Oxidative Decarboxylation of Arylacetic Acids in Water: One-Pot Transition-Metal-Free Synthesis of Aldehydes and Ketones
2017
Mete, Trimbak B. | Khopade, Tushar M. | Bhat, Ramakrishna G.
One-pot transition-metal-free synthesis of aromatic aldehydes and ketones via oxidative decarboxylation of arylacetic acids in water is developed. Protocol relies on the direct decarboxylation of sp3-hybridized carbon in water without any over oxidation into carboxylic acids with minimal waste. Reaction mechanism is investigated and application of this protocol is demonstrated on a gram scale.
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