Substituent Effects in the Oxidation of 2-Alkyl-1,4-dialkoxybenzenes with Ceric Ammonium Nitrate
2016
Love, Brian E. | Simmons, Alexander L.
Increased steric size of alkyl groups and the presence of coordinating atoms on alkoxy groups have both been found to contribute to decreasing yields of diquinones upon reaction of 2-alkyl-1,4-dialkoxybenzenes with CAN. The overall hydrophilicity of the substrates does not appear to be a significant factor in determining the diquinone yield for these reactions.
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