Photoredox Generation of Sulfonyl Radicals and Coupling with Electron Deficient Olefins
2020
Chen, Yiding | McNamara, Nicole | May, Oliver | Pillaiyar, Thanigaimalai | Blakemore, David C. | Ley, Steven V.
Various sulfone tetrazoles were activated via iridium photoredox catalysis in the presence of DMAP to give dialkyl sulfones. The presumed sulfone radical intermediates were trapped by a range of electron-deficient olefins in generally good to excellent yields.
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