Palladium catalysed enantioselective phosphination reactions using secondary phosphine-boranes and aryl iodide
2005
Pican, Stéphanie | Gaumont, Annie-Claude
Preliminary results dealing with the enantioselective version of the C–P cross-coupling reaction between dissymmetric secondary phosphine-borane complexes and aryl iodide derivatives are presented. To gain information on the enantiodiscriminating step, direct observation of an intermediate involved in the catalytic cycle has been achieved by ³¹P NMR spectroscopy.
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