Investigation of Past and Present Multi-metal Input along Two Highways of British Columbia, Canada, Using Lead Isotopic Signatures
2007
Preciado, Humberto F. | Li, Loretta Y. | Weis, Dominique
A multi-media monitoring field investigation, which included atmospheric, road sediment and soil samples, was carried out at two highway study sites to identify past and present Pb sources. Past Pb anthropogenic sources such as paint and leaded gasoline were linked to significant Pb accumulation in roadside soils at both sites through Pb isotopic analyses. This was achieved by identifying the distinct Pb isotopic composition in older versus newer Pb accumulation at different depths across the soil profile. Older Pb accumulations exhibited lower ²⁰⁶Pb/²⁰⁷Pb isotopic ratios, consistent with Canadian Pb-bearing ores, whereas newer Pb accumulations reflected a mixture of the ²⁰⁶Pb/²⁰⁷Pb ratios of road sediment samples, with the Pb isotopic signature of uncontaminated soil. Isotopic analyses were also helpful in identifying road sediment as an important current source of Pb in roadside soils, by comparing the isotopic signatures derived from road sediment and atmospheric dustfall. The known association of Pb with anthropogenic sources was used to indirectly relate other metals (Cu, Mn, Zn) to the same source by the Enrichment Ratio method. Significant positive correlations at the 90-95% confidence level were found between Cu, Zn and Pb Enrichment Ratios in roadside and dust deposition samples. Weaker correlations were found between Mn and Pb, at the highway study site with the least amount of traffic. However, correlations between these two metals were significant at the 90% confidence level for the busier highway site highlighting Mn potential anthropogenic source. An isotopic tracer study is suggested to further investigate the process of Mn redistribution in the environment due to exhaust fuel emissions. More research is needed regarding the potential impact from using a Mn-based fuel additive.
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