Polyethylene cellulose nanofibrils nanocomposites
2017
Maia, Thiago Henrique Silveira | Larocca, Nelson Marcos | Beatrice, Cesar Augusto Gonçalves | de Menezes, Aparecido Júnior | de Freitas Siqueira, Gilberto | Pessan, Luiz Antonio | Dufresne, Alain | França, Marcos Pini | de Almeida Lucas, Alessandra
This paper investigates the use of an aqueous dispersion of polyethylene copolymer with a relatively high content of acrylic acid as a compatibilizer and as an alternative medium to obtain polyethylene CNF nanocomposites. The CNF content was varied from 1 to 90wt% and the appearance, optical, thermal, mechanical and rheological properties, as well the morphology of the films were evaluated. The PE/CNF films are transparent up to 20wt% of NFC indicating a good dispersion of CNF, but a poor distribution, with PE-rich and CNF-rich regions observed by SEM. Improved mechanical properties were achieved, with a 100% and 15,900% increase in the Young’s modulus with 1wt% and 90wt% NFC, respectively. The rheological behavior indicated good melt processability. According to these results, aqueous polyolefin dispersions seem to be a promising, easy and relatively fast route for obtaining cellulose/polyolefins nanocomposites with low to high contents of cellulose nanofibrils.
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