Preparation of Fe-filled MOF-Al-based hydrogel for efficient reclaim of phosphate from wastewater and reusing as a slow-release fertilizer
2022
Wang, Zhengxian | Lu, Jiankang | Wu, Chengyi
In this study, a novel Fe-filled MOF-Al-based hydrogel (SA@Fe@MOF-Al) was prepared and characterized by X-ray diffraction, scanning electron microscopy, thermogravimetric analysis. The SA@Fe@MOF-Al hydrogel bead was used as an adsorbent to adsorb from wastewater. The effects on adsorption were investigated, including pH and coexist ion. The adsorption reached equilibrium within 30 min. The maximum adsorption capacity of SA@Fe@MOF-Al was 103.09 mg g⁻¹ at 298K with pH 7.0. Meanwhile, thermodynamic results confirmed that adsorption is exothermic and spontaneous. The adsorption kinetics displayed that SA@Fe@MOF-Al adsorption process was suitable to the pseudo-first-order and Langmuir model. Moreover, the feasibility of reusing the P-laden carrier material as a slow-release fertilizer was determined. The study results indicated that the product demonstrated excellent slow-release and water-retention properties. Thus, it has potential applications in improving soil moisture content and reducing soil moisture evaporation rate.
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Эту запись предоставил National Agricultural Library