Chemometric appraisal of water quality for domestic and agricultural purposes: a case study from establishing Rooppur Nuclear Power Plant (NPP) area, Pabna District, Bangladesh

Water is the main sources for domestic purposes and as well as for both farming and industrial activities. Therefore, this study investigated the quality of groundwater at Ishwardi, Pabna district of Bangladesh. This study showed that the heavy metals such as Pb, Cd, Cr, As, Ni, Cu, Zn, and Fe were remaining in trace amount. The groundwater quality index (GWQI), heavy metal evaluation index (HEI), heavy metal pollution index (HPI), and degree of contamination (Cd) revealed that all of the groundwater samples belonged to good quality condition for drinking purposes. Nevertheless, Cd provided better index than other indices. Subsequently, hazard quotient (HQ) and hazard index (HI) values for heavy metals indicated that there was no significant noncarcinogenic health risk due to oral ingestion of groundwater except three sites. However, the paired student t-test ([Formula: see text]) revealed that child was found to be more exposed compared to adult for noncarcinogenic health risk due to oral ingestion of the same groundwater samples. This study revealed that pH, EC, TDS, salinity, Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻, PO₄³⁻, and NO₃⁻ values in water samples are in tolerable limit according to Bangladesh (DoE) and international standards (WHO, IS, FAO, USEPA, UCCC). Subsequently, combined approaches of numerous irrigation water quality indices, sodium adsorption ratio (SAR), soluble sodium percentage (SSP), total hardness (TH), residual sodium carbonate (RSC), and Kelley’s ratio (KR), were applied to appraise the appropriateness of water for farming purposes. The irrigation water quality index (IWQI) revealed that majority of the groundwater samples were suitable for agricultural purposes. Classification based on Wilcox and US salinity hazard diagram indicated a consistent conclusion, which indicated that the water quality was in good condition for farming in the study area.