Asymmetric total synthesis of Lycopodium alkaloid (+)-lycopladine A
2013
Xu, Tao | Luo, Xiu-Li | Yang, Yu-Rong
Asymmetric total synthesis of (+)-lycopladine A (1) has been achieved. Key elements of the synthesis include an efficient Helquist annulation to assemble the cis-fused 6/5 bicycle, Stille coupling reaction to elongate the allylic side chain, and Kröhnke pyridine synthesis to set the pyridine core at the final stage.
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Эту запись предоставил National Agricultural Library