Effect of drying on the desorption of diuron and terbuthylazine from natural soils
2007
Lennartz, Bernd | Louchart, Xavier | University of Rostock | Laboratoire d'étude des Interactions Sol - Agrosystème - Hydrosystème (UMR LISAH) ; Institut de Recherche pour le Développement (IRD)-Institut National de la Recherche Agronomique (INRA)-Centre international d'études supérieures en sciences agronomiques (Montpellier SupAgro)-Institut national d’études supérieures agronomiques de Montpellier (Montpellier SupAgro)
Corresponding author. fax: +49 381 498 2159. E-mail address: bernd.lennartz@uni-rostock.de (B. Lennartz).
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Показать больше [+] Меньше [-]Английский. This work was initiated to study the effects of climate induced soil water status variations which can reach extreme values under natural conditions on the sorption process of hydrophobic organic compounds. Based on the classical slurry batch methodology an approach is developed that allows the fast and careful complete drying of soil suspensions (microwave technique). Classical adsorption experiments were followed by three desorption steps with and without drying cycles. Drying and re-wetting enhanced the sorption-desorption hysteresis and Freundlich adsorption coefficients increased from 5.9 to 16 and 5.2 to 21 over three drying cycles for diuron and terbuthylazine respectively. Assuming the validity of a dual stage adsorption process, model evaluation suggests that drying is as a shrinking-like process leading to conformational changes of the dominant sorbent (soil organic matter) which restrict the intra-micro-particle diffusion. Rewetting only leads to a partial recovery of the diffusional pore space.
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