³d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications
2020
Ting, Stephen I. | Garakyaraghi, Sofia | Taliaferro, Chelsea M. | Shields, Benjamin J. | Scholes, Gregory D. | Castellano, Felix N. | Doyle, Abigail G.
Synthetic organic chemistry has seen major advances due to the merger of nickel and photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve generation of excited nickel species, sometimes even in the absence of a photoredox catalyst. To gain insights about these excited states, two of our groups previously studied the photophysics of Ni(ᵗ⁻ᴮᵘbpy)(o-Tol)Cl, which is representative of proposed intermediates in many Ni-photoredox reactions. This complex was found to have a long-lived excited state (τ = 4 ns), which was computationally assigned as a metal-to-ligand charge transfer (MLCT) state with an energy of 1.6 eV (38 kcal/mol). This work evaluates the computational assignment experimentally using a series of related complexes. Ultrafast UV–Vis and mid-IR transient absorption data suggest that a MLCT state is generated initially upon excitation but decays to a long-lived state that is ³d-d rather than ³MLCT in character. Dynamic cis,trans-isomerization of the square planar complexes was observed in the dark using ¹H NMR techniques, supporting that this ³d-d state is tetrahedral and accessible at ambient temperature. Through a combination of transient absorption and NMR studies, the ³d-d state was determined to lie ∼0.5 eV (12 kcal/mol) above the ground state. Because the ³d-d state features a weak Ni–aryl bond, the excited Ni(II) complexes can undergo Ni homolysis to generate aryl radicals and Ni(I), both of which are supported experimentally. Thus, photoinduced Ni–aryl homolysis offers a novel mechanism of initiating catalysis by Ni(I).
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