Bioinspired approach to enhance mechanical properties of starch based nacre-mimetic nanocomposite
2019
Li, Jiali | Zhou, Mi | Cheng, Fei | Lin, Yi | Zhu, Puxin
In this work, a facile biomimetic method was proposed to enhance the interfacial adhesion between layered clay and polymer matrix inspired by strong adhesion of mussel adhesive proteins. Montmorillonite (MMT) was coated with a thin layer of polydopamine (PDA) through self-polymerization of dopamine (DA) and subsequently assembled with corn starch (CS) to generate CS/MMT-DA nanocomposite. FTIR, XPS, SEM and XRD results demonstrated that PDA coating benefited not only the intercalation and dispersion of the modified MMT (MMT-DA) in the polymer matrix but also the strong interfacial adhesion between filler and matrix. The tensile strength of CS/MMT-DA nanocomposites was largely enhanced by increasing the amount of DA or polymerization time. This work can largely expand the application of MMT and provide a new idea for preparing high performance starch nanocomposites.
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Эту запись предоставил National Agricultural Library