A two-dimensional numerical groundwater flow model was established and calibrated for the hyperarid Najd region in southern Oman. The results indicate that recent recharge rates are required to sustain the observed groundwater heads in the Najd. The model was also used to estimate possible ranges of past recharge rates and the effective porosity of the main aquifer unit. Recharge rates during past humid periods were estimated to be no more than 1–3 times modern rates. The effective porosity was estimated to be between 0.06 and 0.093. Insight into the nature of the long-term transport within the aquifer was gained by using transient model runs over the last 350 ka and (1) varying the recharge intensity (from 0.1 to 2.5 times modern), and (2) the timing and duration of humid and dry periods. Finally, results indicate that although recharge rates and the flow conditions have likely changed over time, a steady-state model is capable of reproducing the observed groundwater residence times in the Najd based on carbon-14, helium and chlorine-36 dating.

The Eocene deposits of Kazan Basin in Turkey contain a rare trona mineral which is planned to be extracted by solution mining. The complex flow dynamics and mixing mechanisms as noted from previous hydraulic and hydrochemical data need to be augmented with environmental tracer and noble gas data to develop a conceptual model of the system for the assessment of the impacts of the mining and to develop sustainable groundwater management policies throughout the area. The tracers used include the stable isotopes of water (δ²H, δ¹⁸O), δ¹³C and¹⁴C of dissolved inorganic carbon (DIC), tritium (³H), the chlorofluorocarbons CFC-11 and CFC-12, and the noble gases He and Ne. The system studied consists of three aquifers: shallow, middle, and deep. CFC data indicate modern recharge in the shallow system. The estimates of ages through¹⁴C dating for the deeper aquifer system are up to 34,000 years. Helium concentrations cover a wide range of values from 5 × 10⁻⁸to 1.5 × 10⁻⁵ cm³STP/g.³He/⁴He ratios vary from 0.09RAto 1.29RA(where RAis the atmospheric³He/⁴He ratio of 1.384 × 10⁻⁶), the highest found in water from the shallow aquifer. Mantle-derived³He is present in some of the samples indicating upward groundwater movement, possibly along a NE–SW-striking fault-like feature in the basin.

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.