Site-selective C–H alkylation of myo-inositol via organic photoredox catalysis
2022
Cao, Haonan | Guo, Tianyun | Deng, Xuemei | Huo, Xing | Tang, Shouchu | Liu, Jian | Wang, Xiaolei
Site-selective photoredox reactions with aromatic olefins enable direct alkylation of unprotected myo-inositol at C4. The efficacy of these reactions can be finely tuned by modifying the structures of HAT reagents. These reactions open the possibility of selective C–H alkylations of myo-inositol without the need for multi-step protection–deprotection strategies.
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