Metal-free three-component synthesis of thioamides from β-nitrostyrenes, amines and elemental sulfur
2021
Peng, Ling | Ma, Li | Porter, Ran Ying | Chen, Yunfeng | Tseng, Tommaso
A metal-free CC bond cleavage reaction of β-nitrostyrenes in the presence of elemental sulfur and secondary amines/amides is described. Elemental sulfur serves as both a raw material and an oxidant for CC bond cleavage, and secondary amines or amides are both feasible nitrogen sources. Besides mild reaction condition and simple work-up procedure, the method provided thioamides with good to excellent yields.
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Эту запись предоставил National Agricultural Library