotope breakthrough was observed to be almost congruent to sodium chloride (laboratory tracer experiment) and to uranine (field-scale push-drift-pull test), clearly supporting the assumption of conservative transport. A crosscheck of the isotope data in δ²H-δ¹⁸O plots revealed no significant biases in the tests. On the other hand, the snowmelt’s EC breakthrough suffered from a slight retardation due to ion exchange and mineral reactions.

Groundwater recharge (GR) is a complex process that is difficult to quantify. Increasing attention has been given to unsaturated zone modeling to estimate GR and better understand the processes controlling it. Continuous soil-moisture time series have been shown to provide valuable information in this regard. The objectives of this study were to (i) analyze the processes and factors controlling GR in an unconfined granular aquifer in a cold and humid environment and (ii) assess the uncertainties associated with the use of data from different sources. Soil moisture data monitored over three years at three experimental sites in southern Quebec (Canada) were used to calibrate the HYDRUS-1D model and to estimate ranges of possible GR in a region where groundwater is increasingly used as a source of fresh water. The simulations identified and quantified important factors responsible for the near-surface water balance that leads to GR. The resulting GR estimates from 2016 to 2018 showed marked differences between the three sites, with values ranging from 347 to 735 mm/y. Mean GR for the three sites was 517 mm/y for 2016–2018 and 455 mm/y for the previous 12-year period. GR was shown to depend on monthly variations in precipitation and on soil textural parameters in the root zone, both controlling soil-water retention and evapotranspiration. Monthly recharge patterns showed distinct preferential GR periods during the spring snowmelt (38–45% of precipitation) and in the fall (29% of precipitation). The use of different meteorological datasets was shown to influence the GR estimates.

In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems with features including the occurrence of year-round open water and the formation of icings, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Stable isotopes (δ¹⁸O, δD, δ¹³CDIC), and noble gases have proved useful to study groundwater recharge and flow of groundwater which discharges along rivers in Canada’s western Arctic. In these studies of six catchments, groundwater recharge was determined to be a mix of snowmelt and precipitation. All systems investigated show that groundwater has recharged through organic soils with elevated PCO₂, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 5 °C, which when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater circulation times were found to be up to 31 years for non-thermal waters using the ³ H-³He method.

Groundwater recharge sets a constraint on aquifer water balance in the context of water management. Historical data on groundwater and other relevant hydrological processes can be used to understand the effects of climatic variability on recharge, but such data sets are rare. The climate of the Canadian prairies is characterized by large inter-annual and inter-decadal variability in precipitation, which provides opportunities to examine the response of groundwater recharge to changes in meteorological conditions. A decadal study was conducted in a small (250 km²) prairie watershed in Alberta, Canada. Relative magnitude of annual recharge, indicated by water-level rise, was significantly correlated with a combination of growing-season precipitation and snowmelt runoff, which drives depression-focussed infiltration of meltwater. Annual precipitation was greater than vapour flux at an experimental site in some years and smaller in other years. On average precipitation minus vapour flux was 10 mm y⁻¹, which was comparable to the magnitude of watershed-scale groundwater recharge estimated from creek baseflow. Average baseflow showed a distinct shift from a low value (4 mm y⁻¹) in 1982–1995 to a high value (15 mm y⁻¹) in 2003–2013, indicating the sensitivity of groundwater recharge to a decadal-scale variability of meteorological conditions.

Based on analysis of groundwater hydrogeochemical and isotopic data, this study aims to identify the recharge sources and understand geochemical evolution of groundwater along the downstream section of the Shule River, northwest China, including two sub-basins. Groundwater samples from the Tashi sub-basin show markedly depleted stable isotopes compared to those in the Guazhou sub-basin. This difference suggests that groundwater in the Tashi sub-basin mainly originates from meltwater in the Qilian Mountains, while the groundwater in the Guazhou sub-basin may be recharged by seepage of the Shule River water. During the groundwater flow process in the Tashi sub-basin, minerals within the aquifer material (e.g., halite, calcite, dolomite, gypsum) dissolve in groundwater. Mineral dissolution leads to strongly linear relationships between Na⁺ and Cl⁻ and between Mg²⁺+ Ca²⁺ and SO₄ ²⁻ + HCO₃ ⁻, with stoichiometry ratios of approximately 1:1 in both cases. The ion-exchange reaction plays a dominant role in hydrogeochemical evolution of groundwater in the Guazhou sub-basin and causes a good linear relationship between (Mg²⁺+ Ca²⁺)–(SO₄ ²⁻ + HCO₃ ⁻) and (Na⁺+ K⁺)–Cl⁻ with a slope of −0.89 and also results in positive chloroalkaline indices CAI 1 and CAI 2. The scientific results have implications for groundwater management in the downstream section of Shule River. As an important irrigation district in Hexi Corridor, groundwater in the Guazhou sub-basin should be used sustainably and rationally because its recharge source is not as abundant as expected. It is recommended that the surface water should be used efficiently and routinely, while groundwater exploitation should be limited as much as possible.