Amine–N-heterocyclic carbene cascade catalysis for the asymmetric synthesis of fused indane derivatives with multiple chiral centres
2013
Jia, Zhi-Jun | Jiang, Kun | Zhou, Qing-Qing | Dong, Lin | Chen, Ying-Chun
An aminocatalytic asymmetric Diels–Alder reaction of 2,4-dienals and labile 1-indenones in situ generated from 3-bromo-1-indanones was developed, producing highly fused indane products with multiple chiral centres followed by a cascade N-heterocyclic carbene-mediated benzoin condensation.
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