Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO₂ to CO
2016
Ambre, Ram B. | Daniel, Quentin | Fan, Ting | Chen, Hong | Zhang, Biaobiao | Wang, Lei | Ahlquist, Mårten S. G. | Duan, Lele | Sun, Licheng
Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO₂ reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H₂) for CO production.
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Эту запись предоставил National Agricultural Library